全文获取类型
收费全文 | 979篇 |
免费 | 52篇 |
国内免费 | 133篇 |
专业分类
化学 | 956篇 |
晶体学 | 25篇 |
综合类 | 3篇 |
数学 | 7篇 |
物理学 | 173篇 |
出版年
2023年 | 9篇 |
2022年 | 20篇 |
2021年 | 27篇 |
2020年 | 35篇 |
2019年 | 34篇 |
2018年 | 39篇 |
2017年 | 42篇 |
2016年 | 29篇 |
2015年 | 28篇 |
2014年 | 56篇 |
2013年 | 98篇 |
2012年 | 69篇 |
2011年 | 59篇 |
2010年 | 50篇 |
2009年 | 55篇 |
2008年 | 47篇 |
2007年 | 72篇 |
2006年 | 43篇 |
2005年 | 46篇 |
2004年 | 35篇 |
2003年 | 44篇 |
2002年 | 29篇 |
2001年 | 23篇 |
2000年 | 23篇 |
1999年 | 21篇 |
1998年 | 15篇 |
1997年 | 15篇 |
1996年 | 14篇 |
1995年 | 9篇 |
1994年 | 14篇 |
1993年 | 10篇 |
1992年 | 11篇 |
1991年 | 11篇 |
1990年 | 3篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 5篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1974年 | 1篇 |
1973年 | 2篇 |
排序方式: 共有1164条查询结果,搜索用时 15 毫秒
1.
2.
We study spectral properties of discrete Schrödinger operators with potentials obtained via dimerization of a class of aperiodic sequences. It is shown that both the nature of the autocorrelation measure of a regular sequence and the presence of generic (full probability) singular continuous spectrum in the hull of primitive and palindromic (four block substitution) potentials are robust under dimerization. Generic results also hold for circle potentials. We illustrate these results with numerical studies of the quantum mean square displacement as a function of time. The numerical techniques provide a very fast algorithm for the time evolution of wave packets. 相似文献
3.
Juzo Oyamada 《Tetrahedron》2006,62(29):6918-6925
Synthesis of coumarins from phenols and propiolic acids was examined by using a Pt catalyst such as PtCl2/AgOTf, K2PtCl4/AgOTf, and K2PtCl4/AgOAc. Propiolic acid reacted even with less reactive phenols in trifluoroacetic acid to give coumarins and dihydrocoumarins. In the case of substituted propiolic acids, phenylpropiolic acid and 2-octynoic acid, the reactions proceeded selectively to afford coumarins in good to high yields. 相似文献
4.
G.P. Romanelli D. Bennardi D.M. Ruiz G. Baronetti H.J. Thomas 《Tetrahedron letters》2004,45(48):8935-8939
Substituted coumarins are synthesized from phenols and β-ketoesters by the Pechmann reaction, using a Wells-Dawson heteropolyacid (H6P2W18O62·24H2O) as catalyst by a solvent-free procedure. This one requires low reaction times, 130 °C temperature and as little as 1 mol % of Wells-Dawson acid, obtaining good to excellent yields of coumarins. The catalyst showed to be reusable with no differences in the yields. The results are compared with those of the reactions performed in toluene solution. The presented synthetic procedure is a convenient, clean and fast alternative for synthesizing 4-substituted coumarins (17 examples). 相似文献
5.
Xiao Qi ZHENG Yong Hui WANG Qing Xiang GUO* Li YANG You Cheng LIU Department of Chemistry University of Science Technology of China Hefei National Laboratory of Applied Organic Chemistry Lanzhou University Lanzhou 《中国化学快报》2003,(8)
As artificial enzymes, the binding constants of cyclodextrins (CDs) and their substrates are expected to be high1. For this purpose, many kinds of bridged cyclodextrin dimers2 whose two cyclodextrins are linked by various spacers have been constructed. It was of interest to make the dimers, whose binding constants would exceed 108dm3/mol3. Up to date, the bridged cyclodextrin dimers have been extensively studied as enzyme models and as molecular receptors4-6. Recently, we synthesized a brid… 相似文献
6.
We study the stochastic dynamics of deposition-evaporation cooperative processes of dimers, trimers, etc., in two- and higher-dimensional lattices. The dimer system in bipartite lattices allows for an exact solution of dynamic correlations and scaling functions by means of a quantum spin equivalence. Autocorrelations exhibit a diffusive asymptotic kinetics and crossovers of different dynamic regimes in highly anisotropic lattices. Monte Carlo simulations combined with finite-size scaling arguments support the validity of the diffusive picture in more general situations. Steady-state coverages and diffusion constants are obtained using mean-field approaches, spin wave calculations, and random walk analyses in nearly jammed configurations. 相似文献
7.
针对二聚物三能级蒸气激光系统增益相对于泵浦光方向显著的不对称特性,本文设计了一种稳定的能够充分利用介质增益特性的环形谐振腔,给出了象散和慧差补偿及泵浦激光与谐振腔匹配的条件。文中还给出了Na_2B~1Ⅱ_u-X~1∑_g~+跃迁激光谐振腔设计数据。 相似文献
8.
The thermolysis of dicarbonylcyclopentadienyliron dimer in a sealed tube at 300°C has been reported to produce ferrocene, carbon monoxide, carbon dioxide, cyclopentadiene and elemental iron. We observe in addition to these products the production of biferrocene and elemental carbon. Thermolysis of carbonylcyclopentadienyliron tetramer (produced from the dimer by thermolysis in refluxing xylene) produces ferrocene, iron and carbon monoxidre; no biferrocene, carbon dioxide or elemental carbon are produced. A scheme is proposed to account for these products. 相似文献
9.
Hatsuo Yamamura Kousuke Satake Rieko Hirasawa Shinichi Yamada Masao Kawai 《Journal of inclusion phenomena and macrocyclic chemistry》2007,57(1-4):261-264
A novel cyclodextrin (CD) dimer linked with a bis(picolinyl)cystine (Cys) moiety was prepared by the coupling of Boc-protected
Cys with amino-modified CDs, followed by deprotection of the Boc groups and bispicolinylation. The dimer showed less affinity
to an organic guest molecule compared to that of a native CD monomer. It was attributed to an intramolecular inclusion of
the pyridine moiety into CD cavity. The dimer caused significant increase of its organic guest affinity by an addition of
a copper ion. The included pyridine group may come out of a CD cavity to bind the copper ion and the two CDs included cooperatively
and intermolecularly a guest molecule with high affinity. 相似文献
10.
IntroductionIsodonenanderianus (Hand . Mazz .)H .W .Li(Labiatae) ,widelydistributedinthesouthernpartsofYunnanProvince ,hasbeenusedinChinesetraditionalfolkmedicineasanti inflammatoryanddetoxifiedagent.1Previousphytochemicalinvestigationhasshownthepres enceofaser… 相似文献