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Francesco Minisci Ombretta Porta Cristian Gambarotti Gian Franco Pedulli 《Tetrahedron letters》2004,45(8):1607-1609
Reactions of alkanes with different halogenating systems are compared in order to explore the reactivity of phthalimido-N-oxyl radical in hydrogen abstraction; the importance of polar effects is emphasised. 相似文献
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René T. Boeré Lai-Yoong Goh Chwee Ying Ang Hiu Fung Lau Tracey L. Roemmele 《Journal of organometallic chemistry》2007,692(13):2697-2704
A rational synthesis for 5-tert-butyl-3-cyano-1-(1,2,3,5-dithiadiazolyl)benzene, which was first observed from thermal cleavage of the bis-dithiadiazolyl, has been developed. Voltammetry and electron paramagnetic resonance (EPR) spectra for this radical are reported and its X-ray structure is described. Despite the bulky tBu substituent, the cyano supramolecular synthon is still able to maintain links to a single neighbouring sulfur atom of the S2 unit, as previously observed in cyano-substituted dithiadiazolyls. In the η2 complex with CpCr(CO)2, no such interactions are observed; the nitrile group forms a centrosymmetric dimer through weak contacts with the para H atom on the aryl ring of the partner molecule. This behaviour is contrasted to similar complexes of less bulky dithiadiazolyls, where intermolecular interactions are retained in the crystalline lattice. 相似文献
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