植物血清分类学研究

本文介绍了植物血清分类学的发展历史、意义、基本原理方法,在植物分类学中的应用以及作者对豆科山蚂蝗属(Desmodium)和长柄山蚂蝗属(Podo-carpium)的血清学研究情况,对植物血清分类学提出了理论依据并证实了实际应用价值。     

基于MCM-41分子筛表面的镱离子印迹聚合物的制备及其性能

运用离子印迹技术,以3-氯丙基三乙氧基硅烷为锚定剂,将功能单体直链聚乙烯亚胺(PEI)接枝在MCM-41分子筛表面,选择镱离子作为模板离子,以环氧氯丙烷交联制备出基于MCM-41表面的镱离子印迹聚合物Yb(Ⅲ)-IIP-PEI/MCM-41,并以同样的方法制备非离子印迹聚合物(NIP-PEI/MCM-41)。 利用傅里叶变换红外光谱仪和扫描电子显微镜等技术手段对Yb³⁺印迹聚合物进行表征,采用静态吸附法确定了Yb(Ⅲ)-IIP-PEI/MCM-41对Yb³⁺的最佳吸附条件及选择性吸附性能。 结果表明,Yb(Ⅲ)-IIP-PEI/MCM-41和NIP-PEI/MCM-41的最大吸附量分别为229.93和99.27 mg/g;印迹材料对Yb³⁺的吸附符合Langmuir模型;吸附平衡在40 min的时候基本可以达到,可以利用准二级动力学模型来描述其吸附过程;Yb(Ⅲ)-IIP-PEI/MCM-41对Yb³⁺具有较强的选择性,同时也具有很好的重复使用性能。 成功地将MCM-41和离子印迹聚合物的优点结合起来,制备出一种对稀土Yb离子既有高吸附量又有高选择性的吸附材料,为进一步将其应用在处理实际废水,分离回收低浓度稀土废水中的稀土元素等方面打下了基础。     

16MnR钢夹杂物的行为

系统地调查研究了１６ＭｎＲ钢在整个生产过程中钢中夹杂物的演变规律和清洁度水平,重点考察了钢锭中大型氧化物夹杂的类型,数量,分布,来源的形成,结果表明：钢锭中夹杂物主要是块状Ａｌ２Ｏ３,钢锭中大颗粒夹杂物主要来源于复合渣卷渣。     

New Temperature Integral Approximate Formula for Non-isothermal Kinetic Analysis

A new approximate formula for temperature integral is proposed. The linear dependence of the new fomula on x has been established. Combining this linear dependence and integration-by-parts, new equation for the evaluation of kinetic parameters has been obtained from the above dependence. The validity of this equation has been tested with data from numerical calculating. And its deviation from the values calculated by Simpson's numerical integrating was discussed. Compared with several published approximate formulae, this new one is much superior to all other approximations and is the most suitable solution for the evaluation of kinetic parameters from TG experiments. This revised version was published online in August 2006 with corrections to the Cover Date.     

Approximate formulae for calculation of the integral òT0Tmexp(-E/RT)dT

Summary In this paper two approximate formulae have been developed for calculation of the integral ò^T₀T^mexp(-E/RT)dT by using integration-by-parts approaches. They are in the following forms: I(m,T) = (RT^m+2)/(E+(m+2)RT)exp(-E/RT) I(m,T) = (RT^m+2)/(E+(m+2)(0.00099441E+0.93695599RT)exp(-E/RT) The validity of the two formulae has been confirmed and their accuracies have been tested with data from numerical calculating. In contrast to existing other integral methods, both the present approaches are simply used, accurate, and can be used for arbitrary values of m.     

同步荧光光谱分析中几个问题的探讨

通过实验阐明了同步荧光光谱与普通荧光光谱之间的关系，在此基础上讨论了溶剂散射光对同步荧光分析的影响以及同步荧光分析的灵敏度。     

Enthalpy change and mechanism of oxidation of o-phenylenediamine by hydrogen peroxide catalyzed by horseradish peroxidase

The hydrogen peroxide-oxidation of o-phenylenediamine (OPD) catalyzed by horseradish peroxidase (HRP) at 37 °C in 50 mM phosphate buffer (pH 7.0) was studied by calorimetry. The apparent molar reaction enthalpy with respect to OPD and hydrogen peroxide were −447 ± 8 kJ mol⁻¹ and −298 ± 9 kJ mol⁻¹, respectively. Oxidation of OPD by H₂O₂ catalyzed by HRP (1.25 nM) at pH 7.0 and 37 °C follows a ping-pong mechanism. The maximum rate V_max (0.91 ± 0.05 μM s⁻¹), Michaelis constant for OPD K_m,S (51 ± 3 μM), Michaelis constant for hydrogen peroxide Km,H₂O₂ (136 ± 8 μM), the catalytic constant k_cat (364 ± 18 s⁻¹) and the second-order rate constants k₊₁ = (2.7 ± 0.3) × 10⁶ M⁻¹ s⁻¹ and k₊₅ = (7.1 ± 0.8) × 10⁶ M⁻¹ s⁻¹ were obtained by the initial rate method.     

提高超声C扫描图像分辨率的插值方法研究

根据超声C扫描成像原理,分析了采样间隔对超声C扫描图像分辨率的影响.采用一种基于局部协方差特征的边缘自适应图像插值方法来提高C扫描图像的分辨率,同时将图像局部均方差作为边缘特征判据,使算法得到了简化.该方法根据低分辨率图像的局部协方差估计出高分辨率图像的插值加权系数,能够在放大图像的同时保留图像的边缘特征.试验结果表明,基于局部协方差特征的图像插值方法明显提高了C扫描图像分辨率,并且减小了边缘模糊效应,因此降低了采样间隔对图像分辨率的影响,提高了图像中缺陷分布评价结果的准确性.     

赣西北地区凸额蝗属一新种记述（直翅目：斑腿蝗科）

本文记述了江西省凸额蝗属一新种：宜丰凸额蝗Ｔｒａｕｌｉａ ｙｉｆｅｎｇｅｎｓｉｓ ｓｐ．ｎｏｖ．，该新种近似于短胫凸额蝗Ｔｒａｕｌｉａ ｂｒａｃｈｙｐｅｚａ Ｂｉ。     

燃气蒸汽联合循环燃料系统动力学建模的分析研究

为了提高燃气轮机联合循环动力学建模的精度和适用范围,对影响燃料量的因素进行全面分析.提出将燃料量作为复合自变量进行燃料系统建模的必要性,确立以燃料指令、分配系数、机组负荷、转速和燃料低位发热量作为其简单自变量,采用模块化的灰箱建模法建立燃料系统动态模型.对仿真与实际机组的燃料指令和流量之间的匹配关系进行了研究,提出以燃料设计热耗量为枢纽的仿真系统燃料流量修正方法,建立了更加精确的稳态模型,提高了联合循环动力学模型对于燃料种类变化的适应能力.利用所建立的模型对气、液燃料的切换、混烧过程及机组起动过程进行了数字仿真,分析研究了其动态特性,表明该模型的精度和适应性得到明显的提高.