Raman bandshape analysis and DFT study of CO and CH stretching modes of NN-Dibutyl formamide in DMSO solvent`

The study reports the inter-molecular interactions and dynamics of CO and CH stretching modes of NN- Dibutyl Formamide (DBF) in DMSO solvent using Raman spectroscopic technique. The Raman band of CO and CH stretching modes have been deconvoluted into two distinct bands for neat as well as in DMSO solvent. Peak wavenumbers of CO stretching modes show red shift while CH stretching modes shows blue shift with the increase in solvent concentrations. The optimized geometric parameters, vibrational wavenumbers, Mulliken atomic charges and natural bond orbitals of the molecule has been computed using Density Functional Theory (DFT) method with basis set 6-31 +G (d, p). In addition, the same basis set has been carried out with counterpoise keyword accounting BSSE calculation on monomer and dimer states with DMSO solvent to present an appropriate interacting environment. IEF-PCM solvation model has also been computed using the same basis set and compares the geometrical parameters and vibrational wavenumbers of the molecules and in their complexes. In order to get a complete study of the DBF + DMSO complexes, explicit solvation model has also been calculated for Monomer DBF in two solvent molecules. Theoretical calculations of frequencies have been compared with the experimental findings and the results are found in good agreement.     

基于FPGA的DBF多波束中频接收系统的设计与实现

数字波束形成(DBF)阵列能够充分利用阵列天线所获取的空间信息,通过信号处理技术使波束获得超分辨率和低旁瓣的性能,它由天线阵元、射频下变频模块、AD采样、中频接收系统及上位机控制器组成。对中频接收系统进行数字波束形成的具体方案进行讨论,对多路接收和AD量化一致性造成的各通道间失配提出了幅相校正的解决方案,详细分析了研制中的关键技术。实验结果表明所设计的DBF多波束中频接收系统可有效实现通道间失配的校正,并实现精确的波束赋形功能。     

新显色剂偶氮胂DBF分光光度法测定稀土元素研究

变色酸双偶氮胂类化合物是光度法测定稀土元素的重要显色剂,如偶氮胂Ⅲ、三溴偶氮胂等。为研究各种取代基对这类显色剂与稀土配合物的影响,将对甲基二溴偶氮胂中的甲基换为甲酰基,合成得偶氮胂DBF,化学命名为2-(2-胂酸基苯偶氮)-7-(2,6二溴-4-甲酰基苯偶氮)-1,8-二羟基萘-3,6-二磺酸。