Studies on Monodispersed Microspheres of Zinc Sulfide Doped with Mn^2＋

In this paper,zinc acetate,manganese acetate and thiacetamide are used as raw materials to successfully synthesize monodispersed ZnS:Mn2+ microspheres by using hydrothermal method and taking P123 surfactant as a template. The products were characterized by XRD,STEM,FT-IR and N2 adsorption-desorption. And the results show that the diameter of this microsphere is 1.0 μm or so,which is larger than that of ZnS microsphere without Mn2+ doping,and it has monodispersion,smooth surface and uniform size. The doping of Mn2+ does not obviously change the structure of monodispersed ZnS microsphere. The photoluminescence peak lies in a wide band ranging from 450 to 650 nm,and the microspheres emit orange light; with the increase of Mn2+ concentration,fluorescence intensity of ZnS:Mn2+ microsphere changes,and when the mole ratio of Mn2+:Zn2+ is 0.3:1,the fluorescence intensity is the strongest.     

对211例类风湿关节炎患者微量元素的测定

用同位素激发Ｘ射线荧光分析对２１１例类风湿关节炎患者发中１０种常量及微量元素测定，以探索类风湿关节病与微量元素之间的关系．结果表明：全部女性患者发锌含量明显降低，除３０～３９岁及５０～５９岁年龄组Ｐ＜０．０５外，其余各组均Ｐ＜０．０１。而２０～２９岁男性组患者发锌含量也低，Ｐ＜０．０１。男女患者各组发锶含量较对照组均低，且有明显差异（除男性２０～２９岁组及５０￣５９岁组Ｐ＜０．０５，其余各组均ｐ＜０．０１）。提示类风湿关节病患者发中锌、锶含量较正常人低。因此，如临床上补充锌和锶元素，可能是有效治疗类风湿关节病的新途径．     

小儿血清锌的检测

1988～990年测定了肇庆市9个县10岁以下健康儿童血清微量元素锌的含量，并探讨了缺锌与健康的关系，5930例中，其正常范围在11．6～15．4μmol/L；低于正常值低限者2365例，占39．73%，缺锌与男女性别无关，缺锌与生长发育、贫血都有非常密切关系。     

血清碱性磷酸酶对人体缺锌、补锌的估价作用

概述了碱性磷酸酶（AKP）的基本结构、分型及其血清AKP变化的病理、生理因素，并回顾与总结了多年来国内外学者对血清AKP活力与锌(Zn)含量之间关系的基础与临床研究状况。     

Hydrothermal Synthesis and Crystal Structure of a Zinc Complex： [Zn2.5（phen）（BDC）2（OH）] （phen = 1,10-Phenanthroline,BDC = Benzene-1,4-dicarboxylic Acid）^①

A metal-organic coordination polymer [ZnE.s（phen）（BDC）2（OH）]2 （phen = 1,10- phenanthroline, BDC = benzene-1,4-dicarboxylic acid） 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analyses and IR spectroscopy. The complex crystallizes in the triclinic system, space group PI with a = 11.199（2）, b = 11.593（2）, c = 11.865（3）/A, α= 99.330（1）, β = 111.506（1）, γ = 104.804（1）^o, V= 1328.4（5）A^3, Dc= 1.722 g/cm^3, Z = 1, Mr = 1377.82, F（000） = 692,μ（MoKa） = 2.306 mm^-1, S = 1.093, R= 0.0281 and wR = 0.0756 for 4179 observed reflections （I 〉 2σ（/））. The coordination polyhedron around Zn（II） can be described as a tetrahedron, trigonal bipyramid and octahedron. It is worth noting that the crystal structure of 1 is composed of tetranuclear zinc clusters linked by {ZnO6} units.     

锌锰元素对男性性功能障碍的双向治疗作用

对男性性功能障碍诸如阳痿、阳强症，以临床实例为据，用中西两种医学理论为指导，突出分析微量元素锌、锰的治疗作用，初步验证出锌锰元素在治疗阳痿、阳强这类病证，在对交感神经和副交感神经调控方面有着双向治疗作用。     

铁、锌元素与脑的营养保健

微量元素对脑功能有着十分重要的作用。只需极少量就能明显改善其生理功能,过去一直未予特别注意,直到最近一连串的科学实验结果,才显示了这些微量元素惊人的威力,这些提高智力的微量元素中最值得注意的有2种:铁与锌。微量元素能提高智力,有的增强记忆力,有的促进思考速度,有利     

多元素营养鸡蛋的研制及临床应用研究

研制出钙、铁、锌含量（×１０－６）在４３０～４９）、２２～３２、２３～２６的多元素营养鸡蛋，临床上给６１名儿童、２０名孕妇、８例糖尿病人、６例肿瘤病人连续食用２个月后复查，指血钙、铁、锌值和血红蛋白水平均有提高，尤其对处于生理需要量增高时期的儿童、孕妇效果更明显（Ｐ＜０．０１）．表明选用鸡蛋作为补充钙、铁、锌元素的载体．是防治人体必需元素缺乏的一个良好途径。还就食物中各元素问的相互作用、体内代谢过程进行了讨论．     

缺锌儿童的舌苔改变及其分析

从中医舌诊角度对193例缺锌儿童舌苔改变作了临床观察及理论分析,认为人体内微量元素锌与舌苔之间存在着有机联系,锌的吸收障碍由脾、胃功能失司引起,相应地引起舌苔的改变,大多数表现为“地图舌”。发现“地图舌”患儿在其他临床症状方面与机体“缺锌”状态表现出来的症状相似,而且病因相同,在病理机制及组织学方面曲解释一致,且用“锌”制剂治疗后,“地图舌”明显很快地消失或得到改变。笔者提出,“地图舌”可以作为机体缺锌的临床体征之一,本文为此提供了初步的理论依据。     

Vacuum Ultraviolet Excited Photoluminescence Properties of Novel Na3Y9O3（BO3）8：Tb^3＋ Phosphor

The novel vacuum ultraviolet （VUV） excited Na3 Y9O3 （BO3）8：Tb^3＋ （NYOB：Tb^3＋） green phosphor is prepared. Strong VUV photoluminescence and high quenching concentration of Tb^3＋ （20 wt%） are observed in NYOB： Tb^3＋ and the strong emission are correlated with the unique layer-type structure of NYOB. All the characteristic 4 f - 5d transitions of Tb^3＋ and the host absorption band in VUV region are identified in the excitation spectrum. Based on the results, the energy levels scheme of Tb^3＋ in NYOB：Tb^3＋ is first established. This newly developed NYOB：Tb^3＋ phosphor shows excellent optical properties when compared with the commercial Zn2SiO4：Mn^2＋ and would be a potential VUV-excited green phosphor.