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《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(52):16872-16876
A rhodium(II)‐catalyzed reaction of newly prepared 4‐acyl‐1‐sulfonyl‐1,2,3‐triazoles with benzene, and its derivatives, is investigated. Acceptor/acceptor carbenoids generated from 4‐acyltriazoles undergo selective insertion at aromatic C(sp2)−H bonds in the presence of benzylic C(sp3)−H bonds to produce N ‐sulfonylenaminones. 相似文献
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