首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   43853篇
  免费   5058篇
  国内免费   6695篇
化学   14361篇
晶体学   619篇
力学   1408篇
综合类   620篇
数学   2686篇
物理学   8491篇
综合类   27421篇
  2024年   127篇
  2023年   533篇
  2022年   1083篇
  2021年   1174篇
  2020年   1239篇
  2019年   1057篇
  2018年   1019篇
  2017年   1223篇
  2016年   1323篇
  2015年   1986篇
  2014年   2502篇
  2013年   2986篇
  2012年   3456篇
  2011年   3698篇
  2010年   3278篇
  2009年   3535篇
  2008年   3815篇
  2007年   3655篇
  2006年   3328篇
  2005年   2779篇
  2004年   2110篇
  2003年   1535篇
  2002年   1674篇
  2001年   1436篇
  2000年   1509篇
  1999年   779篇
  1998年   316篇
  1997年   258篇
  1996年   239篇
  1995年   239篇
  1994年   220篇
  1993年   221篇
  1992年   179篇
  1991年   125篇
  1990年   156篇
  1989年   126篇
  1988年   133篇
  1987年   82篇
  1986年   62篇
  1985年   37篇
  1984年   40篇
  1983年   47篇
  1982年   24篇
  1981年   26篇
  1980年   33篇
  1979年   31篇
  1978年   25篇
  1977年   13篇
  1974年   12篇
  1971年   12篇
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
1.
Liu  Shao-Hua  Tian  Bo 《Nonlinear dynamics》2022,108(3):2471-2482
Nonlinear Dynamics - In this paper, a (2+1)-dimensional Caudrey–Dodd–Gibbon–Kotera–Sawada system is investigated in fluid mechanics via the symbolic computation. With the...  相似文献   
2.
Bo  Luo  Gao  Wei  Yu  Yuguo  Chen  Xiaojun 《Nonlinear dynamics》2022,110(1):281-311
Nonlinear Dynamics - The perovskite solar cell (PSC) is one of the most promising photovoltaic candidates along with the highly increasing demand for green electricity. One of the main concerns...  相似文献   
3.
Three nonfused ring electron acceptors (NFREAs) TTC6,TT-C8T and TT-TC8 were purposefully designed and synthesized.The molecular geometry can be adjusted by the steric hindrance of lateral substituents.According to the DFT calculations,from TTC6 to TT-C8T and TT-TC8,planarity of the molecular backbone is gradually improved,accompanying with the enhancing of intramolecular charge transfer effect.As for TT-TC8,the two phenyl substituents are almost perpendicular to the molecular backbone,which endues the acceptor with good solubility and suppresses it to form over-aggregation.Multidirectional regular molecular orientation and closer molecular stacking are formed in TT-TC8 film.As a result,TT-TC8 based devices afford the highest PCE of 13.13%,which is much higher than that of TTC6 (4.41%) and TT-C8T (10.42%) and among the highest PCE values based on NFREAs.  相似文献   
4.
Facile construction of sulfur-rich polymers using readily available raw chemicals is an area aggressively pursued but challenging. Herein we use common feedstocks of ethylene oxide (EO), propylene oxide (PO), and carbonyl sulfide (COS) to synthesize copoly(thioether)s which are traditionally produced from unpleasant and difficult to store episulfides. In this protocol, the EO/COS coupling selectively generates a pure poly(ethylene sulfide) (PES) with melting temperature (Tm) values up to 172°C and high yields up to 98%. The EO/PO/COS terpolymerization leads to the incorporation of soft poly(propylene sulfide) (PPS) and hard PES segments together, affording a random PES-co-PPS copoly(thioether) with the complete consumption of EO and PO. Additionally, by simply varying the EO/PO feeding ratio, the obtained copoly(thioether)s possess tunable thermal properties, Tm values in the range of 76–144°C, and excellent solubility. These copolymerizations are conducted in one-pot/one-step at industrially favored reaction temperatures of 100–120°C using catalysts of common organic bases, suggesting a facile and practical manner. Especially, the copoly(thioether) exhibits high refractive indices up to 1.68 owing to its high sulfur content, suggesting a broad application prospect in optical materials.  相似文献   
5.
以黑果枸杞和全脂奶粉为主要原料,通过单因素试验和响应面优化试验确定黑果枸杞凝固型酸奶的最佳工艺.结果表明:黑果枸杞汁8.20%,白砂糖9%,菌粉0.91%,42℃发酵4.94 h,在此工艺条件下,所得黑果枸杞酸奶感官评分与预测值接近,色泽适宜、质地均匀、酸甜可口,具有黑果枸杞特有的风味.  相似文献   
6.
提升中国创新文化国际竞争力,是全面塑造发展新优势的关键着力点,对我国建设创新型国家具有基础性、长期性、决定性影响.通过构建创新文化竞争力指标体系,选取GII创新指数排名和GDP总量排名均为前20的国家作为研究对象,运用主成分分析法对创新文化国际竞争力进行评价,研究发现:①从综合竞争力水平来看,英国、荷兰、美国、瑞士处于第一梯队,德国、加拿大、法国处于第二梯队,中国、韩国、日本为第三梯队;②从竞争力构成要素来看,中国创新文化可持续发展能力和国家创新驱动力具有相对竞争优势,发展基础力和创新型产业支撑力亟待提升,创新文化吸引力也存在进步空间.为此,提出完善创新文化发展的基础条件、讲好中国故事、加大要素投入等管理启示,以期为提升中国创新文化国际竞争力,建设创新型国家提供针对性建议.  相似文献   
7.
Given their superior penetration depths, photosensitizers with longer absorption wavelengths present broader application prospects in photodynamic therapy (PDT). Herein, Ag2S quantum dots were discovered, for the first time, to be capable of killing tumor cells through the photodynamic route by near-infrared light irradiation, which means relatively less excitation of the probe compared with traditional photosensitizers absorbing short wavelengths. On modification with polydopamine (PDA), PDA-Ag2S was obtained, which showed outstanding capacity for inducing reactive oxygen species (increased by 1.69 times). With the addition of PDA, Ag2S had more opportunities to react with surrounding O2, which was demonstrated by typical triplet electron spin resonance (ESR) analysis. Furthermore, the PDT effects of Ag2S and PDA-Ag2S achieved at longer wavelengths were almost identical to the effects produced at 660 nm, which was proved by studies in vitro. PDA-Ag2S showed distinctly better therapeutic effects than Ag2S in experiments in vivo, which further validated the enhanced regulatory effect of PDA. Altogether, a new photosensitizer with longer absorption wavelength was developed by using the hitherto-unexplored photodynamic function of Ag2S quantum dots, which extended and enhanced the regulatory effect originating from PDA.  相似文献   
8.
以鄂北冬枣为材料,对果实采后低温贮藏过程中相关酶活性与果实硬度进行相关分析、通径分析和灰色关联分析。分析结果表明,各相关酶活性与硬度的相关程度依次为PG、SOD、CAT、PME、POD,与果实硬度的贡献率大小依次为PG、CAT、SOD、PME、POD,与果实硬度的关联度顺序为PME、SOD、PG、CAT、POD。综合分析结果表明,PG活性、CAT活性、SOD活性为果实贮藏过程中主要的酶,在贮藏过程中对果实软化衰老起重要作用。  相似文献   
9.
We conducted measurements of black carbon(BC) aerosol in Jiaxing,China during autumn from September 26 to November 30,2013.We investigated temporal and diurnal variations of BC,and its correlations with meteorological parameters and other major pollutants.Results showed that hourly mass concentrations of BC ranged from 0.2 to 22.0 μg/m3,with an average of 5.1 μg/m3.The diurnai variation of BC exhibited a bimodal distribution,with peaks at 07:00 and 18:00.The morning peak was larger than the evening peak.The mass percentages of BC in PM2.5 and PM10 were 7.1%and 4.8%,respectively.The absorption coefficient of BC was calculated to be 44.4 Mm-1,which accounted for 11.1%of the total aerosol extinction.BC was mainly emitted from local sources in southwestern Jiaxing where BC concentrations were generally greater than 11 μg/m3 during the measurement period.Correlation analysis indicated that the main sources of BC were motor vehicle exhaust,and domestic and industrial combustion.  相似文献   
10.
在多分量地震技术中,准确地求取出纵、横波速比(γ)是多分量资料处理、反演、解释各环节中的一个重要步骤。由于地下同一层位具有相同的波阻抗比,因此该层位的反射纵波和反射转换波相互关联,纵横波速比与时间比存在相互转化关系。基于Sinc插值算法与相关系数谱分析的纵横波速比扫描方法是通过设置一系列γ,利用Sinc插值算法将纵波拉伸后与转换波进行互相关,当互相关系数达到最大时即可求出相应的γ。理论数据和实际资料的测试,验证了该方法的有效性、准确性和实用性。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号