排序方式: 共有12条查询结果,搜索用时 15 毫秒
1.
光度法工作曲线不成线性关系的情况多数是由体系存在逐级配合物所致, 为获得线性关系, 有人提出在两逐级配合物的主要等色点波长测量, 认为这样可以避免同时生成第二配合物的影响, 但没有深入的理论分析。本文通过实验与理论分析, 证明此法在多数情况下仅可改善线性关系, 但不能得到直线, 经进一步研究, 找到了这个问题的另外解决办法。 相似文献
2.
3.
《Composite Interfaces》2013,20(8-9):805-815
Forces between solid surfaces across polymer melts are poorly understood despite their importance for adhesion and composite materials. Using an atomic force microscope (AFM) this force was measured for poly(dimethyl siloxane) (PDMS) on silicon oxide. The influence of molecular weight (4.0–40 kDa) was studied. Forces are attractive for low and repulsive for high molecular weight. In addition, changing the terminal methyl group for a hydroxyl group leads to an increased probability of bridging. 相似文献
4.
5.
《Composite Interfaces》2013,20(6):481-499
Atomic force microscopy (AFM) is employed to study the amine-terminated poly (butadiene-co-acrylonitrile) (ATBN) rubber-modified polybenzoxazine resin. Topographic mapping of the fracture surface is performed in conjunction with lateral force microscopy (LFM) and force–distance curve measurements (F–d). Matrix T g reduction is attributed to the dissolved rubber and the increased mechanical damping (tan δ) is derived from the phase-separated rubber. Saturation of the rubber in the matrix is defined at 6 wt% above which the matrix T g is not influenced upon rubber loading. The solubility limit of the reactive rubber in the matrix phase is determined from the fractured surface using LFM. The torsional force analyzed in the matrix phase increases upon the addition of rubber and levels off at 6 wt%. The results provide a direct correlation between bulk properties acquired by DMA and fractured surface probed by AFM. The presence of interphase between the separated rubbery domain and the continuous matrix phase is confirmed and its thickness is quantified from F–d curves. Moreover, it is found that interphase properties exhibit a strong rubber-concentration dependence. 相似文献
6.
水合双邻羟基苄氨乙酸铜配位结构的EXAFS研究 总被引:1,自引:0,他引:1
用参数化经验公式, 从已知晶体结构的无水双邻羟基苄胺铜(II)[Cu(o-OC6H4CH2NH2)2, 1]的EXAFS数据中分离出振幅和相移, 拟合另一已知晶体结构的水合双邻羟基苄胺铜(II){[Cu(o-OC6H4CH2NH2)2.H2O].1/2.H2O, 2}的结构参数并进行检验后, 代入未知结构的水合双邻羟基苄氨乙酸铜(II)[Cu(o-HOC6H4CH2NHCH2CO2)2.H2O, 3]中进行曲线拟合, 得到配位原子、键长和配位数等结构信息. 结合红外光谱, 推断标题化合物中, Cu(II)与两个苄基氮和两个羧基氧形成一个平面四边形的配位结构.铜与羧基氧键长2.00A, Cu-N键长1.99A, 另有一个较远的配位水分子, 铜与水的氧距离2.95A. 配体上的酚基氧没有与Cu(II)配合. 因此, 邻羟基苄氨乙酸(HBG)与Cu(II)配位时表现为二啮形式. 相似文献
7.
8.
9.
10.
塔板理论色谱流出曲线性质的研究 总被引:10,自引:0,他引:10
塔板理论是色谱动力学理论的重要部分。本文采用数学方法把塔板理论色谱流出曲线从离散函数形式变换为连续函数形式。在此基础上运用计算机进一步研究了塔板理论色谱流出曲线的性质。 相似文献