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A concise, unified and stereoselective total synthesis of (+)-gabosine C and (+)-4-epi-gabosine J from a common polyhydroxylated cyclohexenol intermediate which was synthesized from readily available D-ribose has been described. The synthetic avenue includes stereoselective Grignard reaction, silyl ether deprotection followed by acetate migration, RCM reaction, oxidative diol cleavage, hydroxymethylation and oxidative rearrangement as key steps. 相似文献
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葡萄糖发酵液D-核糖含量的高效液相色谱分析 总被引:3,自引:0,他引:3
D-核糖在生命科学研究领域十分重要,在医药、食品、饲料等工业部门广泛应用,近年来,D-核糖可通过D-葡萄糖在莽草酸营养缺陷型突变株菌种^[1]存在下,经发酵制得,目前国内葡萄糖发酵液中该糖含量分析仍采用苔黑酚光度法,此法没有对发酵液中种种上糖类化合物预先分离,选择性差,得到的是各种糖经合物总含量分析结果,糖类化合物测定的高效液相色谱法有衍生法[2] ,但比较繁琐,近年RI检测器应用于糖类分析日益增多[3,4],但用于葡萄糖发酵液中D-核糖分析尚未见报道,本文采用高效液相色谱法分析葡萄糖发酵液D-核糖含量,并获得良好结果。 相似文献
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Effect of polypyridine derivatives on chromium(VI) oxidation of D-ribose in aqueous media was studied spectrophotometrically. The oxidized product D-erythrose was detected by paper chromatography. The promoters 1,10-phenanthroline, 2,2?-bipyridine, 2-picolinic acid, and 2,3-dipicolinic acid accelerated the oxidation, whereas isomeric 4,7-phenanthroline, 4,4?-bipyridine, 4-picolinic acid, and 2,6-dipicolinic acid did not influence the oxidation. Formation of Cr(VI)-promoter complex was identified through fluorescence spectroscopy. Rate constants depended on promoter concentration. SDS and TX-100 enhanced the D-ribose oxidation, while CPC retarded the reaction. Location of D-ribose inside micelles was observed through 1H NMR. DLS study showed that the relative size of SDS and TX-100 micelles expanded in presence of chromium(VI). 相似文献
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ZHENG Changcheng GUO Xianzhi DENG Guocai YANG Sihai CHEN Rongti 《Chinese Journal of Reactive Polymers》1999,(Z1)
1INTRODUCTIONWriboseisimPObotfortheactivitiesoflivingorganismsandcanbewidelyusedinpharmaceutical,foodandforageindustriesll.ZI.Itcanbeproducedbyfermentationofglucosewiththesubnutritionalmutantstrainoftheilliciumoill3.41.ruribosedemoticfluidhasacidicproperty,itScolorisdarkreddish.Itcontainsphosphateion,chlorideionandalittlequantityofsulfateionandoxalateion.Potassiumionandalittlequantityofsodion,calciumionandmagnesiumioncanalsobefound.Becauseofplentyofimpuritiesinthefluidandthedarkcoloroft… 相似文献
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