首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   21735篇
  免费   2615篇
  国内免费   2199篇
化学   10724篇
晶体学   175篇
力学   826篇
综合类   138篇
数学   1972篇
物理学   5134篇
综合类   7580篇
  2024年   80篇
  2023年   388篇
  2022年   596篇
  2021年   638篇
  2020年   675篇
  2019年   622篇
  2018年   523篇
  2017年   457篇
  2016年   767篇
  2015年   818篇
  2014年   1068篇
  2013年   1269篇
  2012年   1474篇
  2011年   1464篇
  2010年   1123篇
  2009年   1002篇
  2008年   1165篇
  2007年   1120篇
  2006年   1033篇
  2005年   928篇
  2004年   750篇
  2003年   770篇
  2002年   915篇
  2001年   855篇
  2000年   617篇
  1999年   736篇
  1998年   601篇
  1997年   564篇
  1996年   558篇
  1995年   466篇
  1994年   440篇
  1993年   394篇
  1992年   318篇
  1991年   298篇
  1990年   241篇
  1989年   228篇
  1988年   196篇
  1987年   120篇
  1986年   68篇
  1985年   60篇
  1984年   48篇
  1983年   25篇
  1982年   21篇
  1981年   15篇
  1980年   14篇
  1978年   3篇
  1977年   3篇
  1973年   2篇
  1957年   4篇
  1955年   2篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Let p ∈ [1, ∞), q ∈ [1, ∞), α∈ R, and s be a non-negative integer. Inspired by the space JNp introduced by John and Nirenberg(1961) and the space B introduced by Bourgain et al.(2015), we introduce a special John-Nirenberg-Campanato space JNcon(p,q,s) over Rn or a given cube of R;with finite side length via congruent subcubes, which are of some amalgam features. The limit space of such spaces as p →∞ is just the Campanato space which coincides with the space BMO(the space of functions with bounded mean oscillations)when α = 0. Moreover, a vanishing subspace of this new space is introduced, and its equivalent characterization is established as well, which is a counterpart of the known characterization for the classical space VMO(the space of functions with vanishing mean oscillations) over Rn or a given cube of Rn with finite side length.Furthermore, some VMO-H1-BMO-type results for this new space are also obtained, which are based on the aforementioned vanishing subspaces and the Hardy-type space defined via congruent cubes in this article. The geometrical properties of both the Euclidean space via its dyadic system and congruent cubes play a key role in the proofs of all these results.  相似文献   
2.
3.
In the view of substrate availability, atomic efficiency and cost, directly using arenols as coupling partners in cross‐coupling, would be one of the most attractive goals. Up to date, many efforts have been made to activate the C—O bond of phenols with different strategies, for example, through in‐situ formed intermediates, through a catalytic reductive dearomatization‐condensation‐rearomatization sequence or catalytic deoxygenation. In this review, we summarized recent advances in cross‐couplings of arenols as the electrophiles via C—O activation.  相似文献   
4.
Three‐dimensional (3D) nanometal films serving as current collectors have attracted much interest recently owing to their promising application in high‐performance supercapacitors. In the process of the electrochemical reaction, the 3D structure can provide a short diffusion path for fast ion transport, and the highly conductive nanometal may serve as a backbone for facile electron transfer. In this work, a novel polypyrrole (PPy) shell@3D‐Ni‐core composite is developed to enhance the electrochemical performance of conventional PPy. With the introduction of a Ni metal core, the as‐prepared material exhibits a high specific capacitance (726 F g?1 at a charge/discharge rate of 1 A g?1), good rate capability (a decay of 33 % in Csp with charge/discharge rates increasing from 1 to 20 A g?1), and high cycle stability (only a small decrease of 4.2 % in Csp after 1000 cycles at a scan rate of 100 mV s?1). Furthermore, an aqueous symmetric supercapacitor device is fabricated by using the as‐prepared composite as electrodes; the device demonstrates a high energy density (≈21.2 Wh kg?1) and superior long‐term cycle ability (only 4.4 % and 18.6 % loss in Csp after 2000 and 5000 cycles, respectively).  相似文献   
5.
In order to improve the efficiency of 3D near-surface velocity model building, we develop a layer-stripping method using seismic first-arrival times. The velocity model within a Common Mid-Point (CMP) ...  相似文献   
6.
Two new homosecoiridoids, named loniaceticiridoside (1) and lonimalondialiridoside (2), were isolated from an aqueous extract of the flower buds of Lonicera japonica. Their structures including the absolute configuration were determined by extensive spectroscopic studies, especially by 2D NMR and CD data analysis. A proposed biosynthetic pathway and preliminary investigations of the biological activity of compounds 1 and 2 are also discussed.  相似文献   
7.
Total glucosides of paeony are the active constituents of Paeoniae Radix Alba. In this study, a novel strategy was proposed to find more metabolites and the differences between paeoniflorin, albiflorin and total glucosides of paeony (TGP). This strategy was characterized as follows: firstly, the animals were divided into three groups (paeoniflorin, albiflorin and TGP) to identify the source of TGP metabolites from paeoniflorin or albiflorin; secondly, a generic information‐dependent acquisition scan for the low‐level metabolites was triggered by the multiple mass defect filter and dynamic background subtraction; thirdly, the metabolites were identified with a combination of data‐processing methods including mass defect filtering, neutral loss filtering and product ion filtering; finally, a comparative study was used in the metabolism of paeoniflorin, albiflorin and TGP. Based on the strategy, 18 metabolites of TGP, 10 metabolites of paeoniflorin and 13 metabolites of albiflorin were identified respectively. The results indicated that the hydrolysis, conjugation reaction and oxidization were the major metabolic pathways, and the metabolic sites were the glycosidic linkage, the ester bond and the benzene ring. This study is first to explore the metabolism of TGP, and these findings enhance our understanding of the metabolism and the interactions of paeoniflrin and albiflorin in TGP. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
8.
PXI在测控系统中的应用   总被引:3,自引:0,他引:3  
随着有关PXI总线的规范和产品的推出,由于优良的性能指标和适宜的价格,使其受到各相关行业的广泛关注。对风洞测控系统的结构和系统配置作了具体的阐述,并对PXI总线在具体使用中的效果和特点作了较详细的介绍。  相似文献   
9.
高校图书馆数字化与现代化服务   总被引:1,自引:0,他引:1  
互联网改变了图书馆的运作方式,网络已成为高校图书馆信息采集、存储和传播的主要途径。介绍了高校图书馆数字化与现代化服务的主要内容,对高校图书馆数字化与现代化服务的功能与特点、技术关键、对策与措施及发展趋势进行了深入的探讨。  相似文献   
10.
张旬  孙瑾 《山东科学》1992,5(2):30-35
本研究用膏剂法进行无孔渗硅研究,透射电镜、电子探针和M351腐蚀仪分析证实:获得了致密、无孔隙、具有良好耐磨性和耐腐蚀性的渗硅层,并分析了渗硅层形成机理及表层疏松层以及内部孔隙成因。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号