排序方式: 共有1条查询结果,搜索用时 0 毫秒
1
1.
Xuan Leng Thanh Nhut Do Parveen Akhtar Hoang Long Nguyen Petar H. Lambrev Howe‐Siang Tan 《化学:亚洲杂志》2020,15(13):1996-2004
We simulated two‐dimensional electronic spectra (2DES) of the chlorophyll a manifold of light‐harvesting complex II (LHCII) at various temperatures (77, 110, 150, 190, 230, 273, and 293 K) using the hierarchical equations of the motion‐phase matching approach. We confirm the main excitation energy transfer pathways assignments within the chlorophyll a manifold of LHCII measured in a recent work (J. Phys. Chem. B 2019, 123, 6765–6775). The calculated transfer rates are also in general agreement with the measured rates. We also provided theoretical confirmation for the experimental assignments, as uphill and downhill energy transfer processes, of 2D spectral features that were reported in recent experimental reports. These temperature‐dependent features were also ascertained to follow the detailed‐balance principle. 相似文献
1