全文获取类型
收费全文 | 1717篇 |
免费 | 142篇 |
国内免费 | 118篇 |
专业分类
化学 | 1054篇 |
晶体学 | 15篇 |
力学 | 40篇 |
综合类 | 4篇 |
数学 | 170篇 |
物理学 | 306篇 |
综合类 | 388篇 |
出版年
2024年 | 8篇 |
2023年 | 30篇 |
2022年 | 40篇 |
2021年 | 40篇 |
2020年 | 43篇 |
2019年 | 53篇 |
2018年 | 43篇 |
2017年 | 41篇 |
2016年 | 59篇 |
2015年 | 66篇 |
2014年 | 66篇 |
2013年 | 80篇 |
2012年 | 120篇 |
2011年 | 120篇 |
2010年 | 89篇 |
2009年 | 72篇 |
2008年 | 92篇 |
2007年 | 82篇 |
2006年 | 71篇 |
2005年 | 79篇 |
2004年 | 60篇 |
2003年 | 52篇 |
2002年 | 82篇 |
2001年 | 79篇 |
2000年 | 53篇 |
1999年 | 59篇 |
1998年 | 29篇 |
1997年 | 33篇 |
1996年 | 42篇 |
1995年 | 29篇 |
1994年 | 21篇 |
1993年 | 15篇 |
1992年 | 23篇 |
1991年 | 25篇 |
1990年 | 18篇 |
1989年 | 17篇 |
1988年 | 16篇 |
1987年 | 1篇 |
1986年 | 9篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1983年 | 6篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1967年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有1977条查询结果,搜索用时 9 毫秒
1.
Haishan Bu Yanwan Pang Dandan Song Tongyin Yu T. M. Voll George Czornyj B. Wunderlich 《Journal of Polymer Science.Polymer Physics》1991,29(2):139-152
Various approaches to the preparation and verification of single-molecule single crystals are discussed for polyethylene and poly (oxyethylene). Analytic tools are electron microscopy, electron diffraction, and differential scanning calorimetry. The main difficulty in producing a single-molecule single crystal is to keep crystals from joining during growth. 相似文献
2.
本文介绍了在水电工程规划设计时,如何利用三次自然样条插值函数在有限个方案的基础上自动生成无限多个方案,然后采用多目标综合决策模型在其中选择最优方案的一种方法.文中还给出了程序流程,并以某水电站正常蓄水位选择作为实例,对方法进行了验证,结果与专家决策完全吻合. 相似文献
3.
张海山 《首都师范大学学报(自然科学版)》1994,15(2):17-22
本文解决了一类非双曲型的不定型(亚双曲型)广义Cartan矩阵的分类问题.证明了亚双曲型矩阵的阶数范围,并做出了阶数为3,5,6的亚双曲型广义Cartan矩阵的Dynkin图. 相似文献
4.
文章分析了材料力学实验的现状和目前存在的问题,针对性地进行了实验教学改革的探索,并应用于实验教学当中,取得了良好的教学效果。 相似文献
5.
6.
7.
Haishan Bu Erqiang Chen Shengyong Xu Kexin Guo Bernhard Wunderlich 《Journal of Polymer Science.Polymer Physics》1994,32(8):1351-1357
Single-molecule single crystals were grown from amorphous droplets of fractionated isotactic polystyrene. The crystals were analyzed by electron microscopy and electron diffraction. The molecular mass distribution could be matched with a statistical analysis of single-molecule particles (amorphous and crystals). Proof was brought that single molecules of isotactic polystyrene do not reach equilibrium dimensions on crystallization, rather assume the lamellar morphology with chain-folded macroconformation, also known from crystallization of polymolecular crystals. © 1994 John Wiley & Sons, Inc. 1 This article is a US Government work and, as such, is in the public domain in the United States of America. US Government contract No. DE-AC05-840R-21400. 相似文献
8.
On the basis of the structures and properties of the ClO/ClO? system obtained at the density functional theory (DFT) (UB3LYP) level, employing the 6‐311+G(3df) standard basis set, the electron transfer reactivity of this system is investigated. The results indicate that there are five possible stable coupling complexes that correspond to the generous minima on the global potential energy surfaces (PES). The most stable coupling complex is planar EC4, in which there is a O? O linkage with two trans‐Cl atoms. Their stabilization energies are calculated to be 20.57 (EC1: C1), 20.54 (EC2: C2, 2B), 20.69 (EC3: C1), 20.70 (EC4: Cs, 2A′), and 20.69 (EC.5: C2h, 2Bu) kcal/mol at the B3LYP/6‐311+G(3df) level; with the correction of the basis set superposition error (BSSE), the stability order of these encounter complexes is EC4 > EC.5 > EC3 > EC1 > EC2. Based on the five encounter complexes, five coupling modes are designed for the study of the electron transfer reactivity of this system. The dissociation energy curves at the activated states and the corresponding activation energies of these five coupling modes are obtained and are compared at the B3LYP/6‐311+G(3df) and MP2/6‐311+G* levels. The inapplicability of DFT methods has also been discussed in this article in predicting the energy curves, especially with a long contact distance, in which DFT methods give the abnormal behavior for the dissociations of the complexes caused by the “inverse symmetry breaking” problem. On the basis of the golden rule of the time‐dependent perturbation theory, the electron transfer reactivity and the contact distance dependence of the various electron transfer kinetics parameters (e.g., activation energy, coupling matrix element) have been analyzed at the UMP2(full)/6‐311+G* level. The electron transfer can take place over a range of contact distances, but the most effective coupling distance corresponds to only a small range. The coupling orientation analyses also indicate that the most favorable coupling mode to the electron transfer does not always correspond to the most stable encounter complex mechanism. Some highly energetic coupling modes are more favorable for the electron transfer. © 2004 Wiley Periodicals, Inc. Int J Quantum Chem, 2005 相似文献
9.
A simple and efficient preparation of gramicidin S and its analogues is described. It involves solid-phase peptide synthesis and on-resin macrolactamization without side chain protection, affording cyclic products in high yield and high purity. The high specificity of the cyclization reaction was shown to originate in the formation of a pre-organized conformation of the linear biosynthetic precursor of gramicidin S. This facile method will provide convenient access to the analogues of the natural product for functional optimization to counter microbial resistance. 相似文献
10.
In current clinical practice, photodynamic therapy (PDT) is carried out with prescribed drug doses and light doses as well as fixed drug-light intervals and illumination fluence rates. This approach can result in undesirable treatment outcomes of either overtreatment or undertreatment because of biological variations between different lesions and patients. In this study, we explore the possibility of improving PDT dosimetry by monitoring drug photobleaching and photoproduct formation. The study involved 60 mice receiving the same drug dose of a novel verteporfin-like photosensitizer, QLT0074, at 0.3 mg/kg body weight, followed by different light doses of 5, 10, 20, 30, 40 or 50 J/cm2 at 686 nm and a fluence rate of 70 mW/cm2. Photobleaching and photoproduct formation were measured simultaneously, using fluorescence spectroscopy. A ratio technique for data processing was introduced to reliably detect the photoproduct formed by PDT on mouse skin in vivo. The study showed that the QLT0074 photoproduct is stable and can be reliably quantified. Three new parameters, photoproduct score (PPS), photobleaching score (PBS) and percentage photobleaching score (PBS%), were introduced and tested together with the conventional dosimetry parameter, light dose, for performance on predicting PDT-induced outcome, skin necrosis. The statistical analysis of experimental results was performed with an ordinal logistic regression model. We demonstrated that both PPS and PBS improved the prediction of skin necrosis dramatically compared to light dose. PPS was identified as the best single parameter for predicting the PDT outcome. 相似文献