FTIR measurements of CO2 line positions and intensities at high temperature in the 3700-3750 cm spectral region

Positions and intensities for 453 spectral lines in 12 rovibrational bands of ¹²C¹⁶O₂ have been determined between 3700 and 3750 cm⁻¹. At three temperatures (294, 500, and 698 K) eight spectra have been recorded at a pressure around 5 mbar and for an absorption path of about 190 cm⁻¹ using a Bomen DA3 Fourier transform spectrometer (4 × 10⁻³ cm⁻¹ resolution). Some of the measured positions and intensities can be compared with recent experimental results that validate the experimental set-up and the data analysis procedure. The results are also compared with the values listed in the HITRAN 2000 database. If the agreement is generally good, discrepancies are observed for three hot bands.     

Anomalous behavior of conductivity of the confined Q1D electron system over liquid helium

Conductivity of electrons in a quasi-one-dimensional (Q1D) system over liquid helium in narrow channels with the parabolic profile of the potential well has been investigated at temperature T, from 0.4 to 1.8 K, for different driving electric fields and radius of channel curvature. The interval of linear electron densities varied from 2.18×10³ up to 1.7×10⁶ cm⁻¹.

The inverse mobility (1/μ_eff) in the electron-ripplon scattering region at the high linear densities of charges in the channel increases with temperature decreasing. This anomalous behavior of the electron transport in the low-temperature region has been explained by either the electron ordering or the polaronic effects in confined conducting channels. The nonlinear behavior of the electron velocity as a function of a driving electric field is supposed to be due to Breg–Cherenkov radiation of the ripplons. The radiation occurred if the velocity of electrons in the channel approaches to the critical value.     

HER磁镜上硬X射线和热电子测量

一、引言 磁镜运行中,为了要知道它在电子回旋共振加热(ECRH)下形成热电子的参数,我们测量了硬X射线能谱、硬X射线发射的时间特性、不同磁场强度下形成热电子环的位置、以及热电子的脉冲幅度分布等。 HER是中国科学院等离子体物理研究所简单型磁镜装置,它的几何尺寸是,真空室长     

Influence of chemistry and hot rolling conditions on high permeability non-grain oriented silicon steel

This paper discusses the influence of chemical composition on the final electromagnetic properties in higher permeability material. Furthermore, the effect of the hot rolling practice and the end of austenite transformation temperature range on the hot band microstructure is described. The magnetic polarization J₅₀₀₀ better than 1.7 T, using hot rolling conditions 40 mm transfer bar thickness, finish mill entry temperature 1000 °C, and finishing temperature 800–840 °C and after decarburization heat treatment and grain growth treatment, was obtained.     

Physical and Chemical Properties of Dissolved Electrons (Excess Electrons)

Electrons produced in a gaseous, liquid, or solid solvent are called dissolved electrons or excess electrons. These excess electrons can exist as quasi-free particles of high mobility in a delocalized state, comparable with electrons in a metal; or as bound particles of low mobility they can be localized within narrow limits—in a solvent cavity formed by repulsive forces. Localized electrons can also be solvated like normal ions. Characteristically, such solvated electrons exhibit broad and extensive absorption spectra in the visible to near infrared spectral range. The localized and delocalized states of the excess electrons can be in equilibrium with each other, such that a continuous transition of the properties between the limiting extremes can be observed. The reactions of the excess electrons with suitable acceptors (substrates) are initiated by an attachment-detachment equilibrium A + e^? ? A^? which is followed by further chemical rearrangements. The rate constants of these reactions vary by more than 15 powers of ten depending on the substrates and the solvents. Most of the properties of excess electrons in solution can be interpreted by means of a model which is easily understandable but quantitatively evaluated only with considerable effort.     

Reflection of electrons and photons from solids bombarded by 0.1 - to 100-MeV electrons

Electron and photon reflection ratios (in number and energy) for absorbers bombarded by electrons have been computed with the ITS Monte Carlo system version 3. Electrons of energies from 0.1 to 100 MeV have been assumed normally incident on an effectively semi-infinite absorber. The absorbers considered are elemental solids of atomic numbers from 4 to 92. The data on the electron reflection ratios agree rather well with the experimental data collected from literature except some discrepancies when the number-reflection ratio is small. For photons, the number-reflection ratio increases with increasing energy, but the energy-reflection ratio shows a maximum around 10 MeV. Empirical equations for the electron reflection ratios and the photon energy-reflection ratio are given (for electrons, graphs only).     

Heterogeneous and homogeneous electrochemiluminoimmunoassays of hTSH at disposable oxide-covered aluminum electrodes

Heterogeneous and homogeneous immunoassays of human thyroid stimulating hormone (hTSH) were developed on immunometric basis using aromatic Tb(III) chelates as electrochemiluminescent labels and varied types of disposable oxide-covered aluminum electrodes as the solid phase of the immunoassays. The long luminescence lifetime of the present labels allows the use of time-resolved electrochemiluminescence detection and provide the low detection limits of these labels and, thus, sensitive immunoassays. The primary antibody of immunometric immunoassays was coated upon aluminum oxide surface by physical absorption. In homogeneous immunoassays using 66 μl cell and 15 min incubation time, a linear calibration range of 0.25-324 μU/ml was obtained by applying only a single cathodic excitation pulse in the detection step of the assay.     

Anodic behavior of nickel-based alloys in the electrolytic production of NF3

The Ni-based alloys, such as Ni-Co, Ni-Mn, Ni-Ag, Ni-Cu, Ni-Al and Ni-Si, prepared by hot isostatic pressing (HIP) at 1000 °C under 2 × 10⁸ Pa for 2 h were employed as the anodes for electrolytic production of NF₃. The current efficiencies for NF₃ formation were 42-38, 52-40, 52-47, 63-62, 50 and 41% for Ni-Co, Ni-Mn, Ni-Ag, Ni-Cu, Ni-Al and Ni-Si alloys, respectively. The current efficiencies only on Ni-Cu alloys with Cu concentrations lower than 10 mol% were almost the same as those on Ni sheet and HIPed Ni anodes, whereas those on the other alloys used in this study were smaller compared with those on both Ni anodes. On the other hand, the current losses caused by anodic dissolution of Ni-Co, Ni-Mn, Ni-Ag, Ni-Cu, Ni-Al and Ni-Si alloy electrodes were 7.95-4.42, 6.40-7.02, 5.60-6.30, 3.34-6.33, 5.10 and 0.18%, respectively. The anode consumptions of Ni-5 mol% Cu and Ni-5 mol% Si alloys were almost the same or smaller compared with those of Ni sheet and HIPed Ni electrodes, though those of other alloys used were large compared with those of both Ni anodes. Consequently, addition of Cu to the nickel matrix is available for a cheaper cost of anode with keeping a same current efficiency as that on the Ni anode and addition of Si to the nickel matrix is effective for decreasing anode consumption largely. A Ni sheet electrode containing a trace of impurities, such as Co, Mn, Ag and Al, is also favorable as the anode for electrolytic production of NF₃.     

一种确定氧化数的新方法

氧化数是元素的重要性质,在无机化学中应用广泛。长期以来,确定元素氧化数主要根据桐山良一和鲍林等建立的规则,这些规则对于氧化数概念在化学中的推广普及起了很大的作用,但在遇到结构复杂或未知化合物时有时仍然会出现问题。本文根据IUPAC的氧化数定义提出,氧化数完全取决于成键两原子之间的电子供需关系,元素的最高正氧化数受到其原子价层电子数的限制,而元素的最低负氧化数受到同周期稀有气体元素外层电子数与其价层电子数差值的限制,据此建立了确定元素氧化数的新方法,该方法既不需要考虑分子结构,也不依赖元素氧化数的习惯规定,符合氧化数概念提出的初衷,简便易行,例外情况少,不仅适合大学化学教学,也适合中学化学教学。