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Mohanad A. Hussein Dr. Uyen P. N. Tran Dr. Vien T. Huynh Dr. Junming Ho Dr. Mohan Bhadbhade Prof. Dr. Herbert Mayr Dr. Thanh V. Nguyen 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(4):1471-1475
Tropylium bromide undergoes noncatalyzed, regioselective additions to a large variety of Michael acceptors. In this way, acrylic esters are converted into β-bromo-α-cycloheptatrienylpropionic esters. The reactions are interpreted as nucleophilic attack of bromide ions at the electron-deficient olefins and the approach of the tropylium ion to the incipient carbanion. Quantum chemical calculations were performed to elucidate the analogy to the amine- or phosphine-catalyzed Rauhut–Currier reactions. Subsequent synthetic transformations of the bromo-cycloheptatrienylated adducts are reported. 相似文献
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《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(26):7562-7567
Nonaqueous redox‐flow batteries are an emerging energy storage technology for grid storage systems, but the development of anolytes has lagged far behind that of catholytes due to the major limitations of the redox species, which exhibit relatively low solubility and inadequate redox potentials. Herein, an aluminum‐based deep‐eutectic‐solvent is investigated as an anolyte for redox‐flow batteries. The aluminum‐based deep‐eutectic solvent demonstrated a significantly enhanced concentration of circa 3.2 m in the anolyte and a relatively low redox potential of 2.2 V vs. Li+/Li. The electrochemical measurements highlight that a reversible volumetric capacity of 145 Ah L−1 and an energy density of 189 Wh L−1 or 165 Wh kg−1 have been achieved when coupled with a I3−/I− catholyte. The prototype cell has also been extended to the use of a Br2‐based catholyte, exhibiting a higher cell voltage with a theoretical energy density of over 200 Wh L−1. The synergy of highly abundant, dendrite‐free, multi‐electron‐reaction aluminum anodes and environmentally benign deep‐eutectic‐solvent anolytes reveals great potential towards cost‐effective, sustainable redox‐flow batteries. 相似文献
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