Formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber blends: Effects of preparation method,composition, and thermal condition

The effects of preparation method, composition, and thermal condition on formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber (iPP/EPR) blends were studied using modulated differential scanning calorimeter (MDSC), wide angle X‐ray diffraction (WAXD), and phase contrast microscopy (PCM). It was found that the α‐iPP and β‐iPP can simultaneity form in the melt‐blended samples, whereas only α‐iPP exists in the solution‐blended samples. The results show that the formation of β‐iPP in the melt‐blended samples is related to the crystallization temperature and the β‐iPP generally diminishes and finally vanishes when the crystallization temperature moves far from 125 °C. The phenomena that the lower critical temperature of β‐iPP in iPP/EPR obviously increases to 114 °C and the upper critical temperature decreases to 134 °C indicate the narrowing of temperature interval, facilitating the formation of β‐iPP in iPP/EPR. Furthermore, it was found that the amount of β‐iPP in melt‐blended iPP/EPR samples is dependent on the composition and the maximum amount of β‐iPP formed when the composition of iPP/EPR blends is 85:15 in weight. The results through examining the effect of annealing for iPP/EPR samples at melt state indicate that this annealing may eliminate the susceptibility to β‐crystallization of iPP. However, only α‐iPP can be observed in solution‐blended samples subjected to annealing for different time. The PCM images demonstrate that an obvious phase‐separation happens in both melt‐blended and solution‐blended iPP/EPR samples, implying that compared with the disperse degree of EPR in iPP, the preparation method plays a dominant role in formation of β‐iPP. It is suggested that the origin of formation of β‐iPP results from the thermomechanical history of the EPR component in iPP/EPR. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1704–1712, 2007     

激光相干阵列探测中的二元全息光栅

从外差阵列探测出发，围绕木振光束整形问题，就计算全息位相光栅在激光相干雷达系统中的应用进行了理论及实施方面的研究，得出较好的结果。     

Experimental study of photocatalytic oxidation of formaldehyde and its by-products

Formaldehyde is one of the most harmful pollutants that endanger occupants' health and the way of its effective removal has become a focus in the field of air quality. This paper studies the static photocatalytic removal of formaldehyde experimentally and finds out that carbon monoxide, which is more harmful to occupants' health than the formaldehyde itself, is one of the by-products in the process of photocatalytic oxidation of formaldehyde. The increase of carbon monoxide concentration should be taken into consideration in the photocatalytic application. The photocatalyst surface at room temperature can weakly adsorb CO and CO₂, which can deactivate the photocatalysts.     

套索冠醚毛细管色谱柱的研制

用套索冠醚N,N′-双(2-甲基吡啶)-二氮杂-18-冠-6作为固定相,涂渍在弹性石英毛细管内,测其柱效、惰性、热稳定性、平均极性及选择性等性质.其结构由元素分析、红外光谱、核磁共振及质谱分析的试验数据所证实.试验表明,它具有良好的色谱性能、中等极性,适用于对醇、卤代烃、芳香烃等各类异构体的分离,并用分子结构观点探讨了保留机理.     

Preparation and evaluation of uniform-sized molecularly imprinted polymer beads used for the separation of sulfamethazine

Uniform-sized molecularly imprinted polymer (MIP) beads were prepared using a one-step swelling and polymerization method. The obtained sulfamethazine (SMZ)-imprinted polymer showed high affinity and selectivity toward SMZ and other structurally related sulfonamides in acetonitrile or water-acetonitrile mobile phases, particularly in high aqueous systems. The column performance of the MIPs for SMZ and its analogues could be improved by elevating the column temperature and optimizing the flow rate. The hydrogen-bonding effect plays a significant role in the recognition process of SMZ-imprinted polymer systems in organic media, while the ion-exchange effect, as well as hydrophobic effect, dominates the retention mechanism in aqueous-rich media, in addition to shape recognition.     

预制拼装体外索预应力混凝土连续梁的受力性能探讨

通过预制拼装和整体浇筑体外索预应力砼连续梁的模型试验，探讨了节段拼装连续梁的受力性能，并应用有限元法进行了结构分析比较     

安培力及其特点的分析

通过对安培力特点的分析，给出一种判断载流线回受安培力作用时线圈运动或形变总趋势的一般结论．     

中条山植被垂直带谱再分析

根据现状植被的特点，对中条山植被垂直带谱进行了再分析，修正了以前垂直带划分方案中的错误，将垂直带划为：侧柏林带（５００～１０００ｍ）——松栎林带（８００～１５００ｍ）——栓皮栎林带（１４００～２０００ｍ）——杨桦林带（１９００～２２００ｍ）——山地草甸带（２１００～２３５８ｍ）。文中对各带的特征及利用方向作了论述     

山西雪花山野生植物资源研究

雪花山位于山西永济市中条山山脉西段，含有丰富的野生植物资源，有维管植物９６科、４３７属、９１２种。按经济用途，将它分为１３类：淀粉植物、油料植物、维生素植物、饮料植物、甜味剂植物、饲用植物、蜜源植物、药用植物、纤维植物、鞣科植物、香料植物、观赏植物、树脂植物。最后提出了对雪花山野生植物资源进行保护的利用的对策