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排序方式: 共有1553条查询结果,搜索用时 31 毫秒
1.
Dr. Sebastian Lars Müller Xinglong Zhou Dr. Peter Leonard Oxana Korzhenko Dr. Constantin Daniliuc Prof. Dr. Frank Seela 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(12):3077-3090
Silver-mediated α-dC–Ag+–β-dC hybrid base pairs decorated with 5-iodo- or 5-octadiynyl residues are well accommodated in duplex DNA. A strong Tm increase and favorable thermodynamic data for duplex DNA were observed after addition of silver ions. The phenomenon is particularly obvious when both nucleobases of the base pairs are functionalized. Neither the position of the base pair, nor the type of 5-substituent had a negative influence. On the contrary, functionalization of conventional silver-mediated β-dC–Ag+–β-dC homo base pairs showed a negative impact induced by the bulky substituents. To this end, cytosine modified 12-mer oligodeoxynucleotides were prepared by solid-phase synthesis employing new α-anomeric 2′-deoxycytidine phosphoramidites. A multigram scale synthesis was developed for 5-iodo-α-d -2′-deoxycytidine ( 1 ) employing the direct glycosylation of cytosine with Hoffer's α-d -halogenose followed by separation of anomeric DMT nucleosides. Regarding base-pair stability and functionalization silver-mediated α/β-dC hybrid base pairs were found to be superior to β/β-dC homo pairs. According to their extraordinary properties, they might find applications in DNA diagnostics, material science, or nanotechnology. 相似文献
2.
3.
Let G be either a split SO(2n+2), or a split adjoint group of type En, (n=6,7,8), over a p-adic field. In this article we study correspondences arising by restricting the minimal representation of G to various dual pairs in G. 相似文献
4.
The surgery obstruction of a normal map to a simple Poincaré pair (X, Y) lies in the relative surgery obstruction group L *(π 1(Y) → π 1(X)). A well-known result of Wall, the so-called π-π-theorem, states that in higher dimensions a normal map of a manifold with boundary to a simple Poincaré pair with π 1(X) ? π 1(Y) is normally bordant to a simple homotopy equivalence of pairs. In order to study normal maps to a manifold with a submanifold, Wall introduced the surgery obstruction groups LP * for manifold pairs and splitting obstruction groups LS *. In the present paper, we formulate and prove for manifold pairs with boundary results similar to the π-π-theorem. We give direct geometric proofs, which are based on the original statements of Wall’s results and apply obtained results to investigate surgery on filtered manifolds. 相似文献
5.
We prove that for any given c, 1 < c < 17/11, almost all natural numbers are representable in the form [x
c] + [p
c], where x is a natural number and p is a prime. 相似文献
6.
A scheme for teleporting a three-particle state is proposed when three pairs of entangled particles are used as quantum channels. Quantum teleportation can be successfully realized with a certain probability if the receiver adopts an appropriate unitary-reduction strategy. The probability of successful teleportation is determined by the smaller coetficients of the three entangled pairs. 相似文献
7.
生物小分子与铜锌超氧化物歧化酶相互作用的波谱学研究及其应用 总被引:1,自引:0,他引:1
本工作以ESR和NMR为主要手段,并结合其它生化方法,考察了氨基酸、核酸碱基、糖等生命基本物质,和抗坏血酸等生命必需物质与钢锌超氧化物歧化酶的相互作用,实验观测到氨基酸、核酸碱基和抗坏血酸在水溶液中可以与酶中的Cu2+作用而使其脱离活性部位,以小分子络合物形式游离在溶液中,同时使酶失活,脱离活性部位的Cu2+的比例和酶的失活程度取决于小分子配体的加入量及其与Cu2+的络合能力。此外,首次尝试使用ESR方法,并借助氨基酸与酶的作用,考察了铜锌超氧化物歧化酶在盐酸胍变性和热变性过程中的构象变化行为,结果表明这一方法是直观而有效的。 相似文献
8.
Nonlocal character of entangled photon pairs generated in spontaneous parametric downconversion is demonstrated. One photon from a pair propagates through a Mach-Zehnder interferometer and is detected in coincidence-count measurement with its twin. Width of the coincidence-count interference pattern (measured for various values of path difference in the Mach-Zehnder interferometer) depends on spectral width of the twin as a result of entanglement of photons in a pair. The experimental setup is analyzed for a Gaussian spectral filter and a Fabry-Perot resonator. It is shown that nonlocal interference is much stronger for cw pumping in comparison with femtosecond pulsed pumping for values of parameters commonly used in spontaneous parametric downconversion experiments. 相似文献
9.
Jeremy Lovejoy 《Journal of Number Theory》2004,106(1):178-186
It is shown that counting certain differences of overpartition functions is equivalent to counting elements of a given norm in appropriate real quadratic fields. 相似文献
10.