排序方式: 共有41条查询结果,搜索用时 15 毫秒
1.
Alexander Apelblat Emanuel Manzurola Zoya Orekhova 《Journal of solution chemistry》2006,35(6):879-888
Conductivity measurements in dilute aqueous solutions of L-ascorbic acid, sodium-L-ascorbate, magnesium-L-ascorbate, calcium-L-ascorbate and ferrous-L-ascorbate were performed in the (288.15 to 323.15) K temperature range. The limiting molar conductances of the ascorbic anion, λ∘(HAsc−, T), and the dissociation constants of ascorbic acid, K(T), were derived by the use of the Debye-Hückel equation for the activity coefficients and the Onsager and Quint and Viallard conductivity equations. 相似文献
2.
提出了一种铁矿粉热加工生产工艺中亚铁含量测定的新方法。在氮气保护下,用盐酸溶出样中的亚铁,在硫磷混酸介质中以重铬酸钾标准溶液滴定,并对溶样条件进行了研究。该方法简单、快速、准确,已成功地应用于氧化催化法生产氧化铁中亚铁的控制分析和成品鉴定。 相似文献
3.
Utilization of ferric chelate complex of trans-1,2-cyclohexanediaminetetraacetic acid (CDTA) for the oxidative scrubbing of H2S and CH3SH in Kraft mill streams can be beneficial from the standpoints of iron protection against precipitation and oxygen-mediated regenerative oxidation of the ferrous chelate CDTA. The physical solubility of methyl mercaptan in CDTA–Fe(III) complex cannot be measured directly because of oxidation of the sulfur-bearing gaseous species with the ferric chelate. Therefore, this investigation was carried out to determine the gas–liquid partition coefficients and Henry's law constants of methyl mercaptan in aqueous iron-free CDTA solutions and non-reacting ferrous chelate solutions (CDTA–Fe(II) complex), using the static headspace method with an estimated accuracy of about 2%. Experiments with aqueous solutions of chelate concentrations varying between 38 and 300 mol m−3 were carried out at temperatures between 298 and 333 K and atmospheric pressure. It was shown that the methyl mercaptan solubility decreases with increasing temperature for all systems but was not much influenced, in the studied conditions, by the chelate concentration especially at larger temperatures. 相似文献
4.
采用自动电位滴定法标定硫酸铈溶液,并进行硫酸亚铁片中铁含量的测定。自动电位滴定法以电位突跃监测终点,在45℃~50℃之间,以草酸钠溶液标定硫酸铈溶液,测定值的相对标准偏差(n=5)为0.070%。取硫酸亚铁片1片用0.01mol·L-1硫酸溶液30mL溶解,直接用硫酸铈溶液滴定测定铁含量。方法用于硫酸亚铁片样品分析,回收率为100%,测定值的相对标准偏差(n=5)在1.2%~2.6%之间。 相似文献
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We used the isotope selectivity of 57Fe Mössbauer spectroscopy to investigate changes in the magnetic properties of polycrystalline hematite exposed to ferrous iron (Fe(II)). We found that sorption of 56Fe(II), followed by interfacial electron exchange, alters the bulk magnetic properties of 57hematite. After reaction with 56Fe(II), we observed partial suppression of the Morin transition of 57hematite to below 13 K. This is significantly lower than the Morin temperature (T M) of ~230 K measured for isotopically enriched polycrystalline 57hematite, as well as the T M of 264?±?2 K reported for normal polycrystalline hematite. 相似文献
7.
酒石酸亚铁分光光度法测定茶多酚 总被引:35,自引:0,他引:35
采用没食子酸丙酯为基准物质酒石酸亚铁作为显色剂,光度法测定茶多酚制品中茶多酚的含量。最大吸收波长540nm摩尔吸光系数2.65×10^3回收率为98%-101%,相对标准偏差为0.90%。方法简便,结果令人满意。 相似文献
8.
Koji Kano 《Colloid and polymer science》2008,286(1):79-84
This mini-review reports supramolecular system composed of O-methylated β-cyclodextrins and metalloporphyrins that mimic the
functions of myoglobin (Mb) in aqueous solution. Although many Mb functional models have been demonstrated so far, most models
can bind dioxygen only in organic solvents such as toluene. Recently, we prepared the model systems composed of O-methylated
β-cyclodextrin dimers having pyridine and imidazole linkers and tetrakis(4-sulfonatophenyl)porphinato iron(II) (hemoCD and
Fe(II)PImCD). HemoCD binds dioxygen reversibly in aqueous solution, and the dioxygen adduct of hemoCD is very stable (a half-lifetime
is 30 h at pH 7). Although the dioxygen affinity of Fe(II)PImCD is much higher than hemoCD, the stability and the reversibility
of this system is lower. This review compares the functions of these model systems with those in biological systems.
This review was written to dedicate to Professor Janos H. Fendler on the occasion of his 70th birthday. He gave me a chance
to study biomimetic chemistry when he was a professor of Texas A&M University. 相似文献
9.
8-羟基喹啉化学修饰壳聚糖亚铁配合物的合成及结构表征 总被引:4,自引:0,他引:4
为了利用高分子壳聚糖的生物特性降低药物的毒副作用,寻找理想的高分子药物载体,增加药物的生物特性,本文以高分子壳聚糖为载体,以8-羟基喹啉对其进行共价修饰,合成了喹啉类抗疟杀菌药的高分子药物前体,为增加其活性,与亚铁配位,合成了壳聚糖-8-羟基喹啉-亚铁配合物,用元素分析、TG-DTA分析、IR光谱、UV光谱和荧光光谱等研究了配合物的性质,并优化了配合物合成条件.结果表明,CTS-HQ对Fe2+离子的吸附等温线符合Langmuir吸附等温线方程,在室温下,pH=4时吸附8h的饱和吸附量Qmax=86.96mg/g,K=1.474J/mg. 相似文献
10.
乳酸亚铁中总铁的溶样及比色测定 总被引:2,自引:0,他引:2
本文研究在HNO3-HCl体系乳酸亚铁中的Fe^2+会被氧化成Fe^3+,用碘基水杨酸比色法就能准确测定总铁量,回收率在98%-100%,相对标准偏差为1.14%,摩尔吸光系数为5.6×10^4L.mol^-1.cm^-1,含铁量在0-700μg/100mL范围内符合比耳定律。 相似文献