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Dr. Judit Oliver-Meseguer Prof. Antonio Doménech-Carbó Dr. Mercedes Boronat Dr. Antonio Leyva-Pérez Prof. Avelino Corma 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(23):6535-6539
HCl in solution accepts electron density from Au NPs and partially reduces at room temperature, as occurs with other simple diatomic molecules, such as O2 and H2. The activation can be run catalytically in the presence of alkynes to give exclusively E-vinyl chlorides, after the regio- and stereoselective transfer of HCl. Based also on this method, vinyl chloride monomer (VCM) can be produced in a milder and greener way than current industrial processes. 相似文献
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