全文获取类型
收费全文 | 5869篇 |
免费 | 635篇 |
国内免费 | 1401篇 |
专业分类
化学 | 6652篇 |
晶体学 | 62篇 |
力学 | 59篇 |
综合类 | 54篇 |
数学 | 13篇 |
物理学 | 1065篇 |
出版年
2024年 | 36篇 |
2023年 | 107篇 |
2022年 | 262篇 |
2021年 | 253篇 |
2020年 | 252篇 |
2019年 | 241篇 |
2018年 | 216篇 |
2017年 | 214篇 |
2016年 | 273篇 |
2015年 | 243篇 |
2014年 | 235篇 |
2013年 | 494篇 |
2012年 | 334篇 |
2011年 | 345篇 |
2010年 | 296篇 |
2009年 | 371篇 |
2008年 | 345篇 |
2007年 | 375篇 |
2006年 | 324篇 |
2005年 | 354篇 |
2004年 | 319篇 |
2003年 | 263篇 |
2002年 | 207篇 |
2001年 | 183篇 |
2000年 | 201篇 |
1999年 | 181篇 |
1998年 | 152篇 |
1997年 | 127篇 |
1996年 | 122篇 |
1995年 | 106篇 |
1994年 | 78篇 |
1993年 | 87篇 |
1992年 | 68篇 |
1991年 | 47篇 |
1990年 | 26篇 |
1989年 | 15篇 |
1988年 | 32篇 |
1987年 | 17篇 |
1986年 | 22篇 |
1985年 | 21篇 |
1984年 | 16篇 |
1983年 | 5篇 |
1982年 | 12篇 |
1981年 | 11篇 |
1980年 | 7篇 |
1979年 | 8篇 |
1977年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有7905条查询结果,搜索用时 15 毫秒
1.
Dr. Wan‐Ling Liu Ni‐Shin Yang Ya‐Ting Chen Stephen Lirio Cheng‐You Wu Prof. Chia‐Her Lin Prof. Hsi‐Ya Huang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(1):115-119
A green and sustainable strategy synthesizes clinical medicine warfarin anticoagulant by using lipase‐supported metal–organic framework (MOF) bioreactors (see scheme). These findings may be beneficial for future studies in the industrial production of chemical, pharmaceutical, and agrochemical precursors. 相似文献
2.
《Journal of separation science》2018,41(6):1319-1337
The present review discusses the theory and application of van't Hoff analysis in chiral chromatography, with main focus on liquid chromatography. The topics considered include the physical meaning of van't Hoff equation's parameters, interpretation of thermodynamic data in terms of retention and enantioseparation mechanisms, abnormal behavior of van't Hoff plots, and best practices to avoid biased results. 相似文献
3.
Lotfi Boudjema Dr. Jérôme Long Dr. Fabrice Salles Prof. Joulia Larionova Dr. Yannick Guari Prof. Philippe Trens 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(2):479-484
Porous coordination polymers are molecule-based materials presenting a high degree of tunability, which offer many advantages for targeted applications over conventional inorganic materials. This work demonstrates that the hydrophilic/hydrophobic character of Prussian blue analogues having a lipophilic feature may be tuned to optimize the gas adsorption properties. The role of the coordinatively unsaturated metal sites is emphasized through a combination of theoretical and experimental study of water, ethanol, and n-hexane adsorption. 相似文献
4.
Regis Guyonnet 《Journal of statistical physics》1991,65(1-2):269-289
The NMR properties of nuclei linked to long linear polymer molecules are sensitive to the influence of hard walls. In this context, the residual energy of tensorial spin-spin interactions is calculated using a path integral approach. Several thermodynamic quantities of the polymer system (free energy, equation of state,...) are also expressed, taking chain stiffness effects and the presence of two repulsive walls into consideration. 相似文献
5.
The breakthrough and stoichiometric SO2 adsorption efficiencies of a biomass supported Na2CO3 system (80 wt %Na2CO3/straw) have reached 48.9% and 80.6% respectively at a desulfurization temperature of 80℃. 相似文献
6.
应用密度泛函理论,本文系统地研究了O在Au(111)表面上的吸附能、吸附结构、功函数、电子密度和投影态密度,给出了覆盖度从0.11ML到1.0ML的范围内,O的吸附特性随覆盖度变化的规律.研究发现O的稳定吸附位为3重面心立方(fcc)洞位,O在fcc洞位的吸附能对覆盖度比较敏感,其值随着覆盖度的增加而减小;O诱导Au(111)表面功函数的变化量与覆盖度成近线性关系,原因是Au表面电子向O偏移,形成表面偶极子;O—Au的相互作用形成成键态和反键态,且反键态都被占据,造成O—Au键很弱,O吸附能较小.
关键词:
表面吸附
Au(111)表面
密度泛函理论
电子特性 相似文献
7.
We present all-atom molecular dynamics simulations ofn-hexane on the basal plane of graphite at monolayer and multilayer coverages. In keeping with experimental data, we find the
presence of ordered adsorbed layers both at single monolayer coverage and when the adsorbed layer coexists with excess liquid
adsorbate. Using a simulation method that does not impose any particular periodicity on the adsorbed layer, we quantitatively
compare our results to the results of neutron diffraction experiments and find a structural transition from a uniaxially incommensurate
lattice to a fully commensurate structure on increasing the coverage from a monolayer to a multilayer. The zig-zag backbone
planes of all the alkane molecules lie parallel to the graphite surface at the multilayer coverage, while a few molecules
are observed to attain the perpendicular orientation at monolayer coverage.
Dedicated to Professor C N R Rao on his 70th birthday 相似文献
8.
1.INTRODUCTION[()-227.3()]Endotoxinislipopolysaccharide(LPS)derivedfromthecellmembranesofgram-negativebacteria.Endotoxincancausefebrilereactionsinanimalswithsymptomsofhighfever,vasodilation,diarrheaandfetalshockwheninjectedeveninaverysmallamount[1].Iftheconcentrationofendotoxininpatients?bloodishighenoughitcancauseseveresepsis,whichisamajorcauseofdeathinpatientsandcontinuestohaveahighmortalitydespiteappropriatesurgery,potentantibiotic,andintensivesupportivetherapy[2~5].LipidAisthemaintox… 相似文献
9.
Yuh-Shan Ho 《Adsorption》2004,10(2):151-158
The kinetics of four sorption systems, Cu/tree fern, Pb/tree fern, AB9/activated clay and BR18/activated clay have been studied based on the assumption of a pseudo-second order rate law. Pseudo-isotherms using the pseudo-second order kinetic expression constant have been developed to describe the four liquid-solid sorption systems. The experimental results have been analyzed using a pseudo-Langmuir and a pseudo-Redlich-Peterson isotherm. Both isotherms were found to represent the measured sorption data well. According to the evaluation using the pseudo-Langmuir equation, the monolayer sorption capacities were obtained to be 13.9, 46.6, 124 and 105 mg g–1 for copper, lead, AB9 and BR18 respectively. 相似文献
10.