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Bingwei Zhou Yuanyuan Hu Congyang Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2015,127(46):13863-13867
Herein, a manganese‐catalyzed nucleophilic addition of inert C(sp2) H bonds to aldehydes and nitriles is disclosed by virtue of a dual activation strategy. The reactions feature mild reaction conditions, excellent regio‐ and stereoselectivity, and a wide substrate scope, which includes both aromatic and olefinic C H bonds, as well as a large variety of aldehydes and nitriles. Moreover, mechanistic studies shed light on possible catalytic cycles. 相似文献
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