Detecting pore size distribution of activated carbon by low-field nuclear magnetic resonance

In this study, the transverse relaxation time (T₂) of activated carbon (AC) in different relative environment humidity was detected firstly by low-field nuclear magnetic resonance (LFNMR). The pore size (diameter) of AC distributions was calculated by the relationship between T₂ and surface relaxation rate (ρ), where ρ was obtained by the detection of nine porous materials with known pore size. The results showed that the pore size distributions of AC calculated by ρ < 0.19 nm/ms were in good agreement with that obtained by nitrogen adsorption method and proved that LFNMR as a new detection method was feasible for characterizing AC pore size distribution.     

Effect of temperature on the interactions between cellulose and lignin via molecular dynamics simulations

Cellulose - Heating is essential in various biomass pre-treatments and thermal conversion processes. It is of practical significance to study the characteristics of cellulose-lignin and...     

Synthesis and Photophysical Properties of a Sc3N@C80‐Corrole Electron Donor–Acceptor Conjugate

Embedding endohdedral metallofullerenes (EMFs) into electron donor–acceptor systems is still a challenging task owing to their limited quantities and their still largely unexplored chemical properties. In this study, we have performed a 1,3‐dipolar cycloaddition reaction of a corrole‐based precursor with Sc₃N@C₈₀ to regioselectively form a [5,6]‐adduct ( 1 ). The successful attachment of the corrole moiety was confirmed by mass spectrometry. In the electronic ground state, absorption spectra suggest sizeable electronic communications between the electron acceptor and the electron donor. Moreover, the addition pattern occurring at a [5,6]‐bond junction is firmly proven by NMR spectroscopy and electrochemical investigations performed with 1 . In the electronically excited state, which is probed in photophysical assays with 1 , a fast electron‐transfer yields the radical ion pair state consisting of the one‐electron‐reduced Sc₃N@C₈₀ and of the one‐electron‐oxidized corrole upon its exclusive photoexcitation. As such, our results shed new light on the practical work utilizing EMFs as building blocks in photovoltaics.     

考虑外界影响的元动作单元故障概率模型

为描述数控机床运动构件的故障率随时间变化的情况,本文从元动作单元出发,建立了一个关于元动作单元的故障概率模型.首先,根据元动作单元故障发生的原因将故障分成两类,随机故障和老化故障.然后,根据这两种故障类型故障数据的不同特点,选用两个不同的概率分布函数分别进行描述,随机故障用泊松分布进行描述,老化故障用威布尔分布进行描述.接着,给出这两种故障概率模型中各参数的物理意义和估计方法.更进一步,工作负载和工作环境会分别对元动作单元的老化故障和随机故障的故障率造成影响.为比较这两者对故障率影响的大小,提出了工作负载参数R l和工作环境参数R e,并给出这两个参数的估计方法.最后,根据收集到的运动构件的故障数据作出频率直方图,同时,对故障数据进行参数估计得到概率密度函数,并将这两者画在同一幅图上,发现两者具有较好的拟合效果.表明提出的元动作单元故障概率模型适合于描述运动构件故障率随时间的变化,模型有效.     

高中生物教师现状的调查及分析——以玉林市为例

以玉林高中生物教师为研究对象,通过问卷调查法和个人访谈法对高中生物教师队伍的基本结构、生物教师配备、工作量、任职、收入、科研水平和进修培训等情况进行了调查,分析得出了影响高中生物教师发展的不利因素:(1)教师队伍结构不合理;(2)公立和私立学校、城市和乡镇学校,在师资配备、教师培养、待遇等方面的投入存在着较大的差距;(3)高中生物教师工作量较大、得到发展的机会较少;(4)教学资金投入不足,不利于教学工作的开展.文中结合新形势下对高中生物教师的要求,提出了一些促进高中生物教师发展的对策,以求为有关部门有效地优化高中生物教师队伍、合理利用和分配教师资源提供理论依据和实践参考.     

中线在不对称负载作Y连接时的作用

通过实验分析和理论计算,从两个方面说明中线在不对称负载作星形连接时的作用.     

道家全生避害思想解读

阐述道家轻物重生、全生避害的思想,简单分析了其中的不合理因素,如极端个人主义,拒绝功利的价值观以及对自然的过分崇尚等,着重阐述了其中所蕴涵的合理因素,如对个体生命的重视、中道的伦理智慧和天人合一的生态智慧,揭示了全生避害思想的时代意义。     

曲柄滑块刚体导引机构的尺度综合与运动仿真

根据曲柄滑块机构的型式 ,建立了一个含有对心和偏置两种情况在内的 2 0 30 0组的基本尺寸型连杆转角函数的谐波成分数据库。通过模糊识别方法 ,在已建立的数据库中 ,寻找出能够近似实现给定刚体导引的多个曲柄滑块机构基本尺寸型 ;然后计算机构的实际尺寸及安装尺寸参数。文中还给出了综合算例和运动仿真。