柔韧性羧端基不饱和聚酯粉末涂料的研制

本文研制了粉末涂料用柔韧性羧端基不饱和聚酯树脂及其相应的环氧树脂固化的柔韧性不饱和聚酯粉末涂料，讨论了树脂合成，涂料制备及涂层性能，涂层的装饰性能特别是柔韧性能有了较大改善。     

白光有机发光二极管的研究进展

由于白光有机发光二极管(WOLED)具有效率高、亮度高、功耗低、视角广、响应速度快、主动发光、超薄超轻以及可柔性化等优异性能, 并在显示和照明领域有广阔的应用前景, 受到学者和业界的广泛重视而成为研究热点. 本文首先介绍了实现WOLED的不同方法, 然后从发光材料种类的角度, 阐述了全荧光WOLED、全磷光WOLED、基于荧光/磷光杂化WOLED以及延迟荧光WOLED近年来的研究进展, 并结合我们研究团队最近的工作详细地介绍了不同高性能WOLED的器件结构、设计思想、工作原理、物理机制以及发光过程; 接着, 简单介绍了柔性WOLED最近研究进展; 最后探讨了WOLED目前存在的问题及其未来的发展趋势.     

柔性四硫富瓦烯(TTF)的制备、结构及自组装

具有适中氧化还原电位和良好柔韧性的平面有机电子给体是有机分子材料和自组装化学的研究基础.本文以易得的原料和简便的操作方法合成了一系列含有亚乙二氧/硫基和邻苯二巯基的不对称四硫富瓦烯（TTF）衍生物.两种取代基团的引入明显增大了TTF的氧化还原半电位,进而提高了有机电子给体的光电稳定性.与刚性TTF不同本文所设计和合成出的TTF衍生物是一类具有一定柔韧性的有机电子给体.实验证明,通过在TTF外围引入C-S键可明显增强化合物的柔韧性.在复合物（TTF4）（C₆₀）中,TTF4的中心C₂S₄平面与外围C₂S₂平面之间的二面角比中性分子的增加了5.87°,这充分说明柔韧性有机电子给体能够在自组装化学中发挥独特的作用.     

美研究者制成新型太阳能电池

美国南加州大学的研究人员最近成功研制出一种柔韧性很好的碳原子薄膜透明材料，并用它制作出有机光伏电池．研究人员说，这种碳原子材料用途广泛，比如有望用来生产太阳能窗帘和自行发电的衣服．     

石墨掺杂聚四氟乙烯基耐磨涂料在制冷机中的试验研究

通过选用两种不同的石墨掺杂聚四氟乙烯基耐磨涂料,对斯特林制冷机的关键部件活塞进行了喷涂,并分别对该类型的耐磨涂料的性能分别进行摩擦系数、附着力、柔韧性和抗冲击性能的测试,以分析耐磨涂料的涂层性能效果。     

Syntheses,Crystal Structures and Thermal Stabilities of Two New Mixed Ligated Coordination Polymers with Rigid Dicarboxylate and Flexile N-donor Ligands

Two new coordination polymers,[Co(BIPA)(bpp)](1) and [Zn(BIPA)(bpp)(H2O)](2)(H2BIPA = 5-bromoisophthalic acid,bpp = 1,3-di(4-pyridyl)propane) have been synthesized via hydrothermal reactions.The two compounds were characterized by elemental analysis,IR spectra,TG analysis and single-crystal X-ray determination.Compound 1 crystallizes in triclinic,space group P1 with a = 9.0316(13),b = 10.1179(14),c = 11.8884(17) ,α = 68.022(2),β = 84.749(2),γ = 77.791(2)°,V = 984.5(2) 3,Z = 2,C21H17BrN2O4Co,Mr = 500.21,Dc = 1.687 g.cm-3,μ = 2.932 mm-1,S = 0.981,F(000) = 502,R = 0.0440 and wR = 0.1357 for 3773 observed reflections with I > 2σ(I).Compound 2 crystallizes in the monoclinic system,space group P21/c with a = 7.8466(10),b = 27.483(4),c = 9.6583(13) ,β = 96.663(3)°,V = 2068.8(5) 3,Z = 4,C21H19BrN2O5Zn,Mr = 524.66,Dc = 1.685 g.cm-3,μ = 3.155 mm-1,S = 0.969,F(000) = 1056,R = 0.0441 and wR = 0.0517 for 4058 observed reflections with I > 2σ(I).The two compounds are constructed from the BIPA2-and bpp ligands but they exhibit different kinds of one-dimensional chain structures.In 1,the chains are composed of the Co(Ⅱ) ions and BIPA2-ligands,and the chains are further extended into a 2D framework structure by π...π interactions of the benzene rings from the BIPA2-ligands between the adjacent chains.In 2,the chains are made up of Zn(Ⅱ) ions and BIPA2-ligands through another fashion,and the chains are further linked via hydrogen bonding interactions to yield a two-dimensional supramolecular layer structure.Furthermore,the bpp ligand features two kinds of different coordination modes in the two compounds.     

自润滑耐磨涂层在制冷机中的批次试验研究北大核心

通过对斯特林制冷机现用的自润滑耐磨涂层材料进行三批次的喷涂试验,对该三批次的耐磨涂料在同一条件下喷涂后,分别按照国家标准进行摩擦系数、附着力、柔韧性和抗冲击强度的测试,结果得出摩擦系数稳定在0.14-0.15,附着力稳定在0级,柔韧性稳定在1mm,抗冲击强度稳定在12N·m。即三批次耐磨涂层的摩擦系数、附着力、柔韧性和抗冲击强度稳定性较好。     

柔性有机发光二极管柔性电极薄膜的研究进展

柔性有机发光二极管(FOLED)具有机械柔韧性好、低功耗、驱动电压低、高色域、宽视角、响应速度快等优点,在柔性显示、柔性照明、可穿戴设备等方面显示了广阔的应用前景。虽然柔性OLED研究与应用已经有了很大程度的进展,但要实现产业化,稳定性、效率及其电极等方面都需要进一步完善。本文介绍了柔性衬底与导电电极的制备及处理方法,并对柔性OLED的发展趋势进行了展望。     

Laser Feedback Technique for Precise Retardation Measurements

A simple and precise retardation measurement based on laser feedback is demonstrated. The measurement principle is based on polarization flipping induced by optical feedback from an external birefringence cavity. The measured wave plate is located in the external cavity. When the length of the external cavity is tuned, the polarization states of laser will flip between two eigenstates, and the position of polarization flipping in one period of intensity modulation will vary with retardation of the wave plate. The duty ratio of two eigenstates is used to determine the retardation. Main advantages of the technique are that it is compact, low cost, fast and flexible. Especially, it is insensitive to a fluctuation of laser intensity and is suitable for on-line measurement. The experimental results have shown that the measurement uncertainty is better than 0.03° in the range 30°-150°.     

吸塑成型用有机玻璃板柔韧性的研究

采用一种单体IA与甲基丙烯酸甲酯 (MMA)共聚对聚甲基丙烯酸甲酯 (PMMA)进行内增塑以改善PMMA的柔韧性 ,并与外增塑剂邻苯二甲酸二丁脂 (DBP)作比较 ,考察其对PMMA性能的影响。结果表明 ,IA能改善PMMA的柔韧性 ,但效果不及DBP好 ,但是IA在耐挥发性方面却比DBP优越 ,对PMMA其他方面性能的影响则与DBP相似