Unsymmetrical Pyrene‐Fused Phthalocyanine Derivatives: Synthesis,Structure, and Properties

Novel pyrene‐fused unsymmetrical phthalocyanine derivatives 2,3,9,10,16,17‐hexakis(2,6‐dimethylphenoxy)‐22,25‐diaza(2,7‐di‐tert‐butylpyrene)[4,5]phthalocyaninato zinc complex Zn[Pc(Pz‐pyrene)(OC₈H₉)₆] ( 1 ) and 2,3,9,10‐tra(2,6‐dimethylphenoxy)‐15,18,22,25‐traza(2,7‐di‐tert‐butylpyrene)[4,5]phthalocyaninato zinc compound Zn[Pc(Pz‐pyrene)₂(OC₈H₉)₄] ( 2 ) were isolated for the first time. These unsymmetrical pyrene‐fused phthalocyanine derivatives have been characterized by a wide range of spectroscopic and electrochemical methods. In particular, the pyrene‐fused phthalocyanine structure was unambiguously revealed on the basis of single crystal X‐ray diffraction analysis of 1 , representing the first structurally characterized phthalocyanine derivative fused with an aromatic moiety larger than benzene.     

四-对羟基苯基卟啉的自组装及光电特性

利用X射线光电子能谱(XPS)测试5,10,15,20-四-(对羟基苯基)卟啉单体和5,10,15,20-四-(对羟基苯基)卟啉自组装二聚体,并通过化学模拟得到卟啉自组装二聚体分子的最优构象.结果表明:两种卟啉化合物中氧原子的类型不同;在单体卟啉中未检测到瞬态表面光电压信号,卟啉自组装二聚体表现出较好的瞬态表面光伏特性;卟啉自组装二聚体的光限幅性质优于卟啉1单体.     

基于B/S模式的年度考核管理系统的设计与实现

本文阐述了新疆师范大学年度考核管理系统的功能、设计与实现。     

在新形势下如何加强高校素质教育

指出了素质教育在高校实施的重要性，并结合高校素质教育的现状，指出了一些高等教育与素质教育要求相悖离的现象，就高校实施素质教育提出了几点设想。     

Equivalent boundary integral equations for plane elasticity

Indirect and direct boundary integral equations equivalent to the original boundary value problem of differential equation of plane elasticity are established rigorously. The unnecessity or deficiency of some customary boundary integral equations is indicated by examples and numerical comparison.     

Banach空间中凸映照的增长定理

本文利用凸映照的几何特征证明了一般复Banach空间中单位球上正规化双全纯凸映照的增长定理，即||f(x)||≤||x||/(1-||x||),A↓x∈B，对复内积空间，上述估计是最佳的。     

岩石扩容现象与超声横波特征参数相互关系研究评述

介绍了岩石扩容现象与超声皮特征参数相互关系相关专业领域研究的现状及其应用，在用横波速度最大值（Vsmax）来分析岩石微裂纹初始扩展时的应力值（应力门槛值）新方法的基础上，建议利用主动的人工横波震源，应力门槛值、Vsmax后的横波速度值与岩石裂纹加速发展的同步减小特性，更深入地进入地震破裂丛集及前兆特征的研究，有可能建立地震和地质灾害性预报的新方法，并提出利用利用传统方法研究岩石扩容机理，应力门槛值，泊松比等的同时，进行岩石扩容现象，声发射和超声波横波等特性参相互关系研究的新思路。     

“回归直线法”在公司理财中的应用研究

介绍了回归直线法的由来,给出了相关性检验的两种方法:相关系数法和方差分析法,在此基础上,又给出了误差估计的3种简单方法:最大误差法、平均误差法和标准差法,使“回归直线法”在公司理财中的广泛应用,不仅具有可操作性,同时更具有可靠性.     

A Novel Polymethyl Methacrylate （PMMA）TiO2 Nanocomposite and Its Thermal and Photic Stability

A new kind of polymethyl methacrylate （PMMA）-TiO2 nanocomposite was synthesized through polymerization. The thermal and photic stability of this PMMA TiO2 nanocomposites were investigated. The as prepared samples were characterized by scanning electron microscopy （SEM）, UV-Vis spectroscopy, differential thermal analysis （DTA） and the photo-induced weight loss, The results show that the photostability of the PMMA-TiO2 nanocomposite is higher than that of the pure PMMA under UV-light irradiation, The weight loss of the pure PMMA reaches 30 % after 300 h UVirradiation, while the composite only 0.3% under the identical experimental condition. The glass transition temperature （TR） of pure PMMA is only 80℃, while the Tg of the composite reaches 258℃. Compared with pure PMMA, the thermal stability of the composite is greatly enhanced.     

“解方程器”软件包(EQNS-SOLVER)

作者提出了对于任意多项式方程组的一种带有普遍性的求解方法。多项式方程组可能没有解,或者有无穷多个解,或者有有限个解,解是实数也可以是复数。在有限个解的情况下,所创建的方法能够求出所有的解。作者完成了一个软料包,称为《解方程器》,曾在微型计算机上用FORTRAN语言完成计算过程。本文是《解方程器》软料包的说明,内容包括基本原理、方法、程序结构、应用举例以及使用的步骤。