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Palladium‐Catalyzed Regioselective C‐Benzylation via a Rearrangement Reaction: Access to Benzyl‐Substituted Anilines 
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下载免费PDF全文 Dr. Manuel Amézquita‐Valencia Prof. Howard Alper 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(47):16774-16778
An unprecedented C‐benzylation rearrangement reaction, catalyzed by palladium, is reported. The reaction proceeds by rearrangement leading to the direct synthesis of para or ortho benzyl‐substituted N‐methylanilines. The product is obtained in high regioselectivity, without the need to use a ligand for the catalytic process. 相似文献
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E. M. Kasymova A. R. Burilov L. I. Vagapova N. A. Mukmeneva S. V. Bukharov G. N. Nugumanova D. B. Krivolapov M. A. Pudovik I. A. Litvinov A. I. Konovalov 《Russian Chemical Bulletin》2006,55(7):1171-1176
Reactions of hydroxyphenylcarbonyl derivatives with 3,5-di-tert-butyl-4-hydroxybenzyl acetate under mild conditions gave novel functionalized diarylmethanes.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1128–1133, July, 2006. 相似文献
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