全文获取类型
收费全文 | 502篇 |
免费 | 101篇 |
国内免费 | 81篇 |
专业分类
化学 | 401篇 |
晶体学 | 22篇 |
力学 | 22篇 |
综合类 | 13篇 |
数学 | 87篇 |
物理学 | 139篇 |
出版年
2023年 | 1篇 |
2022年 | 6篇 |
2021年 | 7篇 |
2020年 | 5篇 |
2019年 | 28篇 |
2018年 | 19篇 |
2017年 | 25篇 |
2016年 | 25篇 |
2015年 | 36篇 |
2014年 | 35篇 |
2013年 | 52篇 |
2012年 | 35篇 |
2011年 | 37篇 |
2010年 | 43篇 |
2009年 | 25篇 |
2008年 | 35篇 |
2007年 | 20篇 |
2006年 | 28篇 |
2005年 | 30篇 |
2004年 | 20篇 |
2003年 | 20篇 |
2002年 | 27篇 |
2001年 | 25篇 |
2000年 | 29篇 |
1999年 | 20篇 |
1998年 | 18篇 |
1997年 | 12篇 |
1996年 | 8篇 |
1995年 | 4篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1990年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 2篇 |
排序方式: 共有684条查询结果,搜索用时 15 毫秒
1.
2.
3.
Toshihiro Kobayashi 《Mathematical Methods in the Applied Sciences》2004,27(18):2171-2184
In this paper low‐gain adaptive stabilization of undamped semilinear second‐order hyperbolic systems is considered in the case where the input and output operators are collocated. The linearized systems have an infinite number of poles and zeros on the imaginary axis. The adaptive stabilizer is constructed by a low‐gain adaptive velocity feedback. The closed‐loop system is governed by a non‐linear evolution equation. First, the well‐posedness of the closed‐loop system is shown. Next, an energy‐like function and a multiplier function are introduced and the exponential stability of the closed‐loop system is analysed. Some examples are given to illustrate the theory. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
4.
5.
基于阿贝尔黑格斯变量的杨-米尔斯理论的红外阿贝尔化 总被引:1,自引:0,他引:1
通过SU(2)规范场的法捷耶夫-Niemi分解给出了有效阿贝尔-黑格斯型作用量的
一个计算方法. 具体指出了该分解中所用的自然规范固定以及阿贝尔投射与杨-米尔斯理论的红外动力学之间的内在关系. 推导出了色电场的一个伦敦型方程. 相似文献
6.
I. Capek J. Chudej S. Janí
kov 《Journal of polymer science. Part A, Polymer chemistry》2003,41(6):804-820
The sterically stabilized emulsion polymerization of styrene initiated by a water‐soluble initiator at different temperatures has been investigated. The rate of polymerization (Rp) versus conversion curve shows the two non‐stationary‐rate intervals typical for the polymerization proceeding under non‐stationary‐state conditions. The shape of the Rp versus conversion curve results from two opposite effects—the increased number of particles and the decreased monomer concentration at reaction loci as the polymerization advances. At elevated temperatures the monomer emulsion equilibrates to a two‐phase or three‐phase system. The upper phase is transparent (monomer), and the lower one is blue colored, typical for microemulsion. After stirring such a multiphase system and initiation of polymerization, the initial coarse polymer emulsion was formed. The average size of monomer/polymer particles strongly decreased up to about 40% conversion and then leveled off. The initial large particles are assumed to be highly monomer‐swollen particles formed by the heteroagglomeration of unstable polymer particles and monomer droplets. The size of the “highly monomer” swollen particles continuously decreases with conversion, and they merge with the growing particles at about 40–50% conversion. The monomer droplets and/or large highly monomer‐swollen polymer particles also serve as a reservoir of monomer and emulsifier. The continuous release of nonionic (hydrophobic) emulsifier from the monomer phase increases the colloidal stability of primary particles and the number of polymer particles, that is, the particle nucleation is shifted to the higher conversion region. Variations of the square and cube of the mean droplet radius with aging time indicate that neither the coalescence nor the Ostwald ripening is the main driving force for the droplet instability. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 804–820, 2003 相似文献
7.
张昌斌 《纯粹数学与应用数学》1998,14(3):21-24,71
借助于文(1)中的结论研究了仿紧集上的拟-似变分不等式,统一和发展了文(2-6)中的相应结果。 相似文献
8.
由原位缩聚制备了刚性高分子聚酰亚胺(PI)和柔性基体聚N-乙烯吡咯烷附(PVP)的分子复合物,并由实验证明了中间体聚酰胺酸(PA)和聚乙烯吡咯烷酮大分子之间存在的酸一碱相互作用.这种相互作用促进了混容性,使聚酰亚胺能以分子水平或接近分子水平分散在聚毗咯烷酮的基体之中.聚酰亚胺/聚N-乙烯吡咯烷团分子复合物的薄膜呈透明性,在整个组成范围内只有一个Tg,显示单相行为。当PI含量<20%时,SEM相片呈现均相形貌,看不到PI微晶.广角X-ray衍射图表明PI特征结晶峰消失,和无定形的PVP完全混容.当PI含量>40%,SEM显示有均匀分布的、棒状PI微晶存在.通过分子复合,即使PI含量为10%,聚N-乙烯吡咯烷酮不再溶于乙醇,耐热性也有提高. 相似文献
9.
洋葱状富勒烯的提纯研究 总被引:1,自引:0,他引:1
以石墨粉为碳源, Al为催化剂, 采用真空热处理法制备了平均粒径为15~35 nm的洋葱状富勒烯(OLFs).并用CS2分离和空气氧化法对得到的OLFs初产品进行了提纯处理.高分辨透射电镜(HRTEM)、X射线衍射(XRD)、热重分析(TGA)对提纯前后样品的分析表明, CS2分离处理可有效去除初产品中裸露的金属催化剂微粒,然后在空气中610 ℃焙烧200 min,可基本去除无定型碳,并大量去除了石墨状碎片等碳杂质, OLFs的纯度在50%(体积分数)以上. 相似文献
10.
With the introduction of the concept of the iso‐spectrum‐level series, a linear relationship is found between the first differences of the ionization potential of excited states and nuclear charge Z along an iso‐spectrum‐level series, and the ionization potential of excited states of Be‐like sequence are studied systematically on the basis of the weakest bound electron potential model theory. The expression of nonrelativistic ionization potential is derived from the weakest bound electron potential model theory, and relativistic effects are included by using a fourth‐order polynomial in Z. As a demonstration, the ionization potentials of [He]2s2p 3P, [He]2s3s 1S0, [He]2s3p 1P, [He]2s3d 1D2, and [He]2s4d 1D2 series for a range of Be‐like sequence from Z = 4–23 are calculated. The results are compared with the experimental data and the recent sophisticated ab initio results. © 2003 Wiley Periodicals, Inc. Int J Quantum Chem 93: 344–350, 2003 相似文献