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D. Behera T. Mohanty S. K. Dash T. Banerjee D. Kanjilal N. C. Mishra 《Radiation measurements》2003,36(1-6):125-129
Swift heavy ions (SHI) with electronic energy loss exceeding a value of 14.4 keVnm−1 create amorphized latent tracks in YBCO type superconductors. In the low fluence regime of an ion beam where tracks do not overlap, a decrease of the superconducting transition temperature as probed through resistivity studies, is not expected due to availability of percolating current paths. The present study however shows Tc decrease by about 1–3 K in thin films of YBCO when irradiated by 250 MeVAg ions at 79 K at a fluence of 5×1010–1×1012 ionscm−2. The highest fluence used in the present study is three times less than the fluence where track overlapping becomes significant. The Tc tends to increase towards the preirradiation value on annealing the films at room temperature. To explain this unusual result, we consider the effect of ion irradiation in inducing materials modification not only through creation of amorphized latent tracks along the ion path, but also through creation of atomic disorder in the oxygen sublattice in the Cu–O chains of YBCO by the secondary electrons. These electrons are emitted radially from the tracks during the passage of the SHI. Considering the correlation between the charge state of copper and its oxygen coordination, we show in particular that the latter process is a consequence of the inelastic interaction of the SHI induced low-energy secondary electrons with the YBCO lattice, which result in chain oxygen disorder and Tc decrease. 相似文献
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Reaction of gem-difluorinated vinyloxiranes with RCu(X)Li allowed us to introduce the R group regioselectively at the fluorine-attached terminal carbon atom in an SN2′ manner to afford (E)-allylic alcohols exclusively, while homoallylic alcohols with anti stereochemical relationship were found to be obtained selectively from higher-ordered cuprates derived from CuCl and RMgBr in a ratio of 1:3. 相似文献
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J.V. Acrivos 《Microchemical Journal》2005,81(1):98-107
The onset of electro-magnetic optic effects, observed at the Ba L2,3 edges synchrotron X-ray absorption by a YBa2Cu3O7 single crystal, 20 K above the transition temperature to superconductivity, Tc ∼ 92 K is used to identify the role played by the Ba donor layer in the transition to superconductivity in the CuO2 layers. Negative permeability leads to Faraday rotation of the transmitted beam below T = 112 to 56 K for the 22 μm thick single crystal (c-axis orientation of 8π/18 relative to εX-rays) and sharp changes in the density of empty final states lead to zero transmitted radiation in an interval ΔE at the given orientation. The temperature dependence: ΔE(L2) = 1.4, 3.5 and 3.9 eV, while ΔE(L3) = 5.3, 6 and 7 eV at T = 92, 74 and 63 K, respectively, indicates that the width of the empty final states bands increases as T decreases. ΔE(L3)/ΔE(L2) = 3.8 at 92 K to 1.8 at 63 K also indicates that the d5/2 symmetry bands fill faster than those of d3/2 symmetry below Tc, providing the first experimental evidence of unpaired spin-orbit states in the Ba donor layer of a superconductor. These effects, characteristic of ferromagnetic and anti-ferromagnetic materials near a resonance absorption, signal the onset of a Mott transition. The interaction between the layer states is described using 1D conjugate molecular orbitals. 相似文献
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M. M. Korshunov S. G. Ovchinnikov 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,57(3):271-278
In this paper a mean-field theory for the spin-liquid paramagnetic non-superconducting phase of the p- and n-type high-Tc cuprates is developed. This theory applied to the effective t-t'-t′′-J* model with the ab initio calculated parameters and with the three-site correlated hoppings. The static spin-spin and kinematic
correlation functions beyond Hubbard-I approximation are calculated self-consistently. The evolution of the Fermi surface
and band dispersion is obtained for the wide range of doping concentrations x. For p-type systems the three different types
of behavior are found and the transitions between these types are accompanied by the changes in the Fermi surface topology.
Thus a quantum phase transitions take place at x = 0.15 and at x = 0.23.Due to the different Fermi surface topology we found
for n-type cuprates only one quantum critical concentration, x = 0.2. The calculated doping dependence of the nodal Fermi
velocity and the effective mass are in good agreement with the experimental data. 相似文献
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U. Schwingenschlögl C. Schuster 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,55(1):43-47
The incommensurate composite systems M14Cu24O41 (M = Ca, Sr, La)
are based on two fundamental structural units: CuO2 chains and
Cu2O3 ladders. We present electronic structure calculations
within density functional theory in order to address the interrelations
between chains and ladders. The calculations account for the
details of the crystal structure by means of a unit cell comprising 10
chain and 7 ladder units. It turns out that chains and ladders can be treated
independently, which allows us to introduce a model system based on a
reduced unit cell. For the CuO2 chains, we find two characteristic
bands at the Fermi energy. Tight binding fits yield
nearest and next-nearest neighbour interactions of the same order of
magnitude. 相似文献
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Arndt Simon 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》1997,109(17):1873-1891
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P. Ganapati Reddy 《Tetrahedron letters》2005,46(27):4559-4561
An unusual solvent effect in the cuprate displacement reaction of indolizidin-5-yl-methyl p-toluenesulfonate with dialkyl cuprates, derived from an alkyllithium and Grignard reagents, during the synthesis of indolizidine alkaloids 167B and 209D is described. 相似文献