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排序方式: 共有1007条查询结果,搜索用时 31 毫秒
1.
2.
Li Yingle Huang Jiying Gong Shuohong 《International Journal of Infrared and Millimeter Waves》2003,24(6):953-961
The dielectric constant for rain medium is investigated by utilizing the system identification method. The rain rate model and frequency model of permittivity in millimeter waves band for rain medium are presented. The results obtained with models are in very good agreement with references in calculating the attenuation of electromagnetic waves induced by rain, which Shows that the obtained models are valid and practicable. The cross-polar discrimination gotten with rain rate model is in agreement with references. 相似文献
3.
Zhaohui Wang 《Thermochimica Acta》2004,414(1):31-33
Microcalorimetric measurements of excess molar enthalpies, at 298.15 K, are reported for the four binary systems formed by mixing 1-hexene with the cycloalkanes: cyclohexane and methylcyclohexane, and with the aromatic hydrocarcons: benzene and toluene. Smooth Redlich-Kister representations of the results are presented. It was found that the Liebermann-Fried model also provided good representations of the results. 相似文献
4.
J. M. Pico C. P. Menaut J. Fernández J. L. Legido M. I. Paz Andrade 《Journal of solution chemistry》1991,20(1):115-124
Excess molar enthalpies hE at 25 and 35° C and atmospheric pressure, are reported for the binary mixtures formed by a 2-butanone and 2-pentanone with 1-chlorobutane, 1-chloropentane, 1-chlorohexane, or 1-chlorooctane. The hE values for all the mixtures are positive, increasing as the 1-chloroalkane length increases and as the ketone length decreases. Excess molar enthalpies depend slightly on the temperature. The experimental values together with those from the literature were used to calculate the interaction parameters for the Dang-Tassios version of the UNIFAC model.Communicated at the Festsymposium celebrating Dr. Henry V. Kehiaian's 60th birthday, Clermont-Ferrand, France, 17–18 May 1990. 相似文献
5.
We study theoretically a nonlinear response of the planar metal/dielectric nanostructures constituted from periodical array
of ultra thin silver layers and the layers of Kerr-like nonlinear dielectric. We predict hysteresis-type dependences of the
components of the tensor of effective dielectric permittivity on the field intensity allowing the change in material transmission
properties from transparent to opaque and back at extremely low intensities of the light. It makes possible to control the
light by light in all-optical nanoscale devices and circuits. 相似文献
6.
7.
正已醇-邻、间、对二甲苯二元系固液相平衡 总被引:1,自引:0,他引:1
Melting temperatures have been measured and the solid-liquid phase diagrams constructed for 1-hexanol+o-xylene, 1-hexanol+m-xylene and 1-hexanol+p-xylene. They are simple eutectic systems. Excess mole Gibbs free energies were calculated at 298.15K, showing larger positive deviations from ideal-solution behavior. The largest values of GmE are 711、 650 and 800 J•mol-1 for {o-C6H4(CH3)2+C6H13OH}、 {m-C6H4(CH3)2 + C6H13OH} and {p-C6H4(CH3)2+C6H13OH} respectively. 相似文献
8.
Excess volumes V
E
of binary liquid mixtures of quinoline with alkanols have been determined from densities at 30°C as a function of composition. The excess volumes are negative over the whole mole fraction range for all the mixtures and decrease with increasing length of alkanol (C1–C10). The VE data have been analyzed in terms of an approach which uses graph theoretical connectivity parameters of the third degrees for two components. The analysis gives information regarding associated species in the pure state and in the mixture. It is suggested that, in the mixture state, no change occurs in the association of alkanols. 相似文献
9.
Solutions of 1-hexanol and 1,2-hexanediol in heptane have been investigated tigated by means of dielectric time domain spectroscopy (TDS). The permittivity spectrum of 1-hexanol in heptane is characterized by a model function containing a sum of three elementary Debye dispersions, while 1,2-hexanediol in heptane is best described by a Cole-Davidson model function. It is shown that dilute solutions of 1-hexanol in heptane have a completely different behavior to that of 1,2-hexanediol. For the diol, the relaxation time levels off at a high value indicating an existence of higher hydrogen bonded complexes. It is possible to quantify the relative amount of monomeric 1-alcohol molecules from the dielectric spectrum. The monomerization rate for 1-hexanol upon dilution with heptane is initially low, but increases rapidly for mole fractions of heptane exceeding 0.4. 相似文献
10.
Solubility behaviors of binary mixtures of CFCl3 (R-11), CFCl2-CF2Cl (R-113), CHCl3 (R-20), CDCl3 (R-20-d), CHCl2–CF3 (R-123) with room-temperature ionic liquid [bmim][PF6] (1-butyl-3-methylimidazolium hexafluorophosphate) have been investigated using the volumetric and cloud-point methods, since all the systems show liquid–liquid equilibria (LLE). Large immiscibility (LLE) gaps of the perhalogenated compounds (R-11 and R-113) in the ionic liquid have been drastically reduced by the addition of only one hydrogen (or deuterium) in these compounds. The R-123 + [bmim][PF6] binary system belongs to the Type-V fluid behavior. Noticeably large negative values (−2 to −8 cm3 mol−1) of the excess molar volume in the ionic liquid-rich side solution have been observed for all the present systems. Experimental LLE data have been well correlated by the use of the NRTL (non-random two liquid) activity coefficient model. 相似文献