INTROMISSION OF WATER-REPELLENT AND HYDROSCOPIC PROPERTIES SIMULTANEOUSLY TO PP BY PLASMA DISCHARGE METHOD

Plasma-induced surface graft copolymerization of acrylic acid on polypropylene non-woven fabric (PP-g-AA) and polypropylene membrane were reported. The extents of grafting were controlled by the plasma and polymerization condition. Hexadecyltrimethyl ammonium bromide was then coupled with the carboxyl group of PP-g-AA to obtain a polyion complex (PIC). At last, CF4 plasma was used to give PICs hydrophobic property. The moisture regain and water-repellency of the processed PICs was investigated. The surfaces were characterized using ATR FT-IR and XPS. The result indicates that the products have very high ability to adsorb moisture, even better than cotton fiber. At the same time, the products show excellent hydrophobic property, which can‘t be wetted by those reagents whose surface tensions were higher than 327mN/m.     

Modeling the interaction of solitary waves and semi-circular breakwaters by using unsteady reynolds equations

A vertical 2 -D numerical wave model was developed based on unsteady Reynolds equations. In this model, the k-epsilon models were used to close the Reynolds equations, and volume of fluid( VOF) method was used to reconstruct the free surface. The model was verified by experimental data. Then the model was used to simulate solitary wave interaction with submerged, alternative submerged and emerged semi-circular breakwaters. The process of velocity field, pressure field and the wave surface near the breakwaters was obtained. It is found that when the semi-circular breakwater is submerged, a large vortex will be generated at the bottom of the lee side wall of the breakwater ; when the still water depth is equal to the radius of the semi-circular breakwater, a pair of large vortices will be generated near the shoreward wall of the semi-circular breakwater due to wave impacting, but the velocity near the bottom of the lee side wall of the breakwater is always relatively small. When the semi-circular breakwater is emerged, and solitary wave cannot overtop it, the solitary wave surface will run up and down secondarily during reflecting from the breakwater. It can be further used to estate the diffusing and transportation of the contamination and transportation of suspended sediment.     

紫外光固化的聚氨酯－丙烯酸酯－纤维素复合膜

再生纤维素膜(甘蔗渣浆制)表面直接用紫外光固化聚氨酯-丙烯酸酯制备出防水性复合膜。由红外光谱和扫描电镜研究了复合膜的结构。同时,测定了膜的防水性、力学性能、水汽透过性和尺寸稳定性。实验结果表明,当聚氨酯：丙烯酸酯为40:55(质量比),在400W紫外光下固化5min制得的复合膜具有致密的表面结构和较好的性能,该膜经水浸泡后其断裂强度可达干膜的90%,浸水收缩率和膨胀率均小于2.5%,水汽渗透量仅为再生纤维素膜的1/4.由此表明复合膜的防水性和尺寸稳定性明显提高。此外,该复合膜在可见光区的透光率在80%～90%之间,而且对紫外光有屏蔽作用。     

基于MAP-PRF复合的新型创口敷料合成及毒性研究

针对创口处理和修复中保护创面、防止感染和促进愈合等问题,基于仿生合成MAP粘合材料防水、快速闭合创口及生物源PRF快速止血、促进愈合的特性,设计并合成一种新型MAP-PRF复合创口敷料。采用^1H NMR表征材料结构,UV-Vis验证MAP聚氨酯侧链邻二酚粘合单元引入,GPC表征聚合材料分子量分布。细胞毒性分析和热分析数据表明:MAP-PRF复合材料的热稳定性良好、毒性低,可进一步用于生物医药领域的软组织快速粘合修复及硬组织粘接。     

防水型碳化钨气体扩散电极的研究

碳化钨(WC)以高硬度、高耐磨性的特性历来深受治金学家重视,常用它制造刀具、量具和模具,近二十余年才将其作为催化剂加以研究.这些年来,人们已发现WC催化剂具有较强的耐酸性、良好的导电性和电催化活性,且不受任何浓度的一氧化碳和几个PPM的硫化氢中毒,在加氢和脱氢方面,某些性质很类似于铂,故颇受人们关注. 本工作采用与常规不同的制备方法,制成高活性碳化钨粉末催化剂,曾先后对WC粉末在不同气氛中的热稳定性、几种溶液中的电化学稳定性及其阳极氧化机理进行了研究,并将WC粉末用作电催化剂制成半防水型氢电极,以碳为氯电极材料,单电池电极面积0.1m~2,由10个单电池按复极式串联成20D余瓦的氢-氯燃料电池组,在工厂中连续运行三个月,WC氢电极性能保持稳定。在此基础上,为进一步提高WC氢电极活性,提出了防水型WC气体扩散电极的研究.本文主要报导碳化钨粉末制备中物相组成、比表面及其电极制备条件对电极活性的影响,以及该电极的主要性能。     

屋面防水问题的探讨

针对造成屋面渗漏的常见原因,就屋面防水的几个构造层次：结构层、隔离层、刚性防水层、卷材防水层等提出了改进方法及预防措施．     

Dynamic analysis of underground composite structures under explosion loading

In selecting rational types of underground structures resisting explosion, in order to improve stress states of the structural section and make full use of material strength of each part of the section, the research method of composite structures is presented.Adopting the analysis method of micro-section free body, equilibrium equations, constraint equations and deformation coordination equations are given. Making use of the concept of generalized work and directly introducing Lagrange multiplier specific in physical meaning,the validity of the constructed generalized functional is proved by using variation method.The rational rigidity matching relationship of composite structure section is presentedthrough example calculations.     

防水倒吸减压抽滤装置的改进

用单向流动器代替传统抽滤装置中的安全瓶,分离化学实验中的固-液混合物,改进后的抽滤装置操作简单,有效解决了防水倒流问题。     

橡胶基多效协同自修复防水复合材料的研究

制备了环氧树脂改性高吸水纤维,随后将改性纤维与天然橡胶通过混、流延、压延、硫化等工艺制备了环境友好型三层复合自修复防水材料,通过SEM、FT-IR、TY-8000万能材料试验机、BTS-001电动不透水仪等考察了自修复防水材料的微观结构、机械性能、抗氧化性能、自修复性能及防渗透性能等。结果表明,高吸水纤维有助于提高其拉伸强度,最大拉伸强度为1.83MPa,断裂伸长率达到700%以上。防水材料完全切断,自修复24h后,其切口部分无可见痕迹,裂口完全愈合,且24h内无水滴渗漏。自修复48h后拉伸强度可达原始材料的2.36倍,断裂伸长率达到80%左右。