Reaction Engineering Aspects of α-l,4-D-Glucan Phosphorylase Catalysis

Some important process properties of α-l,4-D-ghican phosphorylases isolated from the bacteriumCorynebacterium callunae and potato tubers (Solatium tuberosum) were compared. Apart from minor differences in their stability and specificity (represented by the maximum degree of maltodextrin conversion) and a 10-fold higher affinity of the plant phosphorylase for maltodextrin (K _M of 1.3 g/L at 300 mM of orthophosphate), the performances of both enzymes in a continuous ultrafiltration membrane reactor were almost identical. Product synthesis was carried out over a time course of 300–400 h in the presence or absence of auxiliary pullulanase (increasing the accessibility of the glucan substrate for phosphorolytic attack up to 15–20%). The effect of varied dilution rate and reaction temperature on the resulting productivities was quantitated, and a maximum operational temperature of 40°C was identified.     

由季戊四醇合成季戊四硫醇的新方法

以季戊四醇为原料,先合成四对甲苯磺酸季戊四醇酯,然后四对甲苯磺酸季戊四醇酯与硫氰酸钾在N,N-二甲基甲酰胺中加热反应,生成了2,3,7,8-四硫螺[4,4]壬烷,2,3,7,8-四硫螺[4,4]壬烷经四氢化铝锂还原、酸化,得到季戊四硫醇.产物结构经熔点、红外光谱、质子核磁共振谱、拉曼光谱鉴定.     

The James constant for the <Emphasis Type="Italic">l</Emphasis><Subscript>3</Subscript> − <Emphasis Type="Italic">l</Emphasis><Subscript>1</Subscript> space

In this note, the exact value of the James constant for the l₃-l₁ space is obtained, J(l₃-l₁)=1.5573…. This result improves the known inequality, J(l₃-l₁)≤4/³√10, which was given by Dhompongsa, Piraisangjun and Saejung.     

3-(2'-苯基-1', 2', 3'-连三唑-4'-基)-6-烷基/芳基-均三唑并[3, 4-b]-1, 3, 4-噻二唑的合成

研究了3-(2'-苯基-1', 2', 3'-连三唑-4'-基)-4-氨基-5-巯基-1, 2, 4-三唑(1)与取代苯甲酸和脂肪酸(2a-r)在POCl3催化下的反应, 共合成得到18个新的3-(2'-苯基-1', 2', 3'-连三唑-4'-基)-6-烷基/芳基-均三唑并[3, 4-b]-1, 3, 4-噻二唑(3a-r), 经元素分析,IR, 1H NMR和MS进行了结构确证。     

二溴对甲基偶氮溴羧与钡显色反应的研究与应用

研究了新显色剂二溴对甲基偶氮溴羧与钡显色反应的条件。在磷酸介质中,试剂与钡形成2:1的络合物,最大吸收波长为610nm,摩尔吸光系数为2.13×10~4L·mol~(-1)·cm~(-1),钡量在0～20μg/25ml范围内符合比耳定律。两倍的锶和五倍的钛不干扰,钙的允许量较大,方法用于直接测定钛酸钡烧结物中微量钡,结果满意。     

利用salen型荧光探针测定Cr3+

研究了salen型席夫结构的荧光探针N,N’-二(2-羟基-1-萘甲醛)-l,2-苯二胺(NAPPDIH)对Cr3+的响应。Cr3+能够使该探针的荧光猝灭。研究表明,在pH3.5(乙酸胺-盐酸)和DMSO/H2O(V/V,8:2)的条件下,8.0×10-6 mol/L的Cr3+可以导致NAPPDIH 65%的荧光猝灭。并且,Cr3+的浓度在5.0×10-7～8.0×10-6 mol/L的范围内,与荧光强度的变化值呈良好的线性关系,检出限为3.7×10-7 mol/L。方法可用于直接检测水样中的Cr3+。     

荧光法测定土壤中硼

研究了2-[(5′-羧基-2′-砷酸基苯)偶氮]-1,8-二羟基-3,6-萘二磺酸(5-CarAsA-1)与硼的荧光性能。硼与试剂形成1:2的强荧光配合物,其λ_(ex)/λ_(em)=240nm/381nm,B(Ⅲ)量在0～0.16mg·L~(-1)范围内呈良好线性关系。方法检出限为2μg·L~(-1)。建立了测定缴量硼的新方法。方法应用于土壤中微量硼的测定,结果满意。     

杂多核配位荧光增敏法测定痕量铍

研究了新荧光试剂２－「５－羧基－２－胂酸基苯偶氮」－１,８－二羟基－３,６－萘二碘酸与铍络合的荧光性能。铍与试剂形成荧光络全物,在硼砂介质啼生增敏效应,据此建立了测定痕量铍的新方法。Ｂｅ（Ⅱ）浓度在０－０．１２ｍｇ／Ｌ范围内一荧光哟度呈良好线性关系,方法检测限为０．０７６μｇ／ＬＢｅ（Ⅱ）,用于水及铜基合金样中的痕量铍的测定,结果满意。     

Fluorodaturatin und Homofluorodaturatin—zwei neue β-Carbolinderivate in Samen von

In the transverse section of the seeds ofDatura stramonium L. var.stramonium a conspicuous sea-green fluorescence under UV-light (365 nm) can be observed. Thinlayer chromatography of a methanolic extract shows many blue and sea-green fluorescing substances, the main component being a polar, sea-green fluorescing compound. This substance is characteristic for all of the four varieties ofDatura stramonium L., and therefore of taxonomic interest. Isolation was tried by means of different chromatographic techniques. Combination of column chromatography and preparative thinlayer chromatography allowed the isolation of the main product, which was shown to consist of two substances (GF andGFa). Application of chemical and spectroscopic methods established the structure ofGF, named Fluorodaturatin, as 2,3,5,6-Tetrahydro-9-hydroxy-1H-pyrido-[1,2,3-l, m]--carboline-3-one. The second substanceGFa, called Homofluorodaturatin, was identified as analogue ofGF and the structure could be determined as 1,2,3,4,6,7-Hexahydro-10-hydroxyazepino-[1,2,3-l, m]--carboline-4-one.

Teil der DissertationI. Maier, Universität Wien, 1981; Auszugsweise vorgetragen bei der 2. Wissenschaftlichen Tagung der Österreichischen Pharmazeutischen Gesellschaft, 17. bis 19. Mai 1981, Graz.     

基于l1-l2范数的块稀疏信号重构

压缩感知(compressed sensing,CS) 是一种全新的信息采集与处理的理论框架,借助信号内在的稀疏性或可压缩性,可以从小规模的线性、非自适应的测量中通过求解非线性优化问题重构原信号.块稀疏信号是一种具有块结构的信号,即信号的非零元是成块出现的.受YIN Peng-hang, LOU Yi-fei, HE Qi等提出的l_1-2范数最小化方法的启发,将基于l₁-l₂范数的稀疏重构算法推广到块稀疏模型,证明了块稀疏模型下l₁-l₂范数的相关性质,建立了基于l₁-l₂范数的块稀疏信号精确重构的充分条件,并通过DCA(difference of convex functions algorithm) 和ADMM(alternating direction method of multipliers)给出了求解块稀疏模型下l₁-l₂范数的迭代方法.数值实验表明,基于l₁-l₂范数的块稀疏重构算法比其他块稀疏重构算法具有更高的重构成功率.