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Franz A. Mautner Harald Krischner Christoph Kratky 《Monatshefte für Chemie / Chemical Monthly》1988,119(8-9):921-927
Single crystals of Ca(N3)2·2 H2O have been prepared from aqueous solutions at room temperature. The crystals are monoclinic,a=1 159.0 (3),b=614.2 (2),c=785.5 (2) pm, =106.52 (2)°,Z=4, space group P21/n. The crystal structure was determined by single crystal X-ray diffraction (1 109 Mo-K-reflexions,R=0.052). Calcium atoms are surrounded by four azide groups and four water molecules. The coordination polyhedra are antiprism which are sharing azide groups and water molecules to form layers. The lattice constants and powder pattern agree well with values reported earlier for Ca(N3)2 · 1.5 H2O [1]. It was also shown, that Sr(N3)2 · 2 H2O is isotypic with Ca(N3)2 · 2 H2O. 相似文献
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Introduction4-Mercaptopyridine(4MPY)has been always em-ployed as a model molecule and a probe molecule forRaman spectra in many studies because of its specialstructure with two active groups and its excellent signalin a Raman spectrum.Therefore,4MPY has b… 相似文献
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A. Jesih K. Lutar B.
emva B. Bachmann St. Becker B. G. Müller R. Hoppe 《无机化学与普通化学杂志》1990,588(1):77-83
Single Crystal Investigation on AgF2 For the first time single crystals of AgF2 (black, metalic bright) have been obtained by heating AgF2 powder under a mixture of HF and F2 in autoclaves at 400°C. It crystallizes orthorhombic in the space group Pbca – D (Nr. 61) – with a = 556.8(1), b = 583.1(1) and c = 510.1(1) pm; Z = 4. The Madelung Part of Lattice Energy, MAPLE, and the Effective Coordination Number, ECoN, via the Mean Fictive Ionic Radii, MEFIR, are calculated and discussed. 相似文献
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Reaction of Rhenium(VII) Oxide with 1,4-Dioxane – Crystal Structure of Re2O7(OH2)2 · 2(1,4-Dioxane) By solvolysis of polymeric Re2O7 with 1,4-dioxane in the presence of small amounts of H2O two products of compositions Re2O6(OH)2 · 3(1,4-dioxane) ( 1 ) and Re2O7 · 2H2O · 2(1,4-dioxane) ( 2 ) are formed. From a complete X-ray single-crystal structure analysis 2 could now be characterized structurally (monoclinic, space group P21/c, a = 6.828(3) Å, b = 9.530(2) Å, c = 26.421(8) Å, β = 91.71(3)°, Z = 4). The compound is important as a convenient precursor for the preparation of pure rhenium trioxide. It is to be formulated as Re2O7(OH2)2 · 2(1,4-dioxane) and contains, contrary to 1 , no 1,4-dioxane coordinated to Re. The crystalline phase consists of a supramolecular arrangement of Re2O7(OH2)2 units as in “solid perrhenic acid” and of 1,4-dioxane molecules associated through O? H …? O hydrogen bridges. Analogous to dirhenium heptoxide and to solid perrhenic acid one of the rhenium atoms is in tetrahedral, the other is in distorted octahedral coordination. 相似文献
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BiBi Fatemeh Mirjalili Mohamad Ali Zolfigol Abdolhamid Bamoniri Amin Zarei 《Phosphorus, sulfur, and silicon and the related elements》2013,188(8):1845-1849
A combination of silica sulfuric acid and sodium dichromate dihydrate in the presence of wet SiO 2 were used as an effective oxidizing agent for the oxidation of alcohols to their corresponding aldehyde or ketone derivatives in dichloromethane or toluene with excellent yields. 相似文献
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