全文获取类型
收费全文 | 35342篇 |
免费 | 4271篇 |
国内免费 | 3131篇 |
专业分类
化学 | 17412篇 |
晶体学 | 300篇 |
力学 | 1475篇 |
综合类 | 248篇 |
数学 | 2722篇 |
物理学 | 9252篇 |
综合类 | 11335篇 |
出版年
2024年 | 141篇 |
2023年 | 648篇 |
2022年 | 1011篇 |
2021年 | 1045篇 |
2020年 | 1133篇 |
2019年 | 963篇 |
2018年 | 842篇 |
2017年 | 811篇 |
2016年 | 1199篇 |
2015年 | 1268篇 |
2014年 | 1625篇 |
2013年 | 1977篇 |
2012年 | 2459篇 |
2011年 | 2485篇 |
2010年 | 1750篇 |
2009年 | 1796篇 |
2008年 | 2007篇 |
2007年 | 1967篇 |
2006年 | 1743篇 |
2005年 | 1520篇 |
2004年 | 1217篇 |
2003年 | 1015篇 |
2002年 | 939篇 |
2001年 | 860篇 |
2000年 | 876篇 |
1999年 | 1245篇 |
1998年 | 1016篇 |
1997年 | 1019篇 |
1996年 | 922篇 |
1995年 | 810篇 |
1994年 | 767篇 |
1993年 | 663篇 |
1992年 | 598篇 |
1991年 | 549篇 |
1990年 | 499篇 |
1989年 | 386篇 |
1988年 | 324篇 |
1987年 | 214篇 |
1986年 | 177篇 |
1985年 | 96篇 |
1984年 | 40篇 |
1983年 | 44篇 |
1982年 | 38篇 |
1981年 | 21篇 |
1980年 | 8篇 |
1979年 | 4篇 |
1976年 | 1篇 |
1959年 | 1篇 |
1958年 | 1篇 |
1957年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 387 毫秒
1.
Potential Analysis - We establish some exact asymptotic results for a matching problem with respect to a family of beta distributions. Let X1,…,Xn be independent random variables with common... 相似文献
2.
Gürbüzbalaban Mert Ruszczyński Andrzej Zhu Landi 《Journal of Optimization Theory and Applications》2022,194(3):1014-1041
Journal of Optimization Theory and Applications - We consider a distributionally robust formulation of stochastic optimization problems arising in statistical learning, where robustness is with... 相似文献
3.
Hua Saixiang Zhu Huichao Wang Xiao Wu Mingyuan Wu Qingyun Liu Jiuyi Yang Jianjun Zhang Jianan 《Cellulose (London, England)》2022,29(13):7465-7475
Cellulose - Ultraviolet (UV) protective cotton fabric is a convenient and reliable way to protect human body from sunlight. Herein, a polymerizable UV-absorber,... 相似文献
4.
This study is to numerically test the interfacial instability of ferrofluid flow under the presence of a vacuum magnetic field. The ferrofluid parabolized stability equations(PSEs) are derived from the ferrofluid stability equations and the Rosensweig equations, and the characteristic values of the ferrofluid PSEs are given to describe the ellipticity of ferrofluid flow. Three numerical models representing specific cases considering with/without a vacuum magnetic field or viscosity are created to mathematically examine the interfacial instability by the computation of characteristic values. Numerical investigation shows strong dependence of the basic characteristic of ferrofluid Rayleigh-Taylor instability(RTI) on viscosity of ferrofluid and independence of the vacuum magnetic field.For the shock wave striking helium bubble, the magnetic field is not able to trigger the symmetry breaking of bubble but change the speed of the bubble movement. In the process of droplet formation from a submerged orifice, the collision between the droplet and the liquid surface causes symmetry breaking. Both the viscosity and the magnetic field exacerbate symmetry breaking. The computational results agree with the published experimental results. 相似文献
5.
Yi-Tong Xu Tian-Yang Zhang Zheng Li Xiang-Nan Liu Yuan-Cheng Zhu Wei-Wei Zhao Hong-Yuan Chen Jing-Juan Xu 《Electroanalysis》2022,34(6):947-955
Photoelectrochemical (PEC) cytosensors, a combination of the PEC process and the living-cell assay, have emerged as a powerful tool in the analytical and biological science. This mini review provides a brief introduction of this arena and summaries the key steps about the development of PEC cytosensors with representative examples, followed by future prospects based on our own opinions. 相似文献
6.
A liquid dewetting method for the determination of the viscoelastic properties of ultrathin polymer films has been extended to study thickness effects on the properties of ultrathin polycarbonate (PC) films. PC films with film thicknesses ranging from 4 to 299 nm were placed on glycerol at temperatures from below the macroscopic glass transition temperature (Tg) to above it with the dewetting responses being monitored. It is found that the isothermal creep results for films of the same thickness, but dewetted at different temperatures can be superposed into one master curve, which is consistent with the fact of PC being a thermorheologically simple material. Furthermore, the results show that the Tg of PC thin films is thickness dependent, but the dependence is weaker than the results for freely standing films and similar to literature data for PC films supported on rigid substrates. It was also found that the rubbery plateau region for the PC films stiffens dramatically, but still less than what has been observed for freely standing polycarbonate films. The rubbery stiffening is discussed in terms of a recently reported model that relates macroscopic segmental dynamics with the stiffening. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1559–1566 相似文献
7.
Bingjie Chen Dr. Lianhai Zu Dr. Yao Liu Dr. Ruijing Meng Yutong Feng Prof. Chengxin Peng Feng Zhu Tianzi Hao Jiajia Ru Prof. Yonggang Wang Prof. Jinhu Yang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(8):3161-3166
Incorporating nanoscale Si into a carbon matrix with high dispersity is desirable for the preparation of lithium-ion batteries (LIBs) but remains challenging. A space-confined catalytic strategy is proposed for direct superassembly of Si nanodots within a carbon (Si NDs⊂C) framework by copyrolysis of triphenyltin hydride (TPT) and diphenylsilane (DPS), where Sn atomic clusters created from TPT pyrolysis serve as the catalyst for DPS pyrolysis and Si catalytic growth. The use of Sn atomic cluster catalysts alters the reaction pathway to avoid SiC generation and enable formation of Si NDs with reduced dimensions. A typical Si NDs⊂C framework demonstrates a remarkable comprehensive performance comparable to other Si-based high-performance half LIBs, and higher energy densities compared to commercial full LIBs, as a consequence of the high dispersity of Si NDs with low lithiation stress. Supported by mechanic simulations, this study paves the way for construction of Si/C composites suitable for applications in future energy technologies. 相似文献
8.
Dr. Yong-Sheng Wei Dr. Liming Sun Miao Wang Dr. Jinhua Hong Dr. Lianli Zou Hongwen Liu Dr. Yu Wang Dr. Mei Zhang Dr. Zheng Liu Prof. Yinwei Li Prof. Satoshi Horike Prof. Kazu Suenaga Prof. Qiang Xu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(37):16147-16156
Understanding the thermal aggregation behavior of metal atoms is important for the synthesis of supported metal clusters. Here, derived from a metal–organic framework encapsulating a trinuclear FeIII2FeII complex (denoted as Fe3) within the channels, a well-defined nitrogen-doped carbon layer is fabricated as an ideal support for stabilizing the generated iron nanoclusters. Atomic replacement of FeII by other metal(II) ions (e.g., ZnII/CoII) via synthesizing isostructural trinuclear-complex precursors (Fe2Zn/Fe2Co), namely the “heteroatom modulator approach”, is inhibiting the aggregation of Fe atoms toward nanoclusters with formation of a stable iron dimer in an optimal metal–nitrogen moiety, clearly identified by direct transmission electron microscopy and X-ray absorption fine structure analysis. The supported iron dimer, serving as cooperative metal–metal site, acts as efficient oxygen evolution catalyst. Our findings offer an atomic insight to guide the future design of ultrasmall metal clusters bearing outstanding catalytic capabilities. 相似文献
9.
Journal of Thermal Analysis and Calorimetry - In the present work, pyrolysis kinetic mechanism was studied for regenerated cellulosic fiber (RCF) and composite RCF containing silicon/nitrogen flame... 相似文献
10.
Nonlinear Dynamics - Under investigation is a generalized (3 + 1)-dimensional variable- coefficient Kadomtsev– Petviashvili equation in fluid mechanics. Various exact analytical solutions are... 相似文献