介质对配合物稳定性的影响——Ⅱ.Cu(SCN)+—NaNO3—二氧六环—水体系

本文用分光光度法确定了25℃时配阳离子Cu(SCN)~+在NaNO_3—二氧六环—H_2O介质中的稳定常数。溶剂组成变化范围为0,5,10,15和20wt％二氧六环,离子强度范围为0.2～3.0moledm~(-3),溶液的pH=1.5～1.6。本文提出了基于Pitzer方程式的最小二乘多项式逼近法,确定出各种不同组成混合溶剂中配合物的热力学稳定常数。讨论了该常数和一级介质效应与溶剂组成和介电常数的关系。     

RADIATION CROSSLINKING OF BRANCHED POLY (VINYL ACETATE)

In the present work, radiation crosslinking of different branched poly (vinyl acetate) have beemstudied and the validity of the relationship between sol fraction and radiation dose: R(S+S~(1/2)=1/U_(1qo)+p′_o/q_oR~βto branched poly(vinyl acetate) have been assured.     

CALCULATING THE MOLECULAR INTERNAL ROTATING STERIC FACTOR OF POLYMERS BY THE RADIATION CROSSLINKING METHOD

In this paper, calculating the molecular internal rotating steric factor of polymers by the radiation crosslinking method is studied and a relationship between the molecular internal rotating steric factor (σ) and crosslinking parameter βis established~([1]) by taking account of the effect of polymer chain flexibility on βvalue, σvalue of polymer obtained by this method is in agreement with that given with other method.     

高氯氧化锌烟尘浓硫酸脱氯的影响因素

研究了浓硫酸用量、固化反应时间、物料粒度对浓硫酸法脱氯的影响。结果表明,随着浓硫酸用量增加脱氯率增大,当烟尘酸量达到０．５２ｍｌ／ｇ时,再继续增加酸量,脱氯率反而下降;固化反应时间与脱氯率呈线性关系,随着固化反应时间的延长,脱氯率增大;氯化锌烟尘粒度在６０￣１７５μｍ范围内,对脱氯率影响不大。     

16MnR钢中疲劳裂纹扩展的细观研究

采用显微疲劳试验方法和显微疲劳试验装置对低合金钢１６ＭｎＲ单边缺口试样进行了疲劳试验,研究了短裂纹萌生和扩展的特征。结果表明,短裂纹萌生及扩展分三个阶段,每一阶段的形貌都有其特点,在裂纹扩展后期,短裂纹的发展以裂纹密度不断增加并形成损伤区为主要特征,然后在损伤区选择一条主裂纹扩展。     

STRUCTURE EFFECTS ON THE SOL FRACTION-DOSE RELATIONSHIP IN RADIATION CROSSLINKING OF POLYMERS

The structure effects of polymers on the relationship between sol fraction and radiation dose arediscussed in detail. In consideration of the deviation of experimental results from Charlesby-Pin-ner's and Chen-Liu-Tang's expressions relating sol fraction to radiation dose, we introduced an ex-ponent βconcerned with the structure and property parameters of a polymer (glass transition tem-perature T_g and molecular internal rotating steric factor δ) and assumed that the fracture density isproportional to R~β(R is radiation dose). Thus, a general expression, formula (9), relating solfraction to radiation dose is derived. When β=1 andβ=0.5, this expression is reduced to the above-said two expressions. Us-ing this general expression, the experimental data of a number of polymers are treated. It is shownthat the expression is in good agreement with the experimental results, βvalue is in the range of 0. 5 to1.0.     

石墨炉原子吸收法中热解涂层石墨管在无标准分析法测定环境样品中铬的应用

本文探讨了热解涂层石墨管测定铬的最佳实验条件,研究了各种酸和干扰物质的基体效应,提出用浓氨水为基体改进剂克服高氯酸的干扰。比较了各原子化温度时的理论和实验特征量。使热解涂层石墨管有可能用于无标准分析法测定各种环境样品中的铬。     

功能高分子活性材料硫酸根离子选择电极的研制

利用辐射方法制备硫酸根离子选择电极活性材料,至今未见报导,我们首次采用辐射接枝方法制备了以疏水性高分子为骨架的带有SO~-活性基团的功能高分子活性材料,研制了硫酸根离子选择电极。结果表明,该电极具有内阻低,响应快,稳定性较好的特点,且其功能曲线的线性范围为10~(-1)～10~(-4)MSO_4~-,适宜的pH范围为4～9。     

40Cr调质齿轮弯曲强度可靠性试验研究

论述了４０Ｃｒ钢调质齿轮轮齿弯曲疲劳强度可靠性的试验研究，试验是在４个应力水平（每个应力水平的样本不少于６个）上进行的，在试验数据基础上，拟合出Ｒ－Ｓ－Ｎ曲线及方程，最终获得４０Ｃｒ钢调质齿轮齿在不同可靠度时的弯，弯曲疲劳强度值。     

A Hydrolytically Stable Vanadium(IV) Metal–Organic Framework with Photocatalytic Bacteriostatic Activity for Autonomous Indoor Humidity Control

Metal–organic frameworks (MOFs) with long-term stability and reversible high water uptake properties can be ideal candidates for water harvesting and indoor humidity control. Now, a mesoporous and highly stable MOF, BIT-66 is presented that has indoor humidity control capability and a photocatalytic bacteriostatic effect. BIT-66 (V₃(O)₃(H₂O)(BTB)₂), possesses prominent moisture tunability in the range of 45–60 % RH and a water uptake and working capacity of 71 and 55 wt %, respectively, showing good recyclability and excellent performance in water adsorption–desorption cycles. Importantly, this MOF demonstrates a unique photocatalytic bacteriostatic behavior under visible light, which can effectively ameliorate the bacteria and/or mold breeding problem in water adsorbing materials.