全文获取类型
收费全文 | 21541篇 |
免费 | 2607篇 |
国内免费 | 2182篇 |
专业分类
化学 | 10718篇 |
晶体学 | 175篇 |
力学 | 814篇 |
综合类 | 140篇 |
数学 | 1825篇 |
物理学 | 5129篇 |
综合类 | 7529篇 |
出版年
2024年 | 80篇 |
2023年 | 390篇 |
2022年 | 596篇 |
2021年 | 629篇 |
2020年 | 673篇 |
2019年 | 616篇 |
2018年 | 521篇 |
2017年 | 455篇 |
2016年 | 762篇 |
2015年 | 816篇 |
2014年 | 1060篇 |
2013年 | 1265篇 |
2012年 | 1465篇 |
2011年 | 1457篇 |
2010年 | 1112篇 |
2009年 | 996篇 |
2008年 | 1159篇 |
2007年 | 1116篇 |
2006年 | 1024篇 |
2005年 | 921篇 |
2004年 | 747篇 |
2003年 | 755篇 |
2002年 | 902篇 |
2001年 | 846篇 |
2000年 | 600篇 |
1999年 | 723篇 |
1998年 | 591篇 |
1997年 | 553篇 |
1996年 | 555篇 |
1995年 | 463篇 |
1994年 | 436篇 |
1993年 | 388篇 |
1992年 | 315篇 |
1991年 | 295篇 |
1990年 | 240篇 |
1989年 | 225篇 |
1988年 | 194篇 |
1987年 | 119篇 |
1986年 | 68篇 |
1985年 | 59篇 |
1984年 | 48篇 |
1983年 | 25篇 |
1982年 | 21篇 |
1981年 | 14篇 |
1980年 | 14篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1973年 | 2篇 |
1957年 | 4篇 |
1955年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
1.
2.
In the view of substrate availability, atomic efficiency and cost, directly using arenols as coupling partners in cross‐coupling, would be one of the most attractive goals. Up to date, many efforts have been made to activate the C—O bond of phenols with different strategies, for example, through in‐situ formed intermediates, through a catalytic reductive dearomatization‐condensation‐rearomatization sequence or catalytic deoxygenation. In this review, we summarized recent advances in cross‐couplings of arenols as the electrophiles via C—O activation. 相似文献
3.
Polypyrrole Shell@3D‐Ni Metal Core Structured Electrodes for High‐Performance Supercapacitors
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Gao‐Feng Chen Yu‐Zhi Su Pan‐Yong Kuang Zhao‐Qing Liu Dao‐Yi Chen Xu Wu Nan Li Prof. Shi‐Zhang Qiao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(12):4614-4621
Three‐dimensional (3D) nanometal films serving as current collectors have attracted much interest recently owing to their promising application in high‐performance supercapacitors. In the process of the electrochemical reaction, the 3D structure can provide a short diffusion path for fast ion transport, and the highly conductive nanometal may serve as a backbone for facile electron transfer. In this work, a novel polypyrrole (PPy) shell@3D‐Ni‐core composite is developed to enhance the electrochemical performance of conventional PPy. With the introduction of a Ni metal core, the as‐prepared material exhibits a high specific capacitance (726 F g?1 at a charge/discharge rate of 1 A g?1), good rate capability (a decay of 33 % in Csp with charge/discharge rates increasing from 1 to 20 A g?1), and high cycle stability (only a small decrease of 4.2 % in Csp after 1000 cycles at a scan rate of 100 mV s?1). Furthermore, an aqueous symmetric supercapacitor device is fabricated by using the as‐prepared composite as electrodes; the device demonstrates a high energy density (≈21.2 Wh kg?1) and superior long‐term cycle ability (only 4.4 % and 18.6 % loss in Csp after 2000 and 5000 cycles, respectively). 相似文献
4.
In order to improve the efficiency of 3D near-surface velocity model building, we develop a layer-stripping method using seismic first-arrival times. The velocity model within a Common Mid-Point (CMP) ... 相似文献
5.
Two new homosecoiridoids, named loniaceticiridoside (1) and lonimalondialiridoside (2), were isolated from an aqueous extract of the flower buds of Lonicera japonica. Their structures including the absolute configuration were determined by extensive spectroscopic studies, especially by 2D NMR and CD data analysis. A proposed biosynthetic pathway and preliminary investigations of the biological activity of compounds 1 and 2 are also discussed. 相似文献
6.
Studies on metabolism of total glucosides of paeony from Paeoniae Radix Alba in rats by UPLC‐Q‐TOF‐MS/MS
下载免费PDF全文
![点击此处可从《Biomedical chromatography : BMC》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Wenli Cao Xinguo Wang Haojie Li Xuliang Shi Wencheng Fan Shaohua Zhao Minyan Liu Liying Niu 《Biomedical chromatography : BMC》2015,29(11):1769-1779
Total glucosides of paeony are the active constituents of Paeoniae Radix Alba. In this study, a novel strategy was proposed to find more metabolites and the differences between paeoniflorin, albiflorin and total glucosides of paeony (TGP). This strategy was characterized as follows: firstly, the animals were divided into three groups (paeoniflorin, albiflorin and TGP) to identify the source of TGP metabolites from paeoniflorin or albiflorin; secondly, a generic information‐dependent acquisition scan for the low‐level metabolites was triggered by the multiple mass defect filter and dynamic background subtraction; thirdly, the metabolites were identified with a combination of data‐processing methods including mass defect filtering, neutral loss filtering and product ion filtering; finally, a comparative study was used in the metabolism of paeoniflorin, albiflorin and TGP. Based on the strategy, 18 metabolites of TGP, 10 metabolites of paeoniflorin and 13 metabolites of albiflorin were identified respectively. The results indicated that the hydrolysis, conjugation reaction and oxidization were the major metabolic pathways, and the metabolic sites were the glycosidic linkage, the ester bond and the benzene ring. This study is first to explore the metabolism of TGP, and these findings enhance our understanding of the metabolism and the interactions of paeoniflrin and albiflorin in TGP. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
7.
PXI在测控系统中的应用 总被引:3,自引:0,他引:3
随着有关PXI总线的规范和产品的推出,由于优良的性能指标和适宜的价格,使其受到各相关行业的广泛关注。对风洞测控系统的结构和系统配置作了具体的阐述,并对PXI总线在具体使用中的效果和特点作了较详细的介绍。 相似文献
8.
高校图书馆数字化与现代化服务 总被引:1,自引:0,他引:1
互联网改变了图书馆的运作方式,网络已成为高校图书馆信息采集、存储和传播的主要途径。介绍了高校图书馆数字化与现代化服务的主要内容,对高校图书馆数字化与现代化服务的功能与特点、技术关键、对策与措施及发展趋势进行了深入的探讨。 相似文献
9.
本研究用膏剂法进行无孔渗硅研究,透射电镜、电子探针和M351腐蚀仪分析证实:获得了致密、无孔隙、具有良好耐磨性和耐腐蚀性的渗硅层,并分析了渗硅层形成机理及表层疏松层以及内部孔隙成因。 相似文献
10.