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1.
XU Jun YAN Ai-Zhen XU Qin-Hua Department of Chemistry Nanjing University Nanjing Jiangsu China 《中国化学》1995,(2)
The strength of basic sites has been measured by pyrrole-IR on alkali metal cation exchanged β and X zeolites, as well as NaOH loaded Naβ. The influence of cation type and the structure of zeolites on their basicity has been studied. The acidic and basic properties of the samples were investigated by NH3-TPD and isopropanol reaction. It was shown that the strength of basic sites on samples could be characterized by the shift of vNH band in the pyrrole-IR spectra. The framework oxygen charges were calculated from the Sanderson electronegativity. The changes in basic properties with various alkali metal cation are consistent with the changes of local oxygen charges of the zeolite framework. 相似文献
2.
Kai-li Xiang 《计算数学(英文版)》2002,(2)
1. IntroductionWe consider a class of direct hybrid methods proposed in [11 for solving the second orderinitial value problemy" = f(t,y), y(0),y'(0) given (1.1)The basic method has the formandHere t. = nh and we define t.l.. = t. I aih, i = 1, 2 and n=0,1… 相似文献
3.
E. E. Ergozhin N. A. Bektenov A. K. Mekebaeva N. N. Chopabaeva 《Chemistry of Natural Compounds》2003,39(3):299-302
Phosphorus-containing cellulose cation exchangers were synthesized by reaction of wood cellulose with orthophosphoric acid and the ternary polymer from glycidylmethacrylate, styrene, and maleic anhydride. The effects of the ratio of reactants, temperature, and duration of the reaction on the phosphorylation and exchange capacity of the modified cellulose material were studied. 相似文献
4.
毛细管离子交换电色谱的分离行为 总被引:7,自引:0,他引:7
在离子交换毛细管色谱柱上实施电色谱,并对其分离行为进行了研究,采用75μm(i.d.)20cm的毛细管强阳离子交换柱(3μm)以NaH2PO4-H3PO4缓冲液为淋洗剂,紫外柱上检测(214nm)考察了流动相的pH值,有机改性剂及分离电压等因素对分离的影响,研究表明,不同的pH溶质的流出次序发生改变,随着有机改性剂含量增加,溶质的保留时间减小,而电渗流却增大,同时,对分离的柱效和方法的重现性进行了 相似文献
5.
The monodisperse, porous poly(chloromethylstyrene-co-divinylbenzene) beads of 7.9 microm were prepared by a single-step swelling and polymerization method. The seed particles prepared by dispersion polymerization exhibited good absorption of the monomer phase. Based on this media, a weak cation-exchange (WCX) stationary phase for HPLC was synthesized by a new chemically modified method. The prepared resin has advantages of biopolymer separation, high column efficiency, low column backpressure, high protein mass recovery, and good resolution for proteins. The dynamic protein-loading capacity of the synthesized WCX packings was 18.2 mg/g. Five proteins were separated in 3.0 min using the synthesized WCX stationary phase. The experimental results show that the obtained WCX resin has very weak hydrophobicity. The WCX resin was also used for the rapid separation and purification of lysozyme from egg white in 5.0 min with only one step. The purity and specific bioactivity of the purified lysozyme were found to be more than 93% and 70 245 U/mg, respectively. 相似文献
6.
本文采用表面活性剂十六烷基三甲基溴化铵(C16TABr,以下为1631),在(Na,K)OHSiO2C16TABrH2O体系中分别利用室温、水热及干粉法进行了纯硅MCM41中孔分子筛的合成,考察了阳离子Na+、K+对MCM41合成及稳定性的影响。通过XRD对结晶度的测定,发现NaMCM41的晶化速率明显高于KMCM41,而热稳定性和水热稳定性较差,且a0值小于后者。同时发现,就合成方法而言,室温法得到的产物具有很高的结晶度,利用水热法合成的样品的热稳定性明显较高,而干法得到的分子筛产品具有优良的水热稳定性。 相似文献
7.
The rate of the Wolff-Kishner reaction of benzophenone hydrazone in butyl carbitol increases as the cation of the alkoxide base is varied in the order K>Na>Li>Mg. The replacement of butyl carbitol by 1-decanol also accelerates the reaction, and an additional increase is caused by the presence of crown ether. On the basis of changes in the activation parameters, it is concluded that the reactivity of the hydrazone anion increases as the contact ion pair becomes more fully solvated and dissociated. 相似文献
8.
Alginate Properties and Heavy Metal Biosorption by Marine Algae 总被引:10,自引:0,他引:10
The physical properties of the alginate component in four different brown seaweeds (Sargassumfluitans, Ascophyllum nodosum, Fucus vesiculo-sus, andLaminaria japonica) were characterized using potentiometric titration,13C-nuclear magnetic resonance (NMR), chemical analysis, and viscosity measurements. The heavy metal binding capacities of the
corresponding seaweeds were directly proportional to their respective total carboxyl group content, and related to the electronegativity
of the elements investigated (Ca, Zn, Cd, Cu, and Pb). The uronic acid composition or sequence of the alginate component did
not affect the metal uptake properties of the biosorbents studied here. However, the alginate leaching owing to its solubilization
by Na ions was observed to decrease with increasing intrinsic viscosity of the extracted alginate, related to its molecular
weight, and with increasing apparent acidic dissociation constant, related to the alginate density inside the biomass. 相似文献
9.
D. Tirzite A. Krauze A. Zubareva G. Tirzitis G. Duburs 《Chemistry of Heterocyclic Compounds》2002,38(7):795-800
The alkylation of 3-cyano-1,4-dihydropyridine-2(3H)-thiones or the condensation of an aromatic aldehyde, cyanothioacetamide, acetylacetone, and methyl iodide in the presence of piperidine has given a series of novel 5-acetyl-2-alkylthio-4-aryl-6-methyl-1,4-dihydropyridine-3-carboxylic acid nitriles. A compound was obtained from 3,5-di(tert-butyl)-4-hydroxybenzaldehyde in the molecule of which were combined the active part of the antioxidant ionol and a 1,4-dihydropyridine ring. It was found that, among the compounds synthesized, the highest antiradical activity occurred in a compound having two hydroxyl groups in the 4-phenyl substituent. 相似文献
10.
Ahmed M. Mkadmh 《International journal of quantum chemistry》2020,120(23):e26393
Different isomers of N5+ were modeled at DFT(PBE0)/aug-cc-pV(Q + d)Z, and their ground(transition) state characteristics were assessed through frequency calculations. Single-point energies were accomplished at PBE0/aug-cc-pV(5 + d)Z. Nonlinear optical susceptibilities (NLO) of isomers were accomplished using Firefly, while the linear optical invariant was examined using the finite-field method, Firefly, and modified dipole field tensor in the presence of two different screening factors. The excited states, singlets and triplets, of were modeled at the CIS and CIS(D) and then their optical parameters were estimated at TDFT(PBE0)/aug-cc-pV(Q + d)Z using Firefly. The singlet is found the most stable isomer, with the inversional rate constant larger than that of the Cs isomer and high energy barrier with the triplet counterpart. Isomers 2 , 3 , and 4 are found local minima, while 5 and 6 are saddle points: transition states between equivalent invertomers. Energy calculations of the singlet and triplet isomers were in excellent agreement with the literature. An excellent correlation is found between the average polarizability and the impulse factor. Substantial variations were found between the singlet and triplet excited states in terms of energy, geometry, and optical properties from one side and with from the other side. Reactivity indices showed that N1 and N5 are the optimum nucleophilic and electrophilic reactivity sites. 相似文献