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《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(30):8944-8948
Aromatic‐imide‐based thermally activated delayed fluorescence (TADF) materials with a twisted donor–acceptor–donor skeleton were efficiently synthesized and exhibited excellent thermal stability and high photoluminescence quantum yields. The small ΔE ST value (<0.1 eV) along with the clear temperature‐dependent delayed component of their transient photoluminescence (PL) spectra demonstrated their excellent TADF properties. Moreover, the performance of organic light‐emitting diodes in which TADF materials AI‐Cz and AI‐TBCz were used as dopants were outstanding, with external quantum efficiencies up to 23.2 and 21.1 %, respectively. 相似文献
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Dr. Meng Li Yin-Feng Wang Dr. Dongdong Zhang Prof. Dr. Lian Duan Prof. Dr. Chuan-Feng Chen 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(9):3528-3532
The use of a chiral, emitting skeleton for axially chiral enantiomers showing activity in thermally activated delayed fluorescence (TADF) with circularly polarized electroluminescence (CPEL) is proposed. A pair of chiral stable enantiomers, (−)-(S)-Cz-Ax-CN and (+)-(R)-Cz-Ax-CN, was designed and synthesized. The enantiomers, both exhibiting intramolecular π-conjugated charge transfer (CT) and spatial CT, show TADF activities with a small singlet–triplet energy difference (ΔEST) of 0.029 eV and mirror-image circularly polarized luminescence (CPL) activities with large glum values. Notably, CP-OLEDs based on the enantiomers feature blue electroluminescence centered at 468 nm with external quantum efficiencies (EQEs) of 12.5 and 12.7 %, and also show intense CPEL with gEL values of −1.2×10−2 and +1.4×10−2, respectively. These are the first CP-OLEDs based on TADF-active enantiomers with efficient blue CPEL. 相似文献
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