化学燃烧法制备Bi-2212前驱粉末

高质量的前驱粉是制备高性能Bi-2212线材的基础.本文采用化学燃烧法制备纳米级Bi-2212前驱粉末,分析了Bi-2212纳米粉末的成相过程以及微观形貌,结果表明可以成功制备尺寸小于100 nm的氧化粉末,经过热处理后得到纯的Bi-2212成相粉.与传统共沉淀方法的前驱粉末相比,纳米生粉反应活性更高,Bi-2212成相温度降低,转化效率更高.该方法有利于实现高质量的Bi-2212前驱粉末的批量制备.     

Bi-2212导体用铠甲316LN钢力学性能研究

下一代超导磁体系统有着大电流、高磁场的显著特点,中心场约为5-7T,而最高场达到15T。为了满足如此高的磁场强度,作者需要制作能够达到磁场15T,电流45k A,电磁循环万次后性能稳定要求的超导磁体。目前,Bi2212作为发展的一个方向。Bi2212能否开展高场导体的应用,需要对线材,铠甲材料,以及成型后的导体整体都进行一系列的测试。主要介绍了目前Bi-2212导体使用的铠甲材料——316LN的高温力学性能研究测试。并与其室温、低温力学性能进行了对比;在软件上模拟了高温、加压的情况下材料所受的应力情况,分析了铠甲是否能满足将来的高压热处理。     

一种新的高温超导磁体电磁结构优化设计方法

本文阐述了用于高温超导磁体电磁结构优化设计的一种新方法,与一般优化方法不同之处在于其不用定义磁体的初始结构形状,采用该方法可以得到满足规格和性能要求的较佳磁体结构.通过此方法优化设计了一个中心磁场为3T的Bi系高温超导磁体,其设计结果与满足同样要求且经过优化的单螺管高温超导磁体的设计结果作了对比,由结果表明该方法具有很好的优化效果.     

利用高压热处理技术提高Bi-2223/Ag高温超导带材临界电流

提高临界电流密度(Jc)对促进Bi-2223/Ag高温超导带材的应用有着重要意义.在常压热处理条件下所制备的带材中存在大量的裂纹、孔洞和第二相颗粒等,这些因素都会对带材的超导连接性能产生破坏作用.我们成功建立了一套可用氧气氛的热等静压设备,工作气压和温度可同时达到15MPa和850°C.通过引入裂纹愈合热处理过程,我们成功对带材进行了高压热处理,所得样品中第二相颗粒和裂纹数量大幅度降低,77K、自场下的临界电流相比常压热处理样品提高了20%左右.     

Single-phase AC losses in prototype HTS conductors for superconducting power transmission lines

We report single-phase AC loss measurements on 8-, 4-, and 3-layer, multi-strand, HTS prototype conductors for power transmission lines. We use both calorimetric and electrical techniques. The agreement between the two techniques suggests that the interlayer current distribution in 1-m long conductors are representative of those in long conductors. The losses for the 8- and 4-layer conductors are in rough agreement, with the 8-layer losses being somewhat lower. The 3-layer conductor losses are substantially higher — probably due to unbalanced azimuthal currents for this configuration.     

β-Isothiocyanatoketones: A Convenient Source of Heterocyclic Compounds

Summary. The preparation of -isothiocyanatoketones and their reactions leading to formation of pyrimidine and bicyclic, tricyclic, tetracyclic, and pentacyclic heterocyclic compounds are reviewed. A few references concerning the rearrangement of heterocyclic compounds are also included. Some of the compounds reported have shown good antiinflammatory activity.     

AC transport current loss of assembled conductor of HTS tapes

We study experimentally and theoretically the AC transport current loss characteristics of a tape in multiple tapes assembled in single layer and subject to external field produced by transport currents of adjacent tapes. We measured the AC transport current losses of a Bi2223 silver-sheathed tape in a single layer arrangement of three tapes using our newly developed potential leads arrangement to avoid spurious loss components caused by the magnetization in the adjacent tapes. In the paper, the influence of the external AC field produced by adjacent tapes on the loss characteristics is studied based on the experimental results and theoretical analysis.     

Estimation of Jc(B) dependence from self-field alternating current (AC) losses measured on Bi-2223/Ag tapes

Transport AC losses measured in self-field conditions on multifilamentary Bi-2223 tapes are often found to be lower than those calculated within the framework of the critical state model for a bulk wire with elliptical cross section, though generally higher than predicted for a strip. This effect is sometimes ascribed to the non-ideal geometry of the tapes, which does not exactly reproduce either shape. Here we propose an alternative explanation assuming that the critical current density of superconducting material depends on magnetic field. In practice, we analyzed the AC loss curve and deduced different I_c values for the individual data points, using the standard Norris equation for elliptical conductor. This gives the relation between ‘calculated' I_c and the self-field associated to AC transport current, which can be regarded as an alternative way to qualify the dependence of J_c on magnetic field. Important is that this procedure covers the range of fields below the self-field at I_c where the measurement in background DC field can not be used to determine J_c(B).     

Reduction of AC losses applying novel resistive interfilamentary carbonate barriers in multifilamentary Bi(2223) tapes

Hysteresis losses and coupling losses, a main component of the AC losses in Bi(2223) tapes, can effectively be reduced by enhancing the resistivity of the matrix material between the filaments and applying a filament twist. Since through alloying the sheath, as using AgAu(8 wt.%), the resistivity can only be raised by a factor <10 (77 K), a new conductor configuration with a quite novel composite matrix having resistive SrCO₃ barriers inside the Ag matrix between the filaments was developed. These new barriers, a cheap and commercial material, withstand the tape annealing, do not react with the superconductor, sinter dense and have a good bonding to Ag. Applying two different preparation techniques for 19 filament prototype tapes, critical current densities up to 20.7 kA cm⁻² were achieved. We report on tape preparation, the effect on the phase texture and the superconducting properties of such barrier tapes.     

Current distributions in multifilamentary conductors: the influence of intergrowths

The modelling of both critical and remanent states (i.e., the current density and field distributions) in periodic arrays of flat superconducting strips is important for calculating the AC losses in multifilamentary tapes made for power applications. We model the current and field profiles for such magnetically coupled conductors, and have measured these dependences for BSCCO-22223 tapes using a miniature scanning Hall probe technique. The results indicate that the filaments are also electrically connected to a significant extent, which must be caused by superconducting intergrowths between individual filaments.