A gold-based nanobeacon probe for fluorescence sensing of organophosphorus pesticides

A nanomaterials-based novel molecular beacon has attracted growing attentions in fluorescent assays as many nanomaterials possess excellent quenching efficiency. In this work, a gold-based nanobeacon probe was established to detect organophosphorus pesticides for the first time. The constructed gold-based nanobeacon acted as a signal indicator and could display the decreasing of the intensity in the presence of targets, which competitively bound to single strand DNA. To achieve a high sensitive probe, some parameters including solution pH, temperature and reaction time were investigated and optimized. The gold-based nanobeacon probe assay was proved to be rapid and sensitive to achieve a detection limit of 0.035 μM for isocarbophos, 0.134 μM for profenofos, 0.384 μM for phorate and 2.35 μM for omethoate, respectively. The prepared nanobeacon effectively reduced the background and improved the detection sensitivity and selectivity. The probe is stable, easy to operate and does not need sophisticated instruments. These features makes the probe feasible for screening trace organophosphorus pesticides in real samples.     

Synthesis and Photophysical Properties of a Sc3N@C80‐Corrole Electron Donor–Acceptor Conjugate

Embedding endohdedral metallofullerenes (EMFs) into electron donor–acceptor systems is still a challenging task owing to their limited quantities and their still largely unexplored chemical properties. In this study, we have performed a 1,3‐dipolar cycloaddition reaction of a corrole‐based precursor with Sc₃N@C₈₀ to regioselectively form a [5,6]‐adduct ( 1 ). The successful attachment of the corrole moiety was confirmed by mass spectrometry. In the electronic ground state, absorption spectra suggest sizeable electronic communications between the electron acceptor and the electron donor. Moreover, the addition pattern occurring at a [5,6]‐bond junction is firmly proven by NMR spectroscopy and electrochemical investigations performed with 1 . In the electronically excited state, which is probed in photophysical assays with 1 , a fast electron‐transfer yields the radical ion pair state consisting of the one‐electron‐reduced Sc₃N@C₈₀ and of the one‐electron‐oxidized corrole upon its exclusive photoexcitation. As such, our results shed new light on the practical work utilizing EMFs as building blocks in photovoltaics.     

和谐边疆构建下的宗教渗透问题研究——基于对云南跨境民族的田野调查

通过对云南跨境民族地区的田野调查,该区域宗教渗透不仅没有停止,反而呈现出多样性、隐蔽性等特点。宗教渗透对跨境民族的国家政治认同等造成了严重破坏,对云南边疆社会的稳定构成了较大的威胁,成为了云南边疆地区非传统安全问题中最敏感、最复杂、最难解决的问题之一。抵御宗教渗透不仅要完善政府宗教管理能力、改善经济条件等,更要调动作为文化主体者的跨境民族自身的"文化自觉",以主动抵御宗教渗透。只有如此才是最有效的抵御宗教渗透举措,才最终有利于和谐边疆的构建。     

Detecting nonclassicality of light via Lieb's concavity

Nonclassical light states are important for both conceptual and practical reasons: they are basic ingredients in testing and exploring quantum foundations, and are crucial resources in quantum technologies. Various useful criteria have been developed to detect nonclassicality in the literature, and several meaningful measures of nonclassicality have been introduced and measured experimentally. In this work, by use of a non-Hermitian generalization of the Wigner-Yanase-Dyson skew information and playing with operator ordering in evaluating average photon number, we develop a novel family of criteria for detecting nonclassicality of light based on Lieb's concavity, which is a deep and powerful result concerning interaction between quantum states and observables. We elucidate the information-theoretic as well as the physical meaning of the criteria, and illustrate their effectiveness in capturing and quantifying nonclassicality of various important light states.     

高校图书馆数字化与现代化服务

互联网改变了图书馆的运作方式，网络已成为高校图书馆信息采集、存储和传播的主要途径。介绍了高校图书馆数字化与现代化服务的主要内容，对高校图书馆数字化与现代化服务的功能与特点、技术关键、对策与措施及发展趋势进行了深入的探讨。     

基于能力的IT基础设施评价和规划方法

IT基础设施是IT组合的基础, 其在组织范围内为IT应用和核心业务提供可靠的共享服务.IT基础设施能力关系到企业战略及BPR的成功与否,已经成为企业战略选择的一部分,甚至是企业的一种潜在的核心能力.IT基础设施与企业战略之间的对应是战略对应的一个基本问题.文章提出了基于能力的 IT基础设施评价和规划方法,并建立了基于能力的 IT基础设施评价模型和规划模型.     

硬线控制冷却工艺

研究了影响硬线性能的主要工艺参数，这些参数是决定线材最终产品质量的关键，并初步讨论了其影响规律。     

数字电视机顶盒综述

在介绍数字电视机项盒的定义、功能及分类的基础上，着重探讨了数字电视机顶盒的软、硬件结构以及该产品的市场前景等问题。     

论知识经济条件下图书馆效益的提高

阐明了知识经济条件下图书馆效益可大致用知识的使用状况即文献借阅率、网页点击率、咨询解答率和知识创新率来表示。从知识运动的角度，分析了影响图书馆效益的主要因素。并探讨了提高图书馆效益的有效途径。