基于Mesh网的矿工心电信号无线监测系统研究

在矿难事故发生后实时监测被困矿工的生命体征,能够给营救工作提供重要的信息参考,因此设计了一款基于Mesh网的矿工心电信号无线监测系统.通过ADS1292心电检测模块对矿工的实时心电信息进行监测,然后将心电数据经过STM32F103单片机处理后通过OLED屏显示出来.同时,处理后的数据还可以通过无线组网模块发送至上位机进行显示,从而实现对井下采煤工人生命体征进行远程监测的目的.测试结果表明:该系统可以准确获取矿工心电信号波形,实测心率误差不超过4％,具有良好的应用前景和实用价值.     

Preparation and Properties of Sr3B2O6:Dy3+, Eu3+ White Phosphors Using the High-Temperature Solid-State Method

Journal of Applied Spectroscopy - Sr3B2O6:Dy3+, Eu3+ single-matrix white-light-emitting materials are prepared using the high-temperature solid-state method. The microstructure, emission spectrum,...     

Exact solutions of an asymmetric double well potential

Journal of Mathematical Chemistry - The analytical solutions of an asymmetric double well potential $$V(x)=a\, x^2-b\, x^3+c\, x^4$$ are found to be a triconfluent Heun function $$H_{T}(\alpha ,...     

Anti-Markovnikov Hydroamination of Racemic Allylic Alcohols to Access Chiral γ-Amino Alcohols

A ruthenium-catalyzed formal anti-Markovnikov hydroamination of allylic alcohols for the synthesis of chiral γ-amino alcohols is presented. Proceeding via an asymmetric hydrogen-borrowing process, the catalysis allows racemic secondary allylic alcohols to react with various amines, affording enantiomerically enriched chiral γ-amino alcohols with broad substrate scope and excellent enantioselectivities (68 examples, up to >99 % ee).     

Nanocomposite hydrogel consisting of Na‐montmorillonite with enhanced mechanical properties

A new kind of nanocomposite (NC) hydrogel with Na‐montmorillonite (MMT) is presented in this article. The NC hydrogels were synthesized by free radical copolymerization of acrylamide and (3‐acrylamidopropyl) trimethylammonium chloride (ATC) in the presence of MMT and N,N′‐methylene‐bis‐acrylamide used as chemical cross‐linker. Due to the cation‐exchange reaction between MMT and ATC (cationic monomer) during the synthesis of NC hydrogels, MMT platelets were considered chemical “plane” cross‐linkers, different from “point” cross‐linkers. With increasing amount of MMT, the crosslinking degree enhanced, causing a decrease of the swelling degree at equilibrium. Investigations of mechanical properties indicated that NC hydrogels exhibited enhanced strength and toughness, which resulted from chemical interaction between exfoliated MMT platelets and polymer chains in hydrogels. Dynamic shear measurements showed that both storage modulus and loss modulus increased with increasing MMT content. The idea described here provided a new route to prepare hydrogels with high mechanical properties by using alternative natural Na‐MMT. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1020–1026     

Formation of Azulene-Embedded Nanographene: Naphthalene to Azulene Rearrangement During the Scholl Reaction

Incorporation of a non-hexagonal ring into a nanographene framework can lead to new electronic properties. During the attempted synthesis of naphthalene-bridged double [6]helicene and heptagon-containing nanographene by the Scholl reaction, an unexpected azulene-embedded nanographene and its triflyloxylated product were obtained, as confirmed by X-ray crystallographic analysis and 2D NMR spectroscopy. A 5/7/7/5 ring-fused substructure containing two formal azulene units is formed, but only one of them shows an azulene-like electronic structure. The formation of this unique structure is explained by arenium ion mediated 1,2-phenyl migration and a naphthalene to azulene rearrangement reaction according to an in-silico study. This report represents the first experimental example of the thermodynamically unfavorable naphthalene to azulene rearrangement and may lead to new azulene-based molecular materials.     

基于盒维数的锚杆工作荷载无损检测研究

为研究锚杆工作荷载,应用了分形理论中的盒维数方法。根据一维杆波动理论,在锚杆外露端头安装一个自激式加速度传感器,利用锚杆无损检测加载试验台分级加载、检测标定测得锚杆-围岩相互作用体系在激发荷载作用下的速度响应,计算其加速度响应曲线的盒维数,拟合得出荷载-盒维数曲线,直观地判断锚杆工作荷载和锚固质量。