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Daniel Solé 《Tetrahedron》2007,63(41):10177-10184
Pd(0)-promoted coupling of an amino-tethered vinyl iodide and ketone enolate is the key step to synthesize the CDE ring system of the indole alkaloid strychnopivotine. Attempts to induce the same process in a compound bearing an o-nitrophenyl group as a latent indole moiety failed. 相似文献
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David Brückner 《Tetrahedron》2006,62(16):3809-3814
N-Formyl-tosylamides can be efficiently converted to N-ethynyl-tosylamides in two steps via the corresponding dichlorovinylamides. 相似文献
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Palladium-catalyzed alkenation of thiophenes and furans by regioselective C-H bond functionalization
Jinlong Zhao 《Tetrahedron letters》2009,50(23):2758-229
A palladium-catalyzed direct alkenation of thiophenes and furans has been developed in the presence of AgOAc and pyridine. A variety of olefinic substrates such as acrylates, acrylamides, and acrylonitrile can perform the direct oxidative coupling reactions with various thiophenes and furans to give the mono-alkenylated products in good yields. In most cases, the (E)-isomers were isolated as the major products. 相似文献
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