PREPARATION OF PERFLUOROOCTANOYL-MODIFIED POLY(VINYL-ALCOHOL)S AND THEIR ADSORPTION AT AN AIR-WATER INTERFACE

Perfluorooctanoyl modified poly(vinyl alcohol)s (FPVA) were prepared by means of substituting a small amountof hydroxyl groups on the backbone of poly(vinyl alcohol), for which the initial degree of polymerization is equal to 1750.The substitution extent, defined by the number of substituting units in a chain, for the four FPVA samples was in the range of0.5-5 perfluorooctanoyl groups per chain. The FPVA samples with the highest substitution extent still had good solubility inwater. It was shown by experimental measurement at 30.0±0.1℃ that the surface tension of the aqueous solution of thehighest substituted FPVA decreased to 16.6 mN/In at a higher concentration, e.g about 0.1 g/mL. Obviously,macromolecules of FPVA exhibit a very strong tendency to adsorb at the air-water interface, because the hydrophobicperfluorooctanoyl groups in FPVA have a very high surface activity as they are in small molecular fluorinated surfactants.The chain conformation of such a model polymer adsorbed on the air-water interface was also discussed.     

Interfacial behavior of plant proteins — novel sources and extraction methods

Understanding the air-water and oil-water interfacial behavior of plant proteins is crucial for developing stable emulsions and foams in food systems. Plant crops are often processed into protein extracts with high purity, which primarily consist of globulins. These globulins are often unable to form stiff interfacial layers owing to their compact and highly aggregated state and have inferior functionality compared with animal-derived proteins from milk or eggs. Much of the current focus is on modifying these proteins, whereas better interface stabilizing functionality can also be obtained by choosing more targeted protein extraction methods. This review will highlight the benefits and drawbacks of current and novel protein sources and protein extraction methods with respect to interfacial properties.     

Emission Control by Molecular Manipulation of Double‐Paddled Binuclear PtII Complexes at the Air‐Water Interface

Molecular functions depend on conformations and motions of the corresponding molecular species. An air–water interface is a suitable asymmetric field for the control of molecular conformations and motions under a small applied force. In this work, double‐paddled binuclear Pt^II complexes containing pyrazole rings linked by alkyl spacers were synthesized and their orientations and emission properties dynamically manipulated at the air–water interface. The complexes emerge from water with concurrent variation of interface orientation of the planes of the Pt^II complexes from perpendicular to parallel during mechanical compression suggesting a unique ‘submarine emission‘. Phosphorescence of the complexes is quenched at the air–water interface prior to monolayer formation with intensities subsequently rapidly increasing during monolayer compression. These results indicate that asymmetric reactions and motions might be controlled by applying mechanical force at the air–water interface.     

Fluid-elastic instability in tube arrays subjected to air-water and steam-water cross-flow

Flow induced vibrations in heat exchanger tubes have led to numerous accidents and economic losses in the past. Efforts have been made to systematically study the cause of these vibrations and develop remedial design criteria for their avoidance. In this research, experiments were systematically carried out with air-water and steam-water cross-flow over horizontal tubes. A normal square tube array of pitch-to-diameter ratio of 1.4 was used in the experiments. The tubes were suspended from piano wires and strain gauges were used to measure the vibrations. Tubes made of aluminum; stainless steel and brass were systematically tested by maintaining approximately the same stiffness in the tube-wire systems. Instability was clearly seen in single phase and two-phase flow and the critical flow velocity was found to be proportional to tube mass. The present study shows that fully flexible arrays become unstable at a lower flow velocity when compared to a single flexible tube surrounded by rigid tubes. It is also found that tubes are more stable in steam-water flow as compared to air-water flow. Nucleate boiling on the tube surface is also found to have a stabilizing effect on fluid-elastic instability.     

The effect of air-water interface on the vortex shedding from a vertical circular cylinder

The flow past an interface piercing circular cylinder at the Reynolds number Re=2.7×10⁴ and the Froude numbers Fr=0.2 and 0.8 is investigated using large-eddy simulation. A Lagrangian dynamic subgrid-scale model and a level set based sharp interface method are used for the spatially filtered turbulence closure and the air-water interface treatment, respectively. The mean interface elevation and the rms of interface fluctuations from the simulation are in excellent agreement with the available experimental data. The organized periodic vortex shedding observed in the deep flow is attenuated and replaced by small-scale vortices at the interface. The streamwise vorticity and the outward transverse velocity generated near the edge of the separated region, which enforces the separated shear layers to deviate from each other and restrains their interaction, are primarily responsible for the devitalization of the periodic vortex shedding at the interface. The lateral gradient of the difference between the vertical and transverse Reynolds normal stresses, increasing with the Froude number, is the main source of the streamwise vorticity and the outward transverse velocity at the interface.     

Sum frequency generation spectroscopic study of the condensation effect of cholesterol on a lipid monolayer

Sum frequency generation (SFG) spectra and surface pressure–molecular area (π–A) isotherms have been obtained for mixed cholesterol–DPPC monolayers with cholesterol mole fractions, x(chol.), from 0 to 1.0, at the air–water interface, under same conditions, at 22 °C. Analysis of the spectra indicated that incorporation of cholesterol into the monolayers at 3 mN m⁻¹ greatly increases the conformational and orientational order of the alkyl chains of DPPC, maximizing these properties at x(chol.)=0.4. Analysis also indicated that order in the mixed monolayers at 15 and 35 mN m⁻¹ is not affected by incorporation of cholesterol. The π–A isotherms measured at 3 mN m⁻¹ for the mixed monolayer with x(chol.)=0.4 have the largest negative deviation of the molecular area relative to those of ideal mixtures (the so-called “condensation effect” of cholesterol), indicating the most thermodynamically stable state. Comparison of results from SFG spectra and π–A isotherms explicitly proved that the condensation effect can be interpreted in terms of conformational and orientational ordering of the alkyl chains of DPPC.     

Heat transfer to air–water annular flow in a horizontal pipe

Two-phase air–water flow and heat transfer in a 25 mm internal diameter horizontal pipe were investigated experimentally. The water superficial velocity varied from 24.2 m/s to 41.5 m/s and the air superficial velocity varied from 0.02 m/s to 0.09 m/s. The aim of the study was to determine the heat transfer coefficient and its connection to flow pattern and liquid film thickness. The flow patterns were visualized using a high speed video camera, and the film thickness was measured by the conductive tomography technique. The heat transfer coefficient was calculated from the temperature measurements using the infrared thermography method. It was found that the heat transfer coefficient at the bottom of the pipe is up to three times higher than that at the top, and becomes more uniform around the pipe for higher air flow-rates. Correlations on local and average Nusselt number were obtained and compared to results reported in the literature. The behavior of local heat transfer coefficient was analyzed and the role of film thickness and flow pattern was clarified.     

Modeling and simulation of severe slugging in air-water systems including inertial effects

A mathematical model and numerical simulations corresponding to severe slugging in air-water pipeline-riser systems are presented. The mathematical model considers continuity equations for liquid and gas phases, with a simplified momentum equation for the mixture. A drift-flux model, evaluated for the local conditions in the riser, is used as a closure law. In many models appearing in the literature, propagation of pressure waves is neglected both in the pipeline and in the riser. Besides, variations of void fraction in the stratified flow in the pipeline are also neglected and the void fraction obtained from the stationary state is used in the simulations. This paper shows an improvement in a model previously published by the author, including inertial effects. In the riser, inertial terms are taken into account by using the rigid water-hammer approximation. In the pipeline, the local acceleration of the water and gas phases are included in the momentum equations for stratified flow, allowing to calculate the instantaneous values of pressure drop and void fraction. The developed model predicts the location of the liquid accumulation front in the pipeline and the liquid level in the riser, so it is possible to determine which type of severe slugging occurs in the system. A comparison is made with experimental results published in literature including a choke valve and gas injection at the bottom of the riser, showing very good results for slugging cycle and stability maps. Simulations were also made assessing the effect of different strategies to mitigate severe slugging, such as choking, gas injection and increase in separation pressure, showing correct trends.     

Implications of interfacial characteristics of food foaming agents in foam formulations

The manufacture of food dispersions (emulsions and foams) with specific quality attributes depends on the selection of the most appropriate raw materials and processing conditions. These dispersions being thermodynamically unstable require the use of emulsifiers (proteins, lipids, phospholipids, surfactants etc.). Emulsifiers typically coexist in the interfacial layer with specific functions in the processing and properties of the final product. The optimum use of emulsifiers depends on our knowledge of their interfacial physico-chemical characteristics - such as surface activity, amount adsorbed, structure, thickness, topography, ability to desorb (stability), lateral mobility, interactions between adsorbed molecules, ability to change conformation, interfacial rheological properties, etc. -, the kinetics of film formation and other associated physico-chemical properties at fluid interfaces. These monolayers constitute well defined systems for the analysis of food colloids at the micro- and nano-scale level, with several advantages for fundamental studies. In the present review we are concerned with the analysis of physico-chemical properties of emulsifier films at fluid interfaces in relation to foaming. Information about the above properties would be very helpful in the prediction of optimised formulations for food foams. We concluded that at surface pressures lower than that of monolayer saturation the foaming capacity is low, or even zero. A close relationship was observed between foaming capacity and the rate of diffusion of the foaming agent to the air-water interface. However, the foam stability correlates with the properties of the film at long-term adsorption.     

两亲性嵌段聚醚酯在空气-水界面上的Langmuir单分子膜

聚醚酯是一种新型弹性材料,目前已成为工业化产品[1].对这种嵌段聚醚酯的合成和弹性行为[2]、熔体的流变性能[3]、以及纤维在拉伸状态下的聚集态结构和分子运动[4]已有一些报道.