排序方式: 共有30条查询结果,搜索用时 31 毫秒
1.
运用层析法、结晶法从狭苞橐吾全草中分离得到艾里莫芬烷型倍半萜8β-hydroxyeremophil-7(11)-ene-12,8α(4β,6α)-diolide化合物,并通过质谱、核磁共振氢谱和碳谱、氢核-氢核相关谱、异核多量子相干谱和异核多键相干谱进行结构鉴定.其单晶经X射线衍射测试表明,其晶体属正交晶系,空间群为P212121,晶胞参数为: a=6.8519(5),b=10.7191(8),c=18.5942(14)A,V=1365.67(18) A3,Z=4,Dc=1.354 mg/m3.F(000)=592,μ=0.101 mm-1 相似文献
2.
Quan Xiang WE Xia LIU Yan Ping SHI 《中国化学快报》2005,16(11):1477-1480
A novel dimeric eremophilane, ligulolide B, was isolated from the alcoholic extract of the whole plant of Ligularia virgaurea spp. oligocephala. The structure was elucidated by various spectroscopic methods including intensive 2D NMR techniques (^1H-^1H COSY, gHMQC, gHMBC and ^1H-^1H NOESY) and HR-ESI-MS. 相似文献
3.
Two new pyrrolizidines named lankongensisine A (1), B (2) were isolated from the roots of Ligularia lankongensis collected in Lijiang, Yunnan, and their structures were established by spectroscopic analysis. 相似文献
4.
FuLinYAN AiXiaWANG ZhongJianJIA LeiHE 《中国化学快报》2003,14(12):1253-1254
A new isopropenyl benzofuran-type tetramer was isolated from the roots of ligularia stenocephala and its structure was established by spectroscopic methods. 相似文献
5.
6.
Xue Gao Zhong Jian Jia 《中国化学快报》2008,19(1):71-72
A new 8-O-4′-type neolignan named narynenol (1) was isolated from the roots of Ligularia narynensis. Its structure and the relative configurations were confirmed by spectroscopic data interpretation. 2007 Zhong Jian Jia. Published by Elsevier B.V. on behalf of Chinese Chemical Society, All rights reserved. 相似文献
7.
8.
Tong SHEN Wei Dong XIE Zhong Jian JIA 《中国化学快报》2005,16(9):1220-1222
Two new eremophilane sesquiterpenes, 15β-formic ether-6-oxo-furanoeremophilane (1) and 6α, 15β-epoxy eremophila-7(11)-en-8α, 12-olide (2) were isolation from the roots of Ligularia macrophylla. Their structures were deduced from spectroscopic methods and 2D NMR experiments. 相似文献
9.
8β-hydroxyeremophil-7(11)-ene-12,8α(4β,6α)-diolide was isolated from the Ligularia intermedia and char- acterized by MS, multi NMR and X-ray single crystal diffraction. Its crystal structure was determined as in a orthorhombic type, with space group P212121 with a=6.8519(5), b=10.7191(8), c=18.5942(14) oA, V =1365.67(18) oA3, Z=4, and the calculated density is 1.354 mg/m3. F(000)=592, μ=0.101 mm-1. 相似文献
10.
新疆萨吾尔地区两类花岗岩稀土元素特征 总被引:2,自引:2,他引:2
研究萨吾尔地区两类花岗岩(A型、 I型)的稀土元素特征. 两类花岗岩的稀土元素地球化学特征明显不同, 这与其所处的不同后碰撞构造演化阶段密切相关. 森塔斯岩体和沃肯萨拉岩体为形成于后碰撞阶段晚期挤压-拉张转换体制下的I型花岗岩, 稀土元素特征显示其岩浆演化过程中分离结晶作用不发育, 具幔源特征. 阔依塔斯岩体和恰其海岩体为形成于后碰撞结束阶段拉张体制下的A型花岗岩, 稀土元素特征显示其岩浆演化过程中分离结晶作用发育, 其稀土元素显示的一定的壳源特征应为幔源岩浆受地壳物质混染所致. 相似文献