全文获取类型
收费全文 | 229篇 |
免费 | 5篇 |
国内免费 | 52篇 |
专业分类
化学 | 88篇 |
力学 | 8篇 |
综合类 | 3篇 |
数学 | 38篇 |
物理学 | 30篇 |
综合类 | 119篇 |
出版年
2023年 | 4篇 |
2022年 | 6篇 |
2021年 | 4篇 |
2020年 | 8篇 |
2019年 | 6篇 |
2018年 | 2篇 |
2017年 | 3篇 |
2016年 | 10篇 |
2015年 | 9篇 |
2014年 | 6篇 |
2013年 | 5篇 |
2012年 | 5篇 |
2011年 | 12篇 |
2010年 | 2篇 |
2009年 | 4篇 |
2008年 | 5篇 |
2007年 | 10篇 |
2006年 | 9篇 |
2005年 | 9篇 |
2004年 | 5篇 |
2003年 | 10篇 |
2002年 | 4篇 |
2001年 | 4篇 |
2000年 | 5篇 |
1999年 | 15篇 |
1998年 | 11篇 |
1997年 | 8篇 |
1996年 | 16篇 |
1995年 | 25篇 |
1994年 | 9篇 |
1993年 | 8篇 |
1992年 | 10篇 |
1991年 | 7篇 |
1990年 | 7篇 |
1989年 | 7篇 |
1988年 | 5篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1984年 | 1篇 |
排序方式: 共有286条查询结果,搜索用时 15 毫秒
1.
Dr. Ruijuan Yao Prof. Di Liu Dr. Huihui Wan Dr. Yongqiang Mei Jiahui Wang Dr. Rui Cai Dr. Huimin Zhang Dr. Yuzhen Zhao Dr. Zemin He 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(71):e202202269
By linking the carbazole unit to the nitrogen atom of acridone through phenyl or pyridyl, two compounds, named 10-(4-(9H-carbazol-9-yl)phenyl)acridin-9(10H)-one (AC-Ph-Cz) and 10-(5-(9H-carbazol-9-yl)pyridin-2-yl)acridin-9(10H)-one (AC-Py-Cz) were designed and synthesized. These two materials, characterized with highly twisted and rigid structure, good thermal stability, and balanced carrier-transporting properties, were employed as host materials for green phosphorescent and thermally activated delayed fluorescent organic light-emitting diodes (OLEDs). The carbazole group, despite its small contribution to the highest occupied molecular orbitals (HOMOs) of these two materials, plays an essential role as an intramolecular host in energy delivering and improving the hole transporting ability of these two hosts. The incorporation of the electron-deficient pyridyl group as a linking group slightly improves the electron transporting capability of AC-Py-Cz. The green phosphorescent OLED (PhOLED) based on AC-Py-Cz exhibited excellent device performance with a turn-on voltage of 2.5 V, a maximum power efficiency and an external quantum efficiency (ηext) of 89.8 lm W−1 and 25.2 %, respectively, benefitting from the better charge-balancing ability of AC-Py-Cz host due to the presence of the pyridyl bridge. More importantly, all the devices based on these two hosts showed low efficiency roll-off at high brightness due to the suppressed non-radiative transition in the emitting layer. In particular, the AC-Py-Cz-hosted green PhOLED exhibited an efficiency roll-off of 1.6 % from the maximum next at a high brightness of 1000 cd m−2 and a roll-off of 15.9 % at an extremely high brightness of 10000 cd m−2. This study manifests that acridone-based host materials have great potential in fabricating OLEDs with low efficiency roll-off. 相似文献
2.
本文研究并比较了分别以8-羟基喹啉和巯基苯骈噻唑为萃取剂,以活性硅胶为载体的柱式萃取色谱法对环境水中Zn、Cu、Pb、Cd、Fe、Co、Ni和Mn的最佳富集和洗脱条件。实验证明,后者明显优于前者。以巯基苯骈噻唑为萃取剂的色谱柱对金属元素的吸附具有快速、完全、寿命长和重现性好等特点。在pH=7~8之间回收率可达98%以上,富集倍数为200倍。 相似文献
3.
介绍一种用单片机控制的结构简单、成本低的正(余)弦函数发生器,论述了其基本原理,给出了硬件框图和软件框图,可用于计算机控制的调速系统中。 相似文献
4.
5.
库仑滴定法测定有机硅样品中的氮含量 总被引:3,自引:0,他引:3
本文利用库仑滴定法研究了高分子和低分子硅氮化合物及含氮有机硅样品中氮含量的测定,并研究和讨论了影响测定结果准确性的因素。 相似文献
6.
7.
[reaction: see text] A novel solid-phase synthesis of 1,2-dialkoxyindoles on SynPhase lanterns is described. A unique C-C bond formation involving a nucleophilic displacement of a solid-bound aryl fluorine by dimethyl malonate afforded the arylnitro methyl ester, which upon treatment with tin(II) chloride dihydrate gave the N-hydroxyindolone. Alkylation of the N-hydroxyindolones afforded the corresponding N-hydroxy-2-alkoxyindoles, which were further alkylated to give the 1,2-dialkoxyindole. A library of 64 (8R(1) x 8R(2)) discrete 1,2-dialkoxyindoles was prepared using a color encoding technique on SynPhase A-series lanterns. 相似文献
8.
含氢硅氧烷的硅氢加成反应 总被引:2,自引:0,他引:2
含氢硅氧烷的硅氢加成反应师彤,谢择民,王清正(中国科学院化学研究所北京100080)关键词含氢硅氧烷,二乙烯基四甲基二硅氧烷,硅氢加成反应,~1HNMR铂催化硅氢加成的机理~[1,2]、副反应 ̄[3,4]、聚合物性能 ̄[3,5]等均有报道,个别文献用粘?.. 相似文献
9.
Tyson L ChasseJoshua C Yohannan Namjin KimQun Li Zemin LiChristopher B Gorman 《Tetrahedron》2003,59(22):3853-3861
Examples of new dendrimers are presented. In the first, the effect on electron transfer rate attenuation is investigated for two dendrimer isomers that differ only in the linkage (ortho- versus meta-linked) of the phenyl ether units within one generation of the structure. Second, the effect of encapsulation on electrochemical and luminescence behavior of a new type of rhenium selenide cluster core dendrimer is illustrated. 相似文献
10.
文章对镇源金矿成矿溶液的组分特征.水化学类型.金的存在形式及淀出条件等进行了系统研究,提出了金的矿化分带模式. 相似文献