介绍一个与材料相关的研究型综合化学实验——壳聚糖的制备与表征

在中国科学技术大学夏季学期的研究型实验课程"化学科研基础训练"中开设"壳聚糖的制备与表征"综合实验,以龙虾壳为原料,通过除蛋白、脱盐、脱色、脱乙酰等一系列反应,制备得到目标产物壳聚糖。运用红外光谱、核磁共振仪、黏度法、滴定等对产品的结构及性能进行表征。     

Determination,residue and risk assessment of trifloxystrobin,trifloxystrobin acid and tebuconazole in Chinese rice consumption

A simple and rapid analytical method for the detection of trifloxystrobin, trifloxystrobin acid and tebuconazole in soil, brown rice, paddy plants and rice hulls was established and validated by liquid chromatography with tandem mass spectrometry. Acceptable linearity (R² > 0.99), accuracy (average recoveries of 74.3–108.5%) and precision (intra- and inter-day relative standard deviations of 0.9–8.8%) were obtained using the developed determination approach. In the field trial, the half-lives of trifloxystrobin and tebuconazole in paddy plants were 5.7–8.3 days in three locations throughout China, and the terminal residue concentrations of trifloxystrobin and tebuconazole were <100 and 500 μg/kg (maximum residue limits set by China), respectively, at harvest, which indicated that, based on the recommended application procedure, trifloxystrobin and tebuconazole are safe for use on rice. The risk assessment results demonstrated that, owing to risk quotient values of both fungicides being <100%, the potential risk of trifloxystrobin and tebuconazole on rice was acceptable for Chinese consumers. These data could provide supporting information for the proper use and safety evaluation of trifloxystrobin and tebuconazole in rice.     

Simultaneous determination of major components of Huangqi–Honghua extract in rat plasma using LC–MS/MS and application to a pharmacokinetic study

A sensitive and reliable LC–MS/MS method was developed and validated for simultaneous quantification of the major components of Huangqi–Honghua extact in rat plasma, including hydroxysafflor yellow A (HSYA), astragaloside IV (ASIV), calycosin‐7‐O‐β‐d ‐glucoside (CAG), calycosin, calycosin‐3′‐O‐glucuronide (C‐3′‐G) and calycosin‐3′‐O‐sulfate (C‐3′‐S). After extraction by protein precipitation with acetonitrile and methanol from plasma, the analytes were separated on a Hypersil BDS C₁₈ column by gradient elution with acetonitrile and 5 mM ammonium acetate. The detection was carried out on a triple quadrupole tandem mass spectrometer equipped with electrospray ionization source switched between negative and positive modes. HSYA was monitored in negative ionization mode from 0 to 4.9 min, and ASIV, CAG, calycosin, C‐3′‐G and C‐3′‐S were determined in positive ionization mode from 4.9 to 10 min. The lower limits of quantification of the analytes were 6.25 ng/mL for HSYA, 0.781 ng/mL for CAG and 1.56 ng/mL for ASIV and calycosin. The intra‐ and inter‐assay precision (RSD) values were within 13.43%, and accuracy (RE) ranged from ?8.75 to 9.92%. The validated method was then applied to the pharmacokinetic study of HSYA, ASIV, CAG, calycosin, C‐3′‐G and C‐3′‐S in rat after an oral administration of Huangqi–Honghua extract.     

井下WPT技术机理研究

为解决井下无线传感器电池容量受限的问题,根据井下无线传感器带壮分布的特点,提出了井下无线运动充电的思想.构建充电系统模型,讨论了充电信道建模、接收微带天线设计、多天线协作三个方面的技术路线.本文在研究井下微波输能传输特性的基础上,探讨在低功率密度下,多天线协作的移动无线充电技术在井下运动式充电特性,使用这个技术对无线传感器节点充电,解决井下无线传感器网络能量补充问题,突破现有节点单纯依靠电池供电的局限.     

轧制法生产高复基比不锈复合钢板和钢带的开发应用

不锈钢复合板既具有不锈钢的耐腐蚀性、耐磨性、抗磁性、豪华性和装饰性;又具碳钢良好的可焊性、成型性、拉延性和导热性,还可节约镍铬合金、降低成本,因而具有广阔的发展前景,值得大力推广应用.     

芝麻素类型木脂素的合成研究Ⅳ2－苯基呋喃3，4－二羧酸二甲脂与格氏试剂反应的研究

研究了２－苯基呋喃－３，４－二羧酸二甲酯（２）与格氏试剂苯基溴化镁等（３）反应，生成酮基酸酯２－苯基－４－苯甲酰基呋喃－３－羧酸甲酯（１）的条件和方法。     

现代教育技术在物理教学中的应用

现代教育技术与课程教学的整合,是我国面向21世纪基础教育教学改革的新视点。笔者就物理教学中应用现代教育技术的实践作初步探讨。     

信息技术与物理课程整合的几个层面

《基础教育课程改革纲要》要求 :要“大力推进信息技术在教学过程中的普遍应用 ,促进信息技术与学科课程的整合 ,逐步实现教学内容的呈现方式、学生的学习方式、教师的教学方式和师生互动方式的变革 ,充分发挥信息的优势 ,为学生的学习和发展提供丰富多彩的教育环境和有力的学习工具 .”可见 :信息技术与其它课程的整合是课程教学中把信息技术、信息资源、信息方法和课程内容有机结合 ,是一种新型的教学方式 .下面讨论几个具体层面上的问题 :1　信息技术与物理教学目标和内容的整合面对新世纪 ,信息处理的技能、学习能力、问题解决能力、与…     

一种计算稀土材料陷阱深度的新方法

表征陷阱材料的主要物理量是陷阱深度, 准确计算出陷阱深度对于研究陷阱材料具有重要的意义. 从能带模型出发, 利用速率方程分析了整个热释光过程, 提出了一种计算稀土材料陷阱深度的新方法, 替代以往利用单分子或双分子近似计算陷阱深度的方法. 以SrAl2O4：Eu^2＋, Dy^3＋及Sr4Al14O25：Eu^2＋, Dy^3＋材料为研究对象, 计算了陷阱深度. 研究表明, 这种计算方法能更准确、真实地描述其物理过程.