全文获取类型
收费全文 | 15024篇 |
免费 | 866篇 |
国内免费 | 1509篇 |
专业分类
化学 | 12256篇 |
晶体学 | 173篇 |
力学 | 64篇 |
综合类 | 33篇 |
数学 | 3031篇 |
物理学 | 1842篇 |
出版年
2024年 | 14篇 |
2023年 | 127篇 |
2022年 | 199篇 |
2021年 | 280篇 |
2020年 | 394篇 |
2019年 | 393篇 |
2018年 | 358篇 |
2017年 | 427篇 |
2016年 | 377篇 |
2015年 | 366篇 |
2014年 | 580篇 |
2013年 | 1373篇 |
2012年 | 698篇 |
2011年 | 874篇 |
2010年 | 798篇 |
2009年 | 1025篇 |
2008年 | 1120篇 |
2007年 | 1137篇 |
2006年 | 983篇 |
2005年 | 891篇 |
2004年 | 780篇 |
2003年 | 659篇 |
2002年 | 430篇 |
2001年 | 397篇 |
2000年 | 368篇 |
1999年 | 331篇 |
1998年 | 286篇 |
1997年 | 210篇 |
1996年 | 192篇 |
1995年 | 208篇 |
1994年 | 205篇 |
1993年 | 165篇 |
1992年 | 148篇 |
1991年 | 102篇 |
1990年 | 66篇 |
1989年 | 53篇 |
1988年 | 62篇 |
1987年 | 40篇 |
1986年 | 38篇 |
1985年 | 37篇 |
1984年 | 37篇 |
1983年 | 18篇 |
1982年 | 36篇 |
1981年 | 24篇 |
1980年 | 27篇 |
1979年 | 23篇 |
1978年 | 13篇 |
1977年 | 6篇 |
1976年 | 9篇 |
1974年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Caesium carbonate supported on hydroxyapatite‐encapsulated Ni0.5Zn0.5Fe2O4 nanocrystallites as a novel magnetically basic catalyst for the one‐pot synthesis of pyrazolo[1,2‐b]phthalazine‐5,10‐diones 下载免费PDF全文
Behrooz Maleki Samaneh Barat Nam Chalaki Samaneh Sedigh Ashrafi Esmail Rezaee Seresht Farid Moeinpour Amir Khojastehnezhad Reza Tayebee 《应用有机金属化学》2015,29(5):290-295
A novel nanomagnetic basic catalyst of caesium carbonate supported on hydroxyapatite‐coated Ni0.5Zn0.5Fe2O4 magnetic nanoparticles (Ni0.5Zn0.5Fe2O4@HAP‐Cs2CO3) was prepared. This new catalyst was fully characterized using Fourier transform infrared spectroscopy, transmission and scanning electron microscopy, X‐ray diffraction and vibrating sample magnetometry techniques, and then the catalytic activity of this catalyst was investigated in the synthesis of 1H‐pyrazolo[1,2‐b]phthalazine‐5,10‐dione derivatives. Also, Ni0.5Zn0.5Fe2O4@HAP‐Cs2CO3 could be reused at least five times without significant loss of activity and could be recovered easily by applying an external magnet. Thus, the developed nanomagnetic catalyst is potentially useful for the green and economic production of organic compounds. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
2.
Peng-Yan Gui Xiao-Hui Yan Wen-Juan Yuan Yuan-Liang Ma Xiao Ding Shuai Liu 《Natural product research》2019,33(19):2830-2836
A new A, D-seco limonoid, named 12-acetyloxyperforatin (1), along with three known ones, were isolated from the leaves of Harrisonia perforata. Their structures were elucidated on the basis of spectroscopic analysis, including extensive NMR techniques and computational modelling. These compounds showed no inhibitory activity against the 11β-HSD1 enzyme. 相似文献
3.
Double Michael additions of lithium enolaie of 1,4-dioxaspiro[4.5]dec-6-en-8-one to four acrylates afforded bicyclo[2.2.2]octan-2-ones with high regio- and stereoselectivities in moderate yields. 相似文献
4.
杂多酸催化合成乙酸乙酯 总被引:14,自引:0,他引:14
回流吸附法制备的负载型12-钨磷酸(HPW/C)是合成乙酸乙酯的高效催化剂。最佳反应条件下乙醇转化率达96%,酯化选择性100%。催化剂的高活性是由于HPW在活性炭上高度分散,使活性位增多,有效酸量增大。HPW/C还具有热稳定性高和不易流失等优点。 相似文献
5.
V. L. Topunov 《Acta Appl Math》1989,16(2):191-206
In this paper, an application of the Riquer-Thomas-Janet theory is described for the problem of transforming a system of partial differential equations into a passive form, i.e., to a special form which contains explicitly both the equations of the initial system and all their nontrivial differential consequences. This special representation of a system markedly facilitates the subsequent integration of the corresponding differential equations. In this paper, the modern approach to the indicated problem is presented. This is the approach adopted in the Knuth-Bendix procedure [13] for critical-pair/completion and then Buchberger's algorithm for completion of polynomial ideal bases [13] (or, alternatively, for the construction of Groebner bases for ideals in a differential operator ring [14]). The algorithm of reduction to the passive form for linear system of partial differential equations and its implementation in the algorithmic language REFAL, as well as the capabilities of the corresponding program, are outlined. Examples illustrating the power and efficiency of the system are presented. 相似文献
6.
For z1,z2,z3∈Zn, the tristance d3(z1,z2,z3) is a generalization of the L1-distance on Zn to a quantity that reflects the relative dispersion of three points rather than two. A tristance anticodeAd of diameter d is a subset of Zn with the property that d3(z1,z2,z3)?d for all z1,z2,z3∈Ad. An anticode is optimal if it has the largest possible cardinality for its diameter d. We determine the cardinality and completely classify the optimal tristance anticodes in Z2 for all diameters d?1. We then generalize this result to two related distance models: a different distance structure on Z2 where d(z1,z2)=1 if z1,z2 are adjacent either horizontally, vertically, or diagonally, and the distance structure obtained when Z2 is replaced by the hexagonal lattice A2. We also investigate optimal tristance anticodes in Z3 and optimal quadristance anticodes in Z2, and provide bounds on their cardinality. We conclude with a brief discussion of the applications of our results to multi-dimensional interleaving schemes and to connectivity loci in the game of Go. 相似文献
7.
Let A be a symmetric matrix of size n×n with entries in some (commutative) field K. We study the possibility of decomposing A into two blocks by conjugation by an orthogonal matrix T∈Matn(K). We say that A is absolutely indecomposable if it is indecomposable over every extension of the base field. If K is formally real then every symmetric matrix A diagonalizes orthogonally over the real closure of K. Assume that K is a not formally real and of level s. We prove that in Matn(K) there exist symmetric, absolutely indecomposable matrices iff n is congruent to 0, 1 or −1 modulo 2s. 相似文献
8.
5‐Amino‐4‐methyl‐2‐phenyl‐6‐substitutedfuro[2,3‐d]pyrimidines ( 2a‐c ) were reacted with 2,5‐dimethoxytetrahydrfuran to afford the pyrrolyl derivatives 3a‐c . Compound 3a was chosen as intermediate for the synthesis of poly fused heterocycles incorporated furopyrimidines moiety 4–11 . Some of the synthesized compounds were screened for their antibacterial and antifungal activities. 相似文献
9.
In this paper, the influence functions and limiting distributions of the canonical correlations and coefficients based on affine equivariant scatter matrices are developed for elliptically symmetric distributions. General formulas for limiting variances and covariances of the canonical correlations and canonical vectors based on scatter matrices are obtained. Also the use of the so-called shape matrices in canonical analysis is investigated. The scatter and shape matrices based on the affine equivariant Sign Covariance Matrix as well as the Tyler's shape matrix serve as examples. Their finite sample and limiting efficiencies are compared to those of the Minimum Covariance Determinant estimators and S-estimator through theoretical and simulation studies. The theory is illustrated by an example. 相似文献
10.
A practical access to alkyl- and aryl-substituted (E)-2-(azidomethyl)alkenoates and related azido compounds from the corresponding allylic bromides in aqueous acetone is described. An alternative method to obtain the starting bromides based on heterogeneous catalysis under mild conditions was also investigated. 相似文献