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S. Klaus H. Jiao D. Gördes S. Hübner C. Weckbecker T. Riermeier 《Journal of organometallic chemistry》2004,689(23):3685-3700
N-acyl amino acid esters are easily accessible from enamides by cobalt-catalyzed hydroalkoxycarbonylation in moderate to excellent yield. An important reaction parameter for selective carbonylation is the use of low hydrogen partial pressure, which prevents hydrogenation as a side reaction. The reported method is applicable to various enamides and alcohols. A DFT calculation of the catalytic cycle explains the preferred pathway of this reaction. 相似文献
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