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The antibiotic, flambamycin, is shown to have the novel oligosaccharide structure (1) associated with two orthoester linkages. It is proposed that flambamycin (1), the everninomicins (28), curamycin, avilamycin, destomycin A (29a), destomycin C (29b), destomycin B (30), hygromycin B (29c), the antibiotics A-396-I (29d) and SS-56C (29e), belong to a new family of antibiotics called the orthosomycins. 相似文献
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Christopher A. Ramsden 《Tetrahedron》1977,33(24):3193-3202
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