八烷基氮杂对环仿三氟甲基磺酸盐的合成

从四氮杂对环仿（ｔｅｔｒａａｚａｐａｒａｃｙｃｌｏｐｈａｎｅ）合成得到四烷基氮杂对环仿，再以三氟甲基磺酸甲酯作甲基化试剂，合成得到２种未见文献报道的八烷基氮杂对环仿三氟甲基磺酸盐，提供了新的人工模拟酶有机化合物。     

The nonmarine environment of Quaternary foraminifers in Yanghuzhuang, China: Evidence from boron and strontium isotopes

The concentrations and isotopic compositions of boron and strontium of Quaternary foraminifera and bivalve fossils collected in the Yanghuzhuang section of Yanqing, Beijing and of modern gastropods living in the Guishul River and of river water were measured. The concentrations and isotopic compositions of Quaternary foraminifera and bivalve fossils differed from those of modern marine foraminifers and were similar to those of modern terrestrial gastropods from the Guishui Riven These results Indicate that early Quaternary foraminifera in the Yanghuzhuang section inhabited a nonmarine environment and that these foraminifera were not the result of a transgression or sea flooding. The foraminifera were not special halobios and can survive in the terrestrial condition that resembled those of the ocean.     

Construction and visualization of high-resolution three-dimensional anatomical structure datasets for Chinese digital human

The objective of the China Digital Human Project （CDH） is to digitize and visualize the anatomical structures of human body. In the project, a database with information of morphology, physical characteristics and physiological function will be constructed. The raw data of CDH which was completed in the Southern Medical University is employed. In Huazhong University of Science and Technology （HUST）, the frozen section images are preprocessed, segmented, labeled in accordance with the major organs and tissues of human beings, and reconstructed into three-dimensional （3D） models in parallel on high performance computing clusters （HPC）. Some visualization software for 2D atlas and 3D models are developed based on the new dataset with high resolution （0.1 mm× 0.1 mm × 0.2 mm）. In order to share, release and popularize the above work, a website （www.vch.org.cn） is online. The dataset is one of the most important parts in the national information database and the medical infrastructure.     

Properties of polyethylene glycol (23) lauryl ether with cetyltrimethylammonium bromide in mixed aqueous solutions studied by self-diffusion coefficient NMR

NMR self-diffusion coefficient measurements have been used to study the properties of polyethylene glycol (23) lauryl ether (Brij-35) with cetyltrimethylammonium bromide (CTAB) in the mixed aqueous solutions with different mole fractions of CTAB. By fitting the self-diffusion coefficients to the two-state exchange model, the critical micelle concentrations of the two solutes in the mixed solutions (cmc*1 and cmc*2) were obtained. The critical mixed micelle concentrations (cmc*) were then evaluated by the sum of cmc*1 and cmc*2, which are in good agreement with the results measured by the surface tension method. The cmc* values are lower than those of the ideal case of mixing, which indicates that the behavior of the CTAB/Brij-35 system is nonideal. Moderate interactions between CTAB and Brij-35 in their mixtures can be deduced from the interaction parameters (betaM) based on the cmc* obtained by the NMR self-diffusion method. The compositions (x1) of the mixed micelles at different total surfactant concentrations were also evaluated. By using these results, a possible mechanism of mixed micellar formation and a picture of the formation of nonsimultaneous CTAB/Brij-35 binary mixed micelle were proposed. In contrast to the case of CTAB/TX-100 system, Brij-35 molecules have a tendency to form micelles first at any mole fraction of CTAB. The mixed micellar self-diffusion coefficients (Dm) increase slightly at lower CTAB molar ratios, and then speed up with increasing CTAB mole fraction.     

Major factors controlling the formation of middle and large marine carbonate stratigraphic fields

Marine carbonate oil and gas fields have become an important exploration area in China and even across the world. Their formation, distribution and enrichment are special owing to the complexity of the deposition, diagenesis and accumulation, which is caused by the multiplicity of the carbonate depositional environments and facies, huge extensions of formation time and burial depth, complication of diagenetic evolution, heterogeneity as well as the development of pores, caves and fractures affected by various factors. Oil and gas accumulations in carbonate rocks are not strictly controlled by the second-order structure belt. Most of them, under certain structural settings, are controlled by sedimentary diagenesis and its favorable facies. The hydrocarbon reservoir type is predominantly stratigraphic. Based on the worldwide researches of carbonate fields, the paper concludes that 7 main factors control the formation and distribution of middle-large marine carbonate stratigraphic fields.     

甲基丙烯酸甲酯-萘乙烯共聚物的核磁共振研究——I.甲基丙烯酸甲酯-萘乙烯共聚物的2D NMR谱研究

用500MHz超导核磁共振谱仪测定了甲基丙烯酸甲酯-萘乙烯共聚物的二维异核多量子化学位移相关谱和二维相敏NOESY谱,由此归属了共聚物的碳谱和氢谱,结果表明,聚合物是以无规共聚物为主,其中有一部分是以头-头(或尾-尾)相接的.文中还以反门控去偶测得其共聚含量.     

Reservoir-forming age and its exploration sisnificance to stratisraphic reservoirs in southern Songliao Basin

Despite many studies concerning the forming age, evolution characteristics and the age of petroleum charging in the Fuxin upheaval of southern Songliao Basin, no consensus has been reached so far. This paper presents the first K-Ar dating of autogenetic illite from stratigraphic petroleum reservoirs in the Fuyu oil layer of the Fuxin upheaval belt. Isotopic test and age calculation were carried out based on the separation and purification of illite mineral, X-diffraction analysis and the detection of scanning electron microscopy. The evolution characteristics of structure, sedimentation, reservoir-forming about the Fuxin upheaval belt were interpreted in terms of the synthetical analysis of ＂six-type geological history＂ evolution in southern Songliao Basin. The geologic background of petroleum evolution and reservoir formation are similar in the entire central depression region of southern Songliao Basin. The Changling sag and the Fuxin upheaval belt brought about obvious upheaval-sag separation after the hydrocarbon-generation peak of K2qn^1 and the main reservoir-forming period of the Fuyu oil layer, namely reservoir-forming happened before the Fuxin upheaval belt extensively raised. The reservoirs have three characteristics： the hydrocarbon source rock above the reservoir, the oil source in the locality, and the vertical migration. The geological cognition is corrected, that is, oil source came from the Changling sag and migrated from the side direction. The bulk process of petroleum charging in the stratigraphic hydrocarbon reservoirs in the Fuxin upheaval belt of southern Songliao Basin is determined according to the isotopic age of autogenetic illite in combination with the method of fluid inclusions. The cognition is helpful to exactly evaluate the resource potential and exploration direction in the Fuxin upheaval belt, Changling sag and their peripheral areas. The present results indicate that the combination of the two methods （the K-Ar dating of autogenetic illite and fluid inclusions） is an effective way to lay bare petroleum charging history and ascertain reservoir age.     

Synthesis and properties of novel soluble poly(aryl amine ketone)s as high-performance polymers

A series of poly(aryl amine ketone)s have been obtained by the condensation polymerization of different aromatic dibromides with different primary aromatic diamines via palladium-catalyzed aryl amination reaction. The structures of polymers are characterized by means of FT-IR, 1H NMR spectroscopy, and elemental analysis. The results show an agreement with the proposed structures. DSC and TG measurements show that polymers possess high glass transition temperature (Tg>170℃) and good thermal stability with high decomposition temperatures (TD>450℃). These novel polymers also exhibit good mechanical behaviors and good solubility.     

甲基丙烯酸甲酯-萘乙烯共聚物的核磁共振研究──1.甲基丙烯酸甲酯-萘乙烯共聚物的2D NMR谱研究

用500MHz超导核磁共振谱仪测定了甲基丙烯酸甲酯-萘乙烯共聚物的二维异核多量子化学位移相关谱和二维相敏NOESY谱，由此归属了共聚物的碳谱和氢谱，结果表明，聚合物是以无规共聚物为主，其中有一部分是以头一头（或尾一尾）相接的．文中还以反门控去偶测得其共聚含量．