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排序方式: 共有124条查询结果,搜索用时 15 毫秒
1.
2.
A method for the determination of 2-furaldehyde (F) and 5-hydroxymethyl-2-furaldehyde (HMF) in alcoholic beverages by high performance liquid chromatography (HPLC) is described. A C-18 column and an acetonitrile-water mobile phase with isocratic elution were used. UV detection at 280 nm was carried out. The method was validated according to the EURACHEM guidelines. The procedure offers a high specificity and detection limits of the order of 0.005 μg mL− 1. Recoveries of 94-103% were obtained from spiked samples at different levels with both analytes. Intermediate precision calculated for a period of 2 months was + 0.8% for HMF and + 0.4% for F. The method was applied to the analysis of alcoholic beverages like bourbon, rum, brandy, liquors and aperitif wines. 相似文献
3.
Martí MP Pino J Boqué R Busto O Guasch J 《Analytical and bioanalytical chemistry》2005,382(2):440-443
The aromatic composition of sugar cane spirits and, in general, of alcoholic beverages, is mainly influenced by the ageing process in wood barrels. There are several factors that affect the quality of the final aged product, but the time of the storage in the barrel is perhaps the most important one. Ageing time must therefore be controlled in order to detect counterfeits; however, this parameter is very difficult to control and, at present, there is no analytical method available to determine it. We propose a quantitative method for determining the ageing time of sugar cane spirits in oak barrels by using an electronic nose based on coupling directly a headspace sampler to a mass spectrometer (HS-MS), and multivariate calibration. The method developed is simple and provides, in 5 min, the ageing time of spirits with an accuracy of about 1 month. 相似文献
4.
The stability of spontaneous thin layers and thin layers formed upon cathodical polarization of Ti in KOH solutions have been
studied by potentiostatic and ellipsometric methods. At open circuit potential (OCP) the strongly adherent films, whose thickness
depends on the concentration of the KOH solution, were formed. During the cathodic polarization the transformation of these
films to weakly adsorbed precipitated layers on the electrode surface was observed. Comparing the theoretically computed curves
with the experimental Ψ vs Δ loci measured ellipsometrically, the complex indices of refraction and the thickness of the generated films, from 3.6
to 60 nm in 1 M KOH and from 36 to 105 nm in 5 M KOH (adherent to the electrode surface), were determined. At OCP the rate
of film growth increases with increasing the concentration of KOH solution. Cathodic polarizations change the chemical composition
and retard the rate of film growth. Based on the ellipsometric and electrochemical data the chemical compositions of the formed
films consisted of TiO2, Ti2O3, TiO2·H2O, Ti(OH)3 and TiOOH·nH2O. 相似文献
5.
Michiko Iwamura Yuka Gotoh Tomoyuki Hashimoto Reiko Sakurai 《Tetrahedron letters》2005,46(37):6275-6277
Michael addition reactions of acetoacetates and malonates with acrylates in a 5 M KOH aqueous solution without using any other catalysts are described. When they are either tert-butyl or benzyl esters, the reaction proceeded very rapidly to afford moderate to high yields of the corresponding bis-Michael adducts that are unexpectedly stable under these conditions. 相似文献
6.
热处理及与KOH共炭化对深度脱除煤中无机矿物质的促进作用 总被引:1,自引:0,他引:1
研究了煤经热处理(炭化)以及煤与KOH共炭化对酸洗脱灰的影响。结果表明,煤经炭化再用盐酸洗涤,可以在缓和的条件下大幅度提高酸洗脱灰率;煤与KOH共炭化后再酸洗,不仅对煤中的粘土、黄铁矿等无机矿物质有很好的效果,还特别适于脱除在一般情况下都难以除去的石英矿物。 相似文献
7.
Leornardo S. Mendes 《Analytica chimica acta》2003,493(2):219-231
Fourier transform-near infrared (FT-NIR) and FT-Raman spectrometries have been used to design partial least squares (PLS) calibration models for the determination of the ethanol content of ethanol fuel and alcoholic beverages. In the FT-NIR measurements the spectra were obtained using air as reference, and the spectral region for PLS modeling were selected based on the spectral distribution of the relative standard deviation in concentration. In the FT-Raman measurements hexachloro-1,3-butadiene (HCBD) has been used as an external standard. In the PLS/FT-NIR modeling for ethanol fuel analysis 50 ethanol fuel standards (84.9-100% (w/w)) were used (25 in the calibration, 25 in the validation). In the PLS/FT-Raman modeling 25 standards were used (13 in the calibration, 12 in the validation). The PLS/FT-NIR and FT-Raman models for beverage analysis made use of 24 standards (0-100% (v/v)). Twelve of them contained sugars (1-5% (w/w)), one-half was used in the calibration and the other half in the validation. Different spectral pre-processing were used in the PLS modeling, depending on the type of sample investigated. In the ethanol fuel analysis the FT-NIR pre-processing was a 17 points smoothed first derivative and for beverages no spectral pre-processing was used. The FT-Raman spectra were pre-processed by vector normalization in the ethanol fuel analysis and by a second derivative (17 points smoothing) in the beverage analysis. The PLS models were used in the analysis of real ethanol fuel and beverage samples. A t-test has shown that the FT-NIR model has an accuracy equivalent to that of the reference method (ASTM D4052) in the analysis of ethanol fuel, while in the analysis of beverages, the FT-Raman model presents an accuracy equivalent to the reference method. The limits of detection for NIR and Raman calibration models were 0.05 and 0.2% (w/w), respectively. It has also been shown that both techniques, present better results than gas chromatography (GC) in evaluating the ethanol content of beverages. 相似文献
8.
Devdutt Chaturvedi Nisha Mishra Amit K. Chaturvdi Virendra Mishra 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3):550-558
A quick and efficient, one-pot synthesis of dithiocarbazates was accomplished in high yields by the reaction of various alcoholic tosylates of primary, secondary, and tertiary alcohols, with substituted hydrazines using an Amberlite IRA 400 (basic resin)/CS 2 system. The reaction conditions are mild with simpler work-up procedures than previously reported methods. 相似文献
9.
A quick, efficient, one-pot synthesis of dithiocarbazates was accomplished in high yields by the reaction of various tosylates of primary, secondary, and tertiary alcohols with a variety of substituted hydrazines using the benzyl–trimethylammonium hydroxide (Triton-B)/CS2 system. The reaction conditions are mild with simpler workup procedures than the reported methods. 相似文献
10.
Ji‐Hong Zhao Chun‐Hao Li Zhen‐Hua Lv Ying Xu 《Surface and interface analysis : SIA》2013,45(11-12):1667-1672
The regular micrometer‐scale triangular arrays were formed using ultrafast femtosecond laser irradiation on (111) surface of silicon wafer immersed in KOH solution (0.1 g/ml). At low laser fluence, the resulting surface is covered by triangular pits microstructures, whereas at high laser fluence, the structures are transformed to multilayer‐triangular stacks‐microstructures. The number of triangular stacks layer increased as the laser fluence increased. The formation of triangle microstructure arrays depends on both silicon surface crystallographic orientation and the concentration of KOH solution. Either for lower KOH solution concentration (0.02 g/ml) or other silicon crystallographic orientation, triangle arrays cannot be obtained. We attribute the formation of triangular microstructure arrays to the laser‐assisted chemical etching process. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献