全文获取类型
收费全文 | 1826篇 |
免费 | 76篇 |
国内免费 | 35篇 |
专业分类
化学 | 1108篇 |
晶体学 | 12篇 |
力学 | 54篇 |
综合类 | 4篇 |
数学 | 133篇 |
物理学 | 361篇 |
综合类 | 265篇 |
出版年
2024年 | 11篇 |
2023年 | 13篇 |
2022年 | 70篇 |
2021年 | 76篇 |
2020年 | 45篇 |
2019年 | 49篇 |
2018年 | 44篇 |
2017年 | 34篇 |
2016年 | 69篇 |
2015年 | 61篇 |
2014年 | 77篇 |
2013年 | 154篇 |
2012年 | 129篇 |
2011年 | 152篇 |
2010年 | 108篇 |
2009年 | 115篇 |
2008年 | 82篇 |
2007年 | 76篇 |
2006年 | 74篇 |
2005年 | 71篇 |
2004年 | 49篇 |
2003年 | 46篇 |
2002年 | 41篇 |
2001年 | 27篇 |
2000年 | 20篇 |
1999年 | 19篇 |
1998年 | 10篇 |
1997年 | 11篇 |
1996年 | 8篇 |
1995年 | 5篇 |
1994年 | 9篇 |
1993年 | 12篇 |
1992年 | 9篇 |
1991年 | 9篇 |
1990年 | 9篇 |
1989年 | 7篇 |
1988年 | 7篇 |
1987年 | 7篇 |
1986年 | 12篇 |
1985年 | 12篇 |
1984年 | 13篇 |
1983年 | 6篇 |
1982年 | 14篇 |
1981年 | 11篇 |
1980年 | 7篇 |
1979年 | 6篇 |
1978年 | 4篇 |
1977年 | 10篇 |
1976年 | 7篇 |
1962年 | 3篇 |
排序方式: 共有1937条查询结果,搜索用时 15 毫秒
1.
2.
3.
4.
B. M. Azizur Rahman A. K. M. Saiful Kabir Muttukrishnan Rajarajan Kenneth T. V. Grattan 《Optical and Quantum Electronics》2005,37(1-3):171-183
Modal solutions of planar photonic crystal waveguides with rectangular air-holes are presented by using a rigorous full-vectorial finite element-based approach. The effective indices, mode field profiles, spot-sizes, power confinements, modal hybridness, beat lengths and group velocity dispersions are shown for the fundamental and higher order modes of the quasi-TE and TM polarizations. 相似文献
5.
This paper deals with the development of a numerical method to study the non-linear wave-wave interactions in oceans. Based on works from Webb-Tracy-Resio, the Hasselmann’s non-linear mathematical model is reviewed numerically. With this theory and the selection of action density domain, a program to reduce time of computation has been developed. Results from new computation are displayed graphically and compared with previous program. This work augments our understanding better about the non-linear process of wave-wave interactions and it improves the numerical computations to obtain efficiency in operational forecast. 相似文献
6.
A simple procedure for the synthesis of an important standard, isotopically enriched methylmercury, which is not commercially available, has been established successfully. The isotopically enriched standard synthesized is utilized in conventional isotope dilution mass spectrometry (IDMS), as well as in speciated IDMS (SIDMS), for determination of the true concentration of methylmercury in environmental samples. The CH3201Hg+ standard has been synthesized from commercially available 201HgO and tetramethyltin. The synthesis time required is 1 h at 60°C. The product is highly pure, yielding more than 90% as 201Hg in CH3201Hg+. Hazardous dimethylmercury does not occur during this synthesis procedure. The product synthesized was analyzed using high‐performance liquid chromatography coupled with inductively coupled plasma mass spectrometry (ICP‐MS) and ICP‐MS alone in order to determine its concentration, isotopic composition and purity. The stability of the product was also evaluated for over 6 months and found to be stable at 4°C in the dark. The isotopically enriched methylmercury synthesized can be used in SIDMS and IDMS analyses as a standard. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
7.
开赛尔·买买提明·特肯 《首都师范大学学报(自然科学版)》2007,28(5):52-57,62
乳汁中最主要的有机物是蛋白质、核酸、碳水化合物和脂类,特别是含有身体不能合成的有些氨基酸.随着科技的发展,人们对乳汁的研究更加深入,乳汁的很多营养和医疗保健功效也逐渐被发现.母乳喂养婴儿与奶粉喂养相比最大的差别是可以满足婴儿对营养的特殊需求,母乳所含的物质随着婴儿的需求而改变和调整,能提供易于消化、营养最全面的滋养物,所以母乳是母亲给予婴儿最佳的“礼物”.笔者根据一些资料进行了探究筛选,比较全面地叙述了人乳成分及其作用. 相似文献
8.
Sankar Prasad Bhuniya Safikur Rahman Anshul J. Satyanand Mahendrasinh M. Gharia Ashok M. Dave 《Journal of polymer science. Part A, Polymer chemistry》2003,41(11):1650-1658
Maize starch was modified by allyl chloride adopting an interfacial reaction technique with cetyltrimethyl ammonium bromide as a phase‐transfer catalyst and pyridine as an acid acceptor. The degree of substitution was determined from an increasing carbon content of the modified starch. The percentage of carbon and hydrogen of the allyl‐modified starch was estimated by elemental analysis (C, H, and N), and the product characterization was done through 1H NMR and 13C NMR analyses. The allyl‐modified starch was then copolymerized with methacrylic acid and a combination of methacrylic acid and acrylamide at 50 and 70 °C with potassium persulfate as an initiator. The copolymer thus formed swelled in distilled water after neutralization with sodium carbonate. The percentage of absorption capacity of the hydrogels was determined with distilled water and 0.9% NaCl solution. The highest percentage of absorption, 6500%, was achieved for the developed hydrogel containing allyl starch and acrylic monomer in a 1.7:1 w/w ratio and acrylic monomer, namely, methacrylic acid and acrylamide in a 3.2:1 w/w ratio. The study on biodegradability of the developed hydrogel showed that the hydrogel is degradable in the presence of diastase (amylase). © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1650–1658, 2003 相似文献
9.
M.Iqbal Choudhary SyedGhulam Musharraf Amtul Sami Atta‐ur‐Rahman 《Helvetica chimica acta》2004,87(10):2685-2694
The microbial transformation of (?)‐Ambrox® ( 1 ), a perfumery sesquiterpene, by a number of fungi, by means of standard two‐stage‐fermentation technique, afforded ambrox‐1α‐ol ( 2 ), ambrox‐1α,11α‐diol ( 3 ), ambrox‐1α,6α‐diol ( 4 ), ambrox‐1α,6α,11α‐triol ( 5 ), ambrox‐3‐one ( 6 ), ambrox‐3β‐ol ( 7 ), ambrox‐3β,6β‐diol ( 8 ), 13,14,15,16‐tetranorlabdane‐3,8,12‐triol ( 9 ), and sclareolide ( 10 ) (Schemes 1 and 2). Further incubation of compound 10 with Cunninghamella elegans afforded 3‐oxosclareolide ( 11 ), 3β‐hydroxysclareolide ( 12 ), 2α‐hydroxysclareolide ( 13 ), 2α,3β‐dihydroxysclareolide ( 14 ), 1α,3β‐dihydroxysclareolide ( 15 ), and 3β‐hydroxy‐8‐episclareolide ( 16 ) (Scheme 3). Metabolites 2 – 5, 12, 13 , and 16 were found to be new compounds. The major transformations include a reaction path involving hydroxylation, ether‐bond cleavage and inversion of configuration. Metabolites 11 – 16 of sclareolide showed significant phytotoxicity (Table 1). The structures of the metabolites were characterized on the basis of spectroscopic techniques. 相似文献
10.