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Guangrong Meng Michal Szostak 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2015,127(48):14726-14730
Metal‐catalyzed reactions of amides proceeding via metal insertion into the N CO bond are severely underdeveloped due to resonance stabilization of the amide bond. Herein we report the first Heck reaction of amides proceeding via highly chemoselective N CO cleavage catalyzed by Pd0 utilizing amide bond ground‐state destabilization. Conceptually, this transformation provides access to a myriad of metal‐catalyzed transformations of amides via metal insertion/decarbonylation. 相似文献
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